SYNTHESIS OF TRIMETHYLSILOXYALKYLPHOSPHONATES FROM SILICON-PHOSPHORUS REAGENT

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (1): 33-37.

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SYNTHESIS OF TRIMETHYLSILOXYALKYLPHOSPHONATES FROM SILICON-PHOSPHORUS REAGENT

Zhao YongZhen, Li Zhonghua

Department of Chemistry, Central China Normal University, Wuhan 430070

Received:1990-03-26 Revised:1990-06-07 Published:1991-02-10 Online:1991-02-10

Abstract

Abstract: This paper reports a reaction between trimethylsiloxyphosphite (an active silicon-phosp-horus reagent) with aldehydes or ketones, and fourteen compounds of diethyl trimethylsilo-xyalkylphosphonates have been synthesized.The structures of the products were confirmedby IR,¹H NMR,³¹P NMR,MS and elemental analysis measurements.The reaction mechanismis discussed.

Key words: silicon-phosphorus reagent, trimethylsiloxyphosphite, diethyl trimethylsilox-yalkylphosphonate, aldehyde, ketone, synthesis

Zhao YongZhen, Li Zhonghua. SYNTHESIS OF TRIMETHYLSILOXYALKYLPHOSPHONATES FROM SILICON-PHOSPHORUS REAGENT[J]. Chinese Journal of Applied Chemistry, 1991, 0(1): 33-37.

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SYNTHESIS OF TRIMETHYLSILOXYALKYLPHOSPHONATES FROM SILICON-PHOSPHORUS REAGENT

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