SYNERGISTIC EXTRACTION OF ZINC(Ⅱ)WITH DI(1-METHYLHEPTYL)METHYL PHOSPHONATE AND PRIMARY AMINE N1923

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (2): 11-15.

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SYNERGISTIC EXTRACTION OF ZINC(Ⅱ)WITH DI(1-METHYLHEPTYL)METHYL PHOSPHONATE AND PRIMARY AMINE N₁₉₂₃

Han Shumin, Li Deqian

Changchun Institute of Applied Chemistty, Academia Sinica, Changchun 130022

Received:1990-03-02 Revised:1990-05-28 Published:1991-04-10 Online:1991-04-10

Abstract

Abstract: The synergistic extraction of Zn(Ⅱ) from (Na,H)Cl solutions with di(1-methylheptyl)methylphosphonate (P₃₅₀) and primary amine N₁₉₂₃(RNH₂) in n-heptane at 30℃ has beeninvestigated.The composition of the synergistic extraction complex was determined to be(RNH₃Cl)(3/2)·ZnCl₂·P₃₅₀ by common methods, as well as IR and ¹H NMR.The equilibrium constants and thermodynamic parameters of the synergistic extractionreaction were calculated.The structural effects of TBP, DBBP and P₃₅₀ on the synergisticextraction of Zn were also discussed.

Key words: di(methylheptyl)methyl phosphonate, primary amine, synergistic extraction, zine

Han Shumin, Li Deqian. SYNERGISTIC EXTRACTION OF ZINC(Ⅱ)WITH DI(1-METHYLHEPTYL)METHYL PHOSPHONATE AND PRIMARY AMINE N₁₉₂₃[J]. Chinese Journal of Applied Chemistry, 1991, 0(2): 11-15.

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SYNERGISTIC EXTRACTION OF ZINC(Ⅱ)WITH DI(1-METHYLHEPTYL)METHYL PHOSPHONATE AND PRIMARY AMINE N₁₉₂₃

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