Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (5): 697-706.DOI: 10.19894/j.issn.1000-0518.210129
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Lin-Hu SONG1,2, Shi-You LI1,2,3(), Jie WANG1,2, Jing-Jing ZHANG1,2, Ning-Shuang ZHANG1,2,3, Dong-Ni ZHAO1,2,3, Fei XU1,2
Received:
2021-03-19
Accepted:
2021-08-24
Published:
2022-05-01
Online:
2022-05-24
Contact:
Shi-You LI
About author:
lishiyoulw@163.comSupported by:
CLC Number:
Lin-Hu SONG, Shi-You LI, Jie WANG, Jing-Jing ZHANG, Ning-Shuang ZHANG, Dong-Ni ZHAO, Fei XU. Research Progress of Additives for Acid and Water Removal in Electrolyte of Lithium Ion Battery[J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 697-706.
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URL: http://yyhx.ciac.jl.cn/EN/10.19894/j.issn.1000-0518.210129
Fig.2 The action mechanisms of various additives to remove HF and H2O: (A) Mechanism of PTSI to remove HF[8], (B) Mechanism of DPDMS to remove HF and H2O[9], (C) Mechanism of DODSi to remove HF[11], (D) Mechanism of APTS to remove HF[12], (E) Mechanism of HMDS to remove HF and H2O[25,28], (F) Mechanism of TMSP to remove HF[33], and (G) Mechanism of 1-TMSI to remove HF and H2O[34]
Fig.3 (a) Initial charge/discharge capacities, and (b) Charge capacity retention of Li/MCMB cells that are tested in the electrolytes without and with 1-TMSI additive[34]
Fig.4 Mechanism of new additives to remove HF and H2O: (A) Mechanism of action of DMF and PF5[13],(B) Mechanism of TMS?ON to remove HF and H2O[15], (C) Mechanism of TPP to remove HF and H2O[16]
添加剂 Additive | 特点 Characteristics | 不足 Insufficiencies |
---|---|---|
异氰酸酯(—NCO)基化合物 Isocyanate (—NCO)-based compounds | —NCO中的N原子与H原子结合形成络合物,不仅清除了副产物HF和PF5,还参与生成优良的界面膜 The N atoms in —NCO combine with H atoms to form complexes, which not only remove the by-products HF and PF5, but also participate in the formation of the excellent interfacial film | 该化合物作为添加剂在电解液中除杂的研究较少,机理仍需进一步探究 There's not a lot of research on using these compounds as additives to remove impurities in the electrolyte, and the mechanism still needs to be further explored |
硅烷类(Si—O)化合物 Silane (Si—O) compounds | Si—O烷基属于碱类化合物,可与H+结合,除去电解液中酸性杂质,并且Si对F较高的亲和力可清除分离出的F-,同时参与SEI膜的构建 Si—O alkyl can be combined with H+ to remove acidic impurities in electrolyte, due to its basic functional groups, and the separated F can be removed by Si with higher affinity to F-,participating in the construction of SEI film | Si—O与杂质反应生产络合物参与SEI膜的构建机理目前还不明确,仍需进一步研究 The mechanism of Si—O reacting with impurities to produce complexes and participating in the construction of SEI film is still unclear, and further research is needed |
新型化合物添加剂 Other new compound additives | 在极端环境下(如高温高压),亲F-或亲H+型添加剂自身可清除电解液中的HF杂质 The additives can remove HF impurities in the electrolyte by their affinity with F- or H+ under extreme environments (such as high temperature and high potential) | 高温高压条件易导致电解液分解产生其它杂质,故在该环境下研究除酸、除水型添加剂较为困难 Electrolyte is easy to decompose to produce other impurities at high temperature and potential, so it is difficult to study acid and water removing additives under this condition |
Table 1 Characteristics of various acid?removing and water?removing additives
添加剂 Additive | 特点 Characteristics | 不足 Insufficiencies |
---|---|---|
异氰酸酯(—NCO)基化合物 Isocyanate (—NCO)-based compounds | —NCO中的N原子与H原子结合形成络合物,不仅清除了副产物HF和PF5,还参与生成优良的界面膜 The N atoms in —NCO combine with H atoms to form complexes, which not only remove the by-products HF and PF5, but also participate in the formation of the excellent interfacial film | 该化合物作为添加剂在电解液中除杂的研究较少,机理仍需进一步探究 There's not a lot of research on using these compounds as additives to remove impurities in the electrolyte, and the mechanism still needs to be further explored |
硅烷类(Si—O)化合物 Silane (Si—O) compounds | Si—O烷基属于碱类化合物,可与H+结合,除去电解液中酸性杂质,并且Si对F较高的亲和力可清除分离出的F-,同时参与SEI膜的构建 Si—O alkyl can be combined with H+ to remove acidic impurities in electrolyte, due to its basic functional groups, and the separated F can be removed by Si with higher affinity to F-,participating in the construction of SEI film | Si—O与杂质反应生产络合物参与SEI膜的构建机理目前还不明确,仍需进一步研究 The mechanism of Si—O reacting with impurities to produce complexes and participating in the construction of SEI film is still unclear, and further research is needed |
新型化合物添加剂 Other new compound additives | 在极端环境下(如高温高压),亲F-或亲H+型添加剂自身可清除电解液中的HF杂质 The additives can remove HF impurities in the electrolyte by their affinity with F- or H+ under extreme environments (such as high temperature and high potential) | 高温高压条件易导致电解液分解产生其它杂质,故在该环境下研究除酸、除水型添加剂较为困难 Electrolyte is easy to decompose to produce other impurities at high temperature and potential, so it is difficult to study acid and water removing additives under this condition |
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