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应用化学
Chinese Journal of Applied Chemistry
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Preparation and Application of Melamine Magnetic Molecularly Imprinted Solid Phase Extraction Material
LIU Yunan1,2, ZHANG Zhaohui1,2,3*, CHEN Xing1, CHEN Hongjun1, RAO Wei1, CAI Rong1
(1.Key Laboratory of Hunan Forest Products and Chemical Industry Engineering,
Jishou University,Zhangjiajie 427000,China;
2.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,China;
3.State Key Laboratory of Chemo/Biosensing and Chemometrics,Hunan University,Changsha 410082,China)
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Abstract  A novel melamine magnetic molecularly imprinted polymer(Fe3O4-GO@SiO2@MIP) was prepared based on graphene oxide(GO) using melamine(MEL) as the template molecule, methacrylic acid(MAA) as the functional monomer and ethylene glycol dimethacrylate(EGDMA) as the cross-linker. The Fe3O4-GO@SiO2@MIP was characterized by scanning electron microscope(SEM), transmission electron microscope(TEM), thermogravimetric analysis(TGA) and vibrating sample magnetometer(VSM). The results showed that MEL imprinted layer was grafted on magnetic GO surface successfully. The adsorption properties were investigated by high performance liquid chromatography, and the results demonstrated that the Fe3O4-GO@SiO2@MIP exhibited specific selectivity towards MEL. The maximum adsorption capacity of Fe3O4-GO@SiO2@MIP is 33.11 mg/g, and the selectivity factor of MEL towards CYR and CYA is 2.43 and 2.84, respectively. Combined with magnetic solid phase extraction(M-SPE) and high-performance liquid chromatography with the imprinted material as stationary phase, melamine from the sample solution of milk was successfully separated, enriched and detected.
Keywords Imprinted polymer      Melamine      Magnetic graphene oxide      Magnetic solid phase extraction      High-performance liquid chromatography     
:  O657  
Issue Date: 02 July 2013
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LIU Yunan1,2, ZHANG Zhaohui1,2,3*, CHEN Xing1, CHEN Hongjun1, RAO Wei1, CAI Rong1. Preparation and Application of Melamine Magnetic Molecularly Imprinted Solid Phase Extraction Material[J]. Chinese Journal of Applied Chemistry,2013, 30(10): 1222-1230.
URL:  
http://yyhx.ciac.jl.cn//EN/10.3724/SP.J.1095.2013.30018     OR     http://yyhx.ciac.jl.cn//EN/Y2013/V30/I10/1222
[1] Sugita T,Ishiwata H,Yoshihira K. Release of Formaldehyde and Melamine from Tableware Made of Melamine-formaldehyde Resin[J]. Food Addit Contam,1990,7:21-27.
[2] Wu Y T,Huang C M,Lin C C,et al. Determination of Melamine in Rat Plasma, Liver, Kidney, Spleen, Bladder and Brain by Liquid Chromatography-tandem Mass Spectrometry[J]. J Chromatogr A,2009,1216:7595-7601.
[3] Wu Y N,Zhao Y F,Li J G. A Survey on Occurrence of Melamine and Its Analogues in Tainted Infant Formula in China[J]. Biomed Environ Sci,2009,22(2):95-99.
url: http://118.145.16.217/magsci/article/article?id=14914088
[4] Chang H,Shi X F,Shen W,et al. Characterization of Melamine-associated Urinary Stones in Children with Consumption of Melamine-contaminated Infant Formula[J]. Clin Chim Acta,2012,413(11/12):985-991.
url: http://dx.doi.org/10.1016/j.cca.2012.02.025
[5] Mohd M S,Hana H A,Wan A W I,et al. Dispersive Liquid-liquid Microextraction Method Based on Solidification of Floating Organic Droplet for the Determination of Triazine Herbicides in Water and Sugarcane Samples[J]. Food Chem,2012,133(2):557-562.
url: http://dx.doi.org/10.1016/j.foodchem.2012.01.036
[6] Song X Y,Shi Y P,Chen J. Carbon Nanotubes-reinforced Hollow Fibre Solid-phase Microextraction Coupled with High Performance Liquid Chromatography for the Determination of Carbamate Pesticides in Apples[J]. Food Chem,2013,139(1/4):246-252.
url: http://dx.doi.org/10.1016/j.foodchem.2013.01.112
[7] Wullf G,Sarhan A. Use of Polymer with Enzyme-analogous Structures for Theresolution of Racemates[J]. Angew Chem Int Ed Eng,1972,11(4):341-344.
[8] WANG Jun,LV Tian,ZHAO Meiping,et al. Recognition Performance ofo-Phthalic Acid-Cu(Ac)2 Molecular Imprinting Polymers[J]. Chem J Chinese Univ,2006,27(8):1566-1569(in Chinese).王俊,吕恬,赵美萍,等. 邻苯二甲酸-乙酸铜分子印迹聚合物识别性能的研究[J]. 高等学校化学学报,2006,27(8):1566-1569.
url: http://118.145.16.217/magsci/article/article?id=18633113
[9] ZHANG Maosheng,HUANG Jiarong,ZHENG Xianghua,et al. Preparation and Selective Permeation Characterization of Moleculary Imprinted Membranes with Malachite Green as Template[J]. Chinese J Appl Chem,2010,27(1):107-111(in Chinese).张茂升,黄佳蓉,郑向华,等. 孔雀石绿分子印迹膜的制备和渗透性[J]. 应用化学,2010,27(1):107-111.
url: http://118.145.16.217/magsci/article/article?id=1412726
[10] HUANG Dandan,LI Li,YIN Yongguan,et al. Synthesis of Molecularly Imprinted Polymers for the Application of Selective Clean-up Vinblastine from Catharanthus Roseus Extract[J]. Sci China:Ser B,2010,40(6):794-800(in Chinese).黄丹丹,李莉,殷勇冠,等. 分子印迹聚合物选择性富集长春碱的研究[J]. 中国科学:B辑,2010,40(6):794-800.
url: http://118.145.16.217/magsci/article/article?id=17277506
[11] LI Lili,ZHOU Wenhui,LI Yong,et al. Synthesis of Domoic Acid Imprinted Polymer and Its Extraction Application[J]. Chinese J Appl Chem,2010,27(2):132-136(in Chinese).李丽丽,周文辉,李永,等. 软骨藻酸分子印迹聚合物的制备及其固相萃取应用[J]. 应用化学,2010,27(2):132-136.
url: http://118.145.16.217/magsci/article/article?id=1412809
[12] Ying L,Xin L,Dong C K,et al. Synthesis of Core-shell Magnetic Molecular Imprinted Polymer by the Surface RAFT Polymerization for the Fast and Selective Removal of Endocrine Disrupting Chemicals from Aqueous Solutions[J]. Environ Pollut,2010,158:2317-2323.
[13] Ying L,Xin L,Dong C K,et al. A Graphene Oxide-based Molecularly Imprinted Polymer Platform for Detecting Endocrine Disrupting Chemicals[J]. Carbon,2010,48:3427-3433.
url: http://118.145.16.217/magsci/article/article?id=14936466
[14] Zhang Y,Liu R J,Hu Y L,et al. Microwave Heating in Preparation of Magnetic Molecularly Imprinted Polymer Beads for Trace Triazines Analysis in Complicated Samples[J]. Anal Chem,2009,81:967-976.
[15] ZHOU Wenhui,LIN Liming,GUO Xiuchun,et al. Synthesis of Melamine Molecularly Imprinted Polymer and Separation of Melamine in Milk Products[J]. J Instrum Anal,2009,28(6):687-691(in Chinese).周文辉,林黎明,郭秀春,等. 三聚氰胺分子印迹聚合物的制备及奶制品中三聚氰胺的分离[J]. 分析测试学报,2009,28(6):687-691.
url: http://118.145.16.217/magsci/article/article?id=2618825
[16] YANG Weihai,YAN Shoulei,WEI Chen,et al. Preparation of Melamine Molecularly Imprinted Polymer Microspheres by Precipitation Polymerization[J]. Acta Polym Sin,2010,10:1163-1169(in Chinese).杨卫海,严守雷,卫晨,等. 沉淀聚合法制备三聚氰胺分子印迹聚合物微球[J]. 高分子学报,2010,10:1163-1169.
url: http://118.145.16.217/magsci/article/article?id=1405930
[17] Zhang Z H,Zhang M L,Liu Y N,et al. Preparation of L-Phenylalanine Imprinted Polymer Based on Monodisperse Hybrid Silica Microsphere and Its Application on Chiral Separation of Phenylalanine Racemates as HPLC Stationary Phase[J]. Sep Purif Technol,2012,87:142-148.
[18] Li Z,Di P,Li D,et al. Mixed Hemimicelles SPE Based on CTAB-Coated Fe3O4/SiO2 NPs for the Determination of Herbal Bioactive Constituents from Biological Samples[J]. Talanta,2010,80:1873-1880.
url: http://118.145.16.217/magsci/article/article?id=15380844
[19] Zhang W,Qin L,He X,et al. Molecularly Imprinted Polymer Prepared with Bonded β-Vyclodextrin and Acrylamide on Functionalized Silicagel for Selective Recognition of Tryptophan in Aqueous Media[J]. J Chromatogr A,2008,1187:94-102.
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