Controllable Construction of Porous Nanocube FeSe2/Graphene Composite for Efficient Na⁃Ion Storage

doi:10.19894/j.issn.1000-0518.210141

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (5): 779-786.DOI: 10.19894/j.issn.1000-0518.210141

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Controllable Construction of Porous Nanocube FeSe₂/Graphene Composite for Efficient Na⁃Ion Storage

Fu-Yang WANG¹, Wei-Ming SONG¹(), Li SUN¹, Jian FENG², Jun YE¹, Zhi-Qi YANG¹

^1.School of Chemistry and Chemical Engineering，Qiqihar University，Qiqihar 161006，China
^2.School of Materials Science and Engineering，Northeastern University，Shenyang 110819，China

Received:2021-03-24 Accepted:2021-07-28 Published:2022-05-01 Online:2022-05-24
Contact: Wei-Ming SONG
About author:qdsongweiming@163.com
Supported by:
the Basic Scientific Research Business Expenses of Provincial Colleges and Universities in Heilongjiang Province(135109102);Qiqihar University Postgraduate Innovation Research Project(YJSCX2019038)

Abstract

Abstract:

The design of anode materials with higher specific capacity and cycle stability is very important for the development of sodium ion batteries. Transition metal selenide has become a potential anode electrode material because of its higher theoretical capacity. However， selenide has a low conductivity and a large volume expansion occurs during the insertion/extraction of sodium ions， resulting in a rapid decrease in specific capacity. Therefore， structural control is particularly important. The FeSe₂/rGO composite material with more active sites and more stable structure was prepared by conventional hydrothermal method to grow porous nanocube FeSe₂in situ on two-dimensional reduced graphene oxide（rGO）. When used as an anode material for Sodium ion battery（SIBs）， the FeSe₂/rGO electrode has excellent rate capacity of 694.6 mA?h/g at 0.2 A/g， and high reversible capacity of 300.0 mA?h/g at 2.0 A/g after 300 cycles.

Key words: FeSe₂/rGO, Sandwich structure, Sodium ion batteries, Anode material

CLC Number:

O646

Fu-Yang WANG, Wei-Ming SONG, Li SUN, Jian FENG, Jun YE, Zhi-Qi YANG. Controllable Construction of Porous Nanocube FeSe₂/Graphene Composite for Efficient Na⁃Ion Storage[J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 779-786.

Figures/Tables 6

Fig.1 （A， B） SEM images of Fe-PBA/rGO with different magnifications；（C，D） SEM images of Fe-PBA；（E） TEM image of Fe-PBA/rGO；（F） TEM image of Fe-PBA

Fig.2 （A， B） SEM images of FeSe2/rGO with different magnifications；（C） SEM images of FeSe2@NC；（D） TEM image of FeSe2/rGO；（E） TEM image of FeSe2@NC；（F） EDS elemental mapping of FeSe2/rGO nanocomposites

Fig.3 （A） XRD pattern of FeSe2/rGO and FeSe2@NC，（B） N2 adsorption/desorption isotherms and pore size distributions （inset） of FeSe2/rGO

Fig.4 XPS survey spectra （A）， and high-resolution spectra of Fe2p （B），Se3d （C），N1s （D） for FeSe2/rGO nanocomposite

Fig.5 （A） Cyclic voltammogram for initial five cycles at 0.1 mV/s and （B） galvanostatic discharge-charge curves of FeSe2/rGO electrodes at 0.2 A/g；（C） The rate properties of FeSe2@NC， FeSe2/rGO；（D） Cycle performance of FeSe2@NC and FeSe2/rGO electrodes at 2.0 A/g

Fig.6 （A） The Electrochemical impedance and （B） ionic conductivity of FeSe2 and FeSe2/rGO electrode materials

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Controllable Construction of Porous Nanocube FeSe₂/Graphene Composite for Efficient Na⁃Ion Storage

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