Aquahemistry of Titanocene Dichloride and Crystal Structure of Titanocene Bis(salicylate)

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (1): 28-32.

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Aquahemistry of Titanocene Dichloride and Crystal Structure of Titanocene Bis(salicylate)

Lu Zhengrong¹, Gao Songqi², Zhou Yaokun³, Wu Shaozu³

1. Department of Chemistry, Department of Environmental Science, Wuhan University, Wuhan 430072;
2. Department of Chemistry, Lanzhou University, Lanzhou

Received:1993-01-19 Revised:1993-06-15 Published:1994-02-10 Online:1994-02-10

Abstract

Abstract: The (KCn)₂TiCl₂(R=H, Me )-acetylacetone system reacts with potassium thiocyanate, sodium thiocarbamate or sodium 2- substituted benzoates in aqueous medium, giving (RCp)₂Ti(SCN)₂,(RCp)Ti(S₂CNR₂)₃ and (RCp)₂Ti(O₂C(2-X)C₆H₄)₂ respectly,(X=OH,CI,NH₂) except for bis(methylcyclopentadienyl )salicylatotitanium. The structure of titanocene bis(salicylate ) single crystal was determined by X-ray diffraction. The compound crystallizes in orthorhombic space group P_ccn with a=1. 3538(3)nm,b=1. 4273(5)nm,c=2.1506(7)nm, z=8,R=0.042 and R_w=0.039。

Key words: cyclopentadienyl, titanium compound, aquachemistry, crystal structure

Lu Zhengrong, Gao Songqi, Zhou Yaokun, Wu Shaozu. Aquahemistry of Titanocene Dichloride and Crystal Structure of Titanocene Bis(salicylate)[J]. Chinese Journal of Applied Chemistry, 1994, 0(1): 28-32.

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Aquahemistry of Titanocene Dichloride and Crystal Structure of Titanocene Bis(salicylate)

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