Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid

doi:10.19894/j.issn.1000-0518.220406

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (5): 749-757.DOI: 10.19894/j.issn.1000-0518.220406

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Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid

Chen-Li HAO¹, Qing-Wei DING¹, Shi-Chang JIA¹, Yang-Bo MAO², Song-Bai WANG³, Jun MA¹()

^1.School of Environment and Resources，Taiyuan University of Science and Technology，Taiyuan 030024，China
^2.Engineering Research Center of Heavy Machinery of Ministry of Education，Taiyuan University of Science and Technology，Taiyuan 030024，China
^3.School of Chemistry and Chemical Engineering，Shanxi University，Taiyuan 030006，China

Received:2022-12-16 Accepted:2023-03-28 Published:2023-05-01 Online:2023-05-26
Contact: Jun MA
About author:junma0888@tyust.edu.cn
Supported by:
Shanxi Scholarship Council of China(2021-011);the Natural Science Foundation of Shanxi Province(201901D111249);the Doctoral Starting up Foundation of Taiyuan University of Science and Technology(20192012);the College Student's Innovative Entrepreneurial Training Plan Program(202210109014)

Abstract

Abstract:

In this paper， titanate nanotubes （TNTs） are prepared by hydrothermal method， and then the titanate nanotubes （TNTs-LA） are modified with lipoic acid by impregnation method. The structure of TNTs-LA is characterized by scanning electron microscopy （SEM）， transmission electron microscopy （TEM）， X-ray diffraction （XRD）， X-ray photoelectron spectroscopy （XPS） and infrared spectroscopy （FT-IR）， and the adsorption performance of methylene blue （MB） is evaluated. The results show that the adsorption performance of titanate nanotubes modified with lipoic acid is obviously enhanced. The removal of MB is also related to the pH of solution. The kinetic study shows that the adsorption kinetics of MB by titanate nanotubes accords with the second-order kinetic equation. The maximum adsorption capacity of MB on TNTs-LA is 216.98 mg/g by Langmuir adsorption isotherm model.

Key words: Titanate nanotubes, Lipoic acid, Methylene blue, Adsorption

CLC Number:

O647.3

Chen-Li HAO, Qing-Wei DING, Shi-Chang JIA, Yang-Bo MAO, Song-Bai WANG, Jun MA. Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid[J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 749-757.

Figures/Tables 13

Fig.1 Chemical structure of Lipoic acid

Fig.2 SEM images of TNTs （A） and TNTs-LA （B）

Fig.3 TEM images of TNTs （A， B） and TNTs-LA （C， D）

Fig.4 XRD images of TNTs and TNTs-LA

Fig.5 Survey XPS spectra （A）， high resolution spectra of S2p （B） and O1s （C） of TNTs-LA

Fig.6 FT-IR spectra of TNTs and TNTs-LA

Fig.7 Effect of dosage on adsorption of MB by TNTs-LA

Fig.8 Kinetic adsorption curves of TNTs-LA

Table 1 Kinetic parameters for adsorption of MB by TNTs-LA

Kinetic models	Pseudo first order kinetic moder			Pseudo second order kinetic moder
Parameters	q_e，cal/（mg·g^-1）	k₁/min^-1	r²	q_e，cal/（mg·g^-1）	k₂/（g·mg^-1·min^-1）	r²	q_e，exp/（mg·g^-1）
MB	150.75	0.065	0.956 9	162.23	5.86×10^-4	0.984 7	161.07

Fig.9 Isothermal adsorption fitting curve of TNTs-LA

Table 2 Isotherm model parameters for adsorption of MB by TNTs-LA

Isotherm models	Langmuir model			Freundlich model
Parameters	Q/（mg·g^-1）	b/（L·mg^-1）	r²	K_F/（mg·g^-1）	n	r²
MB	216.98	3.51	0.975 8	136.36	0.16	0.846 9

Table 3 Adsorption capacity of MB by different materials

Materials	TNTs-LA	TNTs^［39］	Jordanian diatomite^［40］	Natural zeolite^［41］	Apricot stone^［42］
MB saturation adsorption/（mg·g^-1）	216.98	133.33	143.3	63.2	55.0

Fig.10 Effect of pH on adsorption of MB by TNTs-LA

References 43

1	NITHYA R， THIRUNAVUKKARASU A， SATHYA A， et al. Magnetic materials and magnetic separation of dyes from aqueous solutions： a review［J］. Environ Chem Lett， 2021， 19（2）： 1275-1294.
2	任南琪，周显娇，郭婉茜，等. 染料废水处理技术研究进展［J］. 化工学报， 2013（1）： 84-94.
	REN N Q， ZHOU X J， GUO W Q， et al. A review on treatment methods of dye wastewater［J］. CIESC J， 2013（1）： 84-94.
3	訾洛阳，丁志斌. 印染废水脱色研究进展［J］. 给水排水， 2008（S1）： 5.
	ZI L Y， DING Z B. Research progress on decolorization of printing and dyeing wastewater［J］. Water Wastewater Eng， 2008（S1）： 5.
4	袁思杰，张芮铭. 染料废水处理技术研究进展［J］. 染料与染色， 2022（4）： 59.
	YUAN S J， ZHANG R M. Research progress of dye wastewater treatment technology［J］. Dyestuffs Color， 2022（4）： 59.
5	孙怡. 高级氧化技术处理难降解有机废水的研发趋势及实用化进展［J］. 化工学报， 2017， 68（5）： 14.
	SU Y. Study on the adsorption properties of methylene blue dye on oat straw treated with different acids［J］. CIESC J， 2017， 68（5）： 14.
6	ES A， RE A， YK A， et al. Review on recent advances of carbon based adsorbent for methylene blue removal from waste water［J］. Mater Today Chem， 2020， 16： 100233.
7	SONG L， CAO L， LI J， et al. Lead titanate nanotubes synthesized via ion-exchange method： characteristics and formation mechanism［J］. J Alloy Compd， 2011， 509（20）： 6061-6066.
8	HINOJOSA-REYES M， CAMPOSECO-SOLIS R， RUIZ F. H₂Ti₃O₇ titanate nanotubes for highly effective adsorption of basic fuchsin dye for water purification［J］. Micropor Mesopor Mat， 2018， 276： 183-191.
9	LEE C K， LIU S S， JUANG L C， et al. Application of titanate nanotubes for dyes adsorptive removal from aqueous solution［J］. J Hazard Mater， 2007， 148（3）： 756-760.
10	LIU W， WANG T， BORTHWICK A G L， et al. Adsorption of Pb²⁺， Cd²⁺， Cu²⁺ and Cr³⁺ onto titanate nanotubes： competition and effect of inorganic ions［J］. Sci Total Environ， 2013， 456/457： 171-180.
11	LIU W， ZHAO X， WANG T， et al. Adsorption of U（Ⅵ） by multilayer titanate nanotubes： effects of inorganic cations， carbonate and natural organic matter［J］. Chem Eng J， 2016， 286： 427-435.
12	YANG D， SARINA S， ZHU H， et al. Capture of radioactive cesium and iodide ions from water by using titanate nanofibers and nanotubes［J］. Angew Chem Int Ed， 2011， 50（45）： 10594-10598.
13	JI H， WANG T， HUANG T， et al. Adsorptive removal of ciprofloxacin with different dissociated species onto titanate nanotubes［J］. J Clean Prod， 2021， 278： 123924.
14	XU X， LIU Y， WANG T， et al. Co-adsorption of ciprofloxacin and Cu（Ⅱ） onto titanate nanotubes： speciation variation and metal-organic complexation［J］. J Mol Liu， 2019， 292： 111375.
15	张兴堂，王玉梅，张春梅，等. 钛酸纳米管的化学修饰及发光性能的稳定化［J］. 中国科学， 2005， 35（5）： 372-377.
	ZHANG X T， WANG Y M， ZHANG C M， et al. Stablization of luminescent properties and chemical modification of titanate nanotubes［J］. Sci Sin Chim， 2005， 35（5）： 372-377.
16	GOTO T， CHO S H， OHTSUKI C， et al. Selective adsorption of dyes on TiO₂-modified hydroxyapatite photocatalysts morphologically controlled by solvothermal synthesis［J］. J Environ Chem Eng， 2021， 9（4）： 105738.
17	SKUBAL L R， MESHKOV N K， RAJH T， et al. Cadmium removal from water using thiolactic acid-modified titanium dioxide nanoparticles［J］. J Photochem Photobiol A： Chem， 2002， 148（1/2/3）： 393-397.
18	HABIBA U， JOO T C， SIDDIQUE T A， et al. Effect of degree of deacetylation of chitosan on adsorption capacity and reusability of chitosan/polyvinyl alcohol/TiO₂ nano composite［J］. Int J Biol Macromol， 2017， 104： 1133-1142.
19	LI J， FENG J， YAN W. Excellent adsorption and desorption characteristics of polypyrrole/TiO₂ composite for methylene blue［J］. App Surf Sci， 2013， 279： 400-408.
20	ZHANG Q， DENG Y X， LUO H， et al. Assembling a natural small molecule into a supramolecular network with high structural order and dynamic functions［J］. J Am Chem Soc， 2019， 141（32）： 12804-12814.
21	HUANG J， WRÓBLEWSKA A A， STEINKOENIG J， et al. Assembling lipoic acid and nanoclay into nacre-mimetic nanocomposites［J］. Macromolecules， 2021， 54（10）： 4658-4668.
22	JIN Z， SUGIYAMA Y， ZHANG C， et al. Rapid photoligation of gold nanocolloids with lipoic acid-based ligands［J］. Chem Mater， 2020， 32（17）： 7469-7483.
23	ZHANG Q， DENG Y， SHI C Y， et al. Dual closed-loop chemical recycling of synthetic polymers by intrinsically reconfigurable poly（disulfides）［J］. Matter， 2021， 4（4）： 1352-1364.
24	吴磊，张宇辉，司杨. 不同酸处理燕麦秸秆对亚甲基蓝染料的吸附性能研究［J］. 青海大学学报， 2022， 40（3）： 1-6.
	WU L， ZHANG Y H， SI Y. Study on the adsorption properties of methylene blue dye on oat straw treated with different acids［J］. J Qinghai Univ， 2022， 40（3）： 1-6.
25	WANG Q， LEI X， PAN F， et al. A new type of activated carbon fibre supported titanate nanotubes for high-capacity adsorption and degradation of methylene blue［J］. Colloids Surf A， 2018， 555： 605-614.
26	HEZARJARIBI M， BAKERI G， SILLANP M， et al. Novel adsorptive PVC nanofibrous/thiol-functionalized TNT composite UF membranes for effective dynamic removal of heavy metal ions［J］. J Environ Manage， 2021， 284： 111996.
27	BADRUDDOZA A Z M， TAY A S H， TAN P Y， et al. Carboxymethyl-β-cyclodextrin conjugated magnetic nanoparticles as nano-adsorbents for removal of copper ions： synthesis and adsorption studies［J］. J Hazard Mater， 2011， 185（2/3）： 1177-1186.
28	ZHANG Y， LU D， KONDAMAREDDY K K， et al. Controllable preparation and efficient visible-light-driven photocatalytic removal of Cr（Ⅵ） using optimized Cd_0.5Zn_0.5S nanoparticles decorated H-titanate nanotubes［J］. Adv Powder Technol， 2021， 32（10）： 3788-3800.
29	KAMRAN U， PARK S J. Functionalized titanate nanotubes for efficient lithium adsorption and recovery from aqueous media-science direct［J］. J Solid State Chem， 2020， 283： 121157.
30	LIU W， CAI Z， ZHAO X， et al. High-capacity and photoregenerable composite material for efficient adsorption and degradation of phenanthrene in water［J］. Environ Sci Technol， 2016， 50（20）： 11174-11183.
31	SUN W L， XIA J， LI S， et al. Effect of natural organic matter （NOM） on Cu（Ⅱ） adsorption by multi-walled carbon nanotubes： relationship with NOM properties［J］. Chem Eng J， 2012， 200： 627-636.
32	敖航. 硫醇稳定金纳米簇的可控制备，发光性质及传感应用研究［D］. 金华：浙江师范大学， 2018.
	AO H. Controllable fabrication， luminescence properties and sensing applications of thiolate-protected gold nanoclusters［D］. Jinhua： Zhejiang Normal University， 2018.
33	温俊峰，刘侠，马向荣，等. 沙柳基磁性多孔炭的制备及其吸附亚甲基蓝性能研究［J］. 功能材料， 2021， 52（4）： 8.
	WEN J F， LIU X， MA X R， et al. Preparation of magnetic porous carbon from Salix and adsorption properties for methylene blue［J］. J Funct Mater， 2021， 52（4）： 8.
34	LAGERGREN S. Zur theorie der sogenannten adsorption geloster stoffe［J］. Kungliga Svenska Vetenskapsakademiens. Handlingar， 1898， 24： 1-39.
35	HO Y S， MCKAY G. Sorption of dye from aqueous solution by peat［J］. Chem Eng J， 1998， 70（2）： 115-124.
36	SIMONIN J P. On the comparison of pseudo-first order and pseudo-second order rate laws in the modeling of adsorption kinetics［J］. Chem Eng J， 2016， 300： 254-263.
37	王晶，韩巧宁，雷以廷，等. 一步法制备富氧木质素活性炭及其亚甲基蓝吸附性能［J］. 化工学报， 2021， 72（5）： 2826-2836.
	WANG J， HANG Q N， LEI Y T， et al. One-step preparation of oxygen-enriched lignin activated carbon and its methylene blue adsorption performance［J］. CIESC J， 2021， 72（5）： 2826-2836.
38	曹从军，马含笑，侯成敏，等. 乙基纤维素磁性复合材料对溶液中铜离子的吸附性能［J］. 应用化学， 2022， 39（6）： 969-979.
	CAO C J， MA H X， HOU C M， et al. Adsorption of Cu（Ⅱ） from solution by modified magnetic ethyl cellulose［J］. Chin J Appl Chem， 2022， 39（6）： 969-979.
39	董川，马骏，刘宏芳，等. 钛酸纳米管/活性炭复合材料对水体中铅和亚甲基蓝的吸附［J］. 山西大学学报：自然科学版， 2017， 40（3）： 569-576.
	DONG C， MA J， LIU H F， et al. Titanate nanotubes/activated carbon composite material for the adsorption of lead and methylene blue in water［J］. J Shanxi Univ （Nat Sci Ed）， 2017， 40（3）： 569-576.
40	AL-GHOUTI M A， KHRAISHEH M A M， AHMAD M N M， et al. Adsorption behaviour of methylene blue onto Jordanian diatomite： a kinetic study［J］. J Hazard Mater， 2009， 165（1/2/3）： 589-598.
41	MOUNI L， MERABET D， BOUZAZA A， et al. Adsorption of Pb（Ⅱ） from aqueous solutions using activated carbon developed from Apricot stone［J］. Desalination， 2011， 276（1/2/3）： 148-153.
42	HAN R， ZHANG J， HAN P， et al. Study of equilibrium， kinetic and thermodynamic parameters about methylene blue adsorption onto natural zeolite［J］. Chem Eng J， 2009， 145（3）： 496-504.
43	杨权成，张开永，郭德，等. 介孔硅酸钙吸附亚甲基蓝性能研究［J］. 无机盐工业， 2021， 53（10）： 86-91.
	YANG Q C， ZHANG K Y， GUO D， et al. Research on adsorption properties of methylene blue by mesoporous calcium silicate ［J］. Inorg Chem Ind， 2021， 53（10）： 86-91.

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Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid

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