A Fluorescent Magnesium-Based Metal-Organic Framework with a Sensitive Sensing Property for Carbon Disulfide

doi:10.11944/j.issn.1000-0518.2017.09.170189

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (9): 1059-1065.DOI: 10.11944/j.issn.1000-0518.2017.09.170189

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A Fluorescent Magnesium-Based Metal-Organic Framework with a Sensitive Sensing Property for Carbon Disulfide

GONG Liaokuo^a^b,SONG Ying^a,SHEN Nannan^a^b,ZHANG Bo^a^b,WU Zhaofeng^a^*(),HUANG Xiaoying^a^*()

^aState Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou 350002,China
^bUniversity of Chinese Academy of Sciences,Beijing 100049,China

Received:2017-06-01 Accepted:2017-06-22 Published:2017-08-31 Online:2017-08-31
Contact: WU Zhaofeng,HUANG Xiaoying
Supported by:
Supported by the National Natural Science Foundation of China(No.21403233), the 973 Program(No.2014CB845603)

Abstract

Abstract:

Presented here are the solvothermal synthesis, structural characterization and fluorescent properties of a magnesium metal-organic framework(Mg-MOF), namely [Mg₄(1,4-NDC)₄(DMA)₂(CH₃OH)₂(H₂O)₂]·DMA·CH₃OH(1, 1,4-H₂NDC=1,4-naphthalene dicarboxylic acid, DMA=N,N'-Dimethylacetamide). Single-crystal X-ray diffraction studies revealed that compound 1 crystallized in the monoclinic space group P2₁/c(No.14) with a=2.06090(12) nm, b=2.21014(13) nm, c=1.50385(10) nm, β=111.399(3)°, V=6.3776(7) nm³, Z=4, D_c=1.403 g/cm³, F(000)=2824, R=0.0596 and wR=0.1225(I>2σ(I)). The structure of compound 1 features a three-dimensional(3D) network constructed from the 1,4-NDC ligands as bridging linkers and binuclear magnesium clusters as the secondary building units, with cages occupied by different solvent molecules of DMA and CH₃OH. Notably, fluorescence studies revealed that compound 1 demonstrated sensitive sensing towards carbon disulfide(CS₂); remarkably, the fluorescence intensity of compound 1 could be almost completely quenched at the low concentration of 0.4%(volume fraction) of CS₂. Thermal stability was investigated by thermogravimetric analysis which indicated that compound 1 could be stable up to 140 ℃.

Key words: magnesium, metal-organic framework, fluorescence sensor, carbon disulfide

GONG Liaokuo, SONG Ying, SHEN Nannan, ZHANG Bo, WU Zhaofeng, HUANG Xiaoying. A Fluorescent Magnesium-Based Metal-Organic Framework with a Sensitive Sensing Property for Carbon Disulfide[J]. Chinese Journal of Applied Chemistry, 2017, 34(9): 1059-1065.

References

[1]	Chuang W L,Huang C C,Chen C J,et al.Carbon Disulfide Encephalopathy:Cerebral Microangiopathy[J]. Neurotoxicology,2007,28(2):387-393.
[2]	Wang S,Irving G,Jiang L L,et al.Oxidative Stress Mediated Hippocampal Neuron Apoptosis Participated in Carbon Disulfide-Induced Rats Cognitive Dysfunction[J]. Neurochem Res,2017,42(2):583-594.
[3]	Ciaffoni L,Peverall R, Ritchie G A D. Laser Spectroscopy on Volatile Sulfur Compounds:Possibilities for Breath Analysis[J]. J Breath Res,2011,5(2):024002.
[4]	Furton K G,Myers L J. The Scientific Foundation and Efficacy of the Use of Canines as Chemical Detectors for Explosives[J]. Talanta,2001,54(3):487-500.
[5]	Lu W,Xiao P,Liu Z Z,et al.Reaction-Driven Self-Assembled Micellar Nanoprobes for Ratiometric Fluorescence Detection of CS2 with High Selectivity and Sensitivity[J]. ACS Appl Mater Interfaces,2016,8(31):20100-20109.
[6]	Zhang R K,Li G K,Hu Y F. Simple and Excellent Selective Chemiluminescence-Based CS2 On-Line Detection System for Rapid Analysis of Sulfur-Containing Compounds in Complex Samples[J]. Anal Chem,2015,87(11):5649-5655.
[7]	Heine J,Muller-Buschbaum K. Engineering Metal-Based Luminescence in Coordination Polymers and Metal-Organic Frameworks[J]. Chem Soc Rev,2013,42(24):9232-9242.
[8]	Hu Z C,Deibert B J,Li J. Luminescent Metal-Organic Frameworks for Chemical Sensing and Explosive Detection[J]. Chem Soc Rev,2014,43(16):5815-5840.
[9]	Banerjee D,Hu Z C,Li J. Luminescent Metal-Organic Frameworks as Explosive Sensors[J]. Dalton Trans,2014,43(28):10668-10685.
[10]	Kreno L E,Leong K,Farha O K,et al.Metal-Organic Framework Materials as Chemical Sensors[J]. Chem Rev,2012,112(2):1105-1125.
[11]	Cui Y J,Yue Y F,Qian G D,et al.Luminescent Functional Metal-Organic Frameworks[J]. Chem Rev,2012,112(2):1126-1162.
[12]	Meyer L V,Schoenfeld F,Zurawski A,et al. A Blue Luminescent MOF as a Rapid Turn-Off/Turn-On Detector for H2O, O-2 and CH2Cl2, MeCN:3∞Ce(Im)3ImH·ImH[J]. Dalton Trans, 2015, 44(9):4070-4079.
[13]	Xu F,Wang H,Teat S J,et al.Synthesis, Structure and Enhanced Photoluminescence Properties of Two Robust, Water Stable Calcium and Magnesium Coordination Networks[J]. Dalton Trans,2015,44(47):20459-20463.
[14]	Jayaramulu K,Kanoo P,George S J,et al.Tunable Emission From a Porous Metal-Organic Framework by Employing an Excited-State Intramolecular Proton Transfer Responsive Ligand[J]. Chem Commun,2010,46(42):7906-7908.
[15]	Brown J W,Henderson B L,Kiesz M D,et al.Photophysical Pore Control in an Azobenzene-Containing Metal-Organic Framework[J]. Chem Sci,2013,4(7):2858-2864.
[16]	Wu Z F,Tan B,Feng M L,et al.A Magnesium-Carboxylate Framework Showing Luminescent Sensing for CS2 and Nitroaromatic Compounds[J]. J Solid State Chem,2015,223:59-64.
[17]	Wu Z F,Tan B,Feng M L,et al.A Magnesium MOF as a Sensitive Fluorescence Sensor for CS2 and Nitroaromatic Compounds[J]. J Mater Chem A,2014,2(18):6426-6431.
[18]	Douvali A,Tsipis A C,Eliseeva S V,et al.Turn-On Luminescence Sensing and Real-Time Detection of Traces of Water in Organic Solvents by a Flexible Metal-Organic Framework[J]. Angew Chem Int Ed,2015,54(5):1651-1656.
[19]	Sheldrick G M. Crystal Structure Refinement with SHELXL[J]. Acta Crystallogr,2015,71:3-8.
[20]	Zhai Q G,Lin Q P,Wu T Z,et al.Induction of Trimeric [Mg3(OH)(CO2)6] in a Porous Framework by a Desymmetrized Tritopic Ligand[J]. Dalton Trans,2012,41(10):2866-2868.
[21]	Guo Z Y,Li G H,Zhou L,et al.Magnesium-based 3D Metal-Organic Framework Exhibiting Hydrogen-Sorption Hysteresis[J]. Inorg Chem,2009,48(17):8069-8071.
[22]	Zhai Q G,Bu X,Zhao X,et al.Advancing Magnesium-Organic Porous Materials Through New Magnesium Cluster Chemistry[J]. Cryst Growth Des,2016,16(3):1261-1267.
[23]	Rood J A,Noll B C,Henderson K W. Synthesis, Structural Characterization, Gas Sorption and Guest-Exchange Studies of the Lightweight, Porous Metal-Organic Framework Alpha-[Mg3(O2CH)6][J]. Inorg Chem,2006,45(14):5521-5528.
[24]	Lakowicz J R. Principles of Fluorescence Spectroscopy[M]. New York:Plenum Press,1983:260-266.

A Fluorescent Magnesium-Based Metal-Organic Framework with a Sensitive Sensing Property for Carbon Disulfide

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