Preparation of Molecularly Imprinted Solid Phase Extraction Column Using Double Functional Monomers for the Determination of trans-Resveratrol

doi:10.11944/j.issn.1000-0518.2015.11.150137

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (11): 1283-1289.DOI: 10.11944/j.issn.1000-0518.2015.11.150137

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Preparation of Molecularly Imprinted Solid Phase Extraction Column Using Double Functional Monomers for the Determination of trans-Resveratrol

LI Yuanyuan^a^*(),ZHAO Chuande^b,ZHANG Haixia^b

^aKey Laboratory of Energy and Chemical Engineering,Ningxia University,Yinchuan 750021,China
^bSchool of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,China

Received:2015-04-13 Accepted:2015-06-26 Published:2015-11-02 Online:2015-11-02
Contact: LI Yuanyuan
Supported by:
Supported by the National Natural Science Foundation of China(No.21465019), Research Project for Science and Technology of Higher Education of Ningxia Province of China(No.NGY2014011)

Abstract

Abstract:

A novel molecularly imprinted polymer(DMIP) for trans-resveratrol was fabricated with bonded β-cyclodextrin(β-CD) and methacrylic acid as double monomers. Molecularly imprinted solid phase extraction column prepared with bonded double monomers has higher imprinting effect to the template molecule. DMIP prepared using bonded β-CD and methacylic acid, either separately or combined have shown various recognition properties. The results of adsorption experiments indicated that the selectivity of DMIP is superior to those obtained with only methacrylic acid(SMIP). Molecularly imprinted solid phase extraction column was used to determine the trans-resveratrol in wine and Chinese liquor samples. The recoveries of 87.9%~93.2%, 87.9%~93.2% and 89.3%~91.2% are obtained for red wine and white wine and Chinese Liquor, respectively. This method is highly sensitive and specific for the analyte, along with a low limit of determination at 0.001 mg/L and a linear range from 0.003 to 2 mg/L.

Key words: molecularly imprinted polymers, trans-resveratrol, β-cyclodextrin, solid-phase extraction, wine sample, high performance liquid chromatography

LI Yuanyuan, ZHAO Chuande, ZHANG Haixia. Preparation of Molecularly Imprinted Solid Phase Extraction Column Using Double Functional Monomers for the Determination of trans-Resveratrol[J]. Chinese Journal of Applied Chemistry, 2015, 32(11): 1283-1289.

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Preparation of Molecularly Imprinted Solid Phase Extraction Column Using Double Functional Monomers for the Determination of trans-Resveratrol

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