Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (2): 77-80.

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Extraction of Sc(Ⅲ) by ELM Method Using PMBP as Caaarrier

Li Yadong, Li Zhiyong, Zheng Huagui, Li Longquan, Zhou Yi   

  1. Department of Applied Chemistry, University of Science and Technology of China, Heifei 230026
  • Received:1993-06-08 Revised:1993-10-26 Published:1994-04-10 Online:1994-04-10

Abstract: Scandium(Ⅲ) was extracted by the emulsion liquid membrane (ELM)method using 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-on as a carrier. The extraction rate of Sc(Ⅲ) was more than 95.5% and the separation factor for Sc(Ⅲ) and mixed rare earths βSC/RE was 32.0. The optimum conditions for the extraction as follows:pH=1.7~3.8 for feed liquid, PMBP 0.4%, surfactant Span80.3%, mixed solution of liquid paraffin and kerosene 5%, concentration of HCl in the internal phase 3mol/L, Roi=1:1,Rwe=20:1.

Key words: scandium, mixed rare earth, extraction, separation, emulsion liquid membranemethod, benzoyl-methyl-phenyl-pyrazolidone