Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (3): 301-306.DOI: 10.11944/j.issn.1000-0518.2020.03.190225

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Preparation and Properties of Superhydrophobic and Flame-Retardant Cotton Fabric

JI Wanliab*(),ZHONG Shaofenga,YU Xuemana   

  1. a Department of Jianhu, Zhejiang Industry Polytechnic College,Shaoxing,Zhejiang 31200,China
    b School of Light Industrial and Engineering,Shaanxi University of Science & Technology,Xi'an 710021,China
  • Received:2019-08-12 Accepted:2019-11-19 Published:2020-03-01 Online:2020-03-10
  • Contact: JI Wanli
  • Supported by:
    Supported by Zhejiang Industrial Polytechnic College Project (No. 20170283), Shaoxing Key Innovation Team(No.222709010920717004), and Shaanxi University of Science and Technology(No.BJ08?18)

Abstract:

Magnesium hydroxide (Mg(OH)2) was incorporated into cotton fiber to build surface roughness and improve flame-retardancy of cotton fabric. Subsequently, flame-retardant and superhydrophobic cotton fabric was prepared by further dip-coating of cotton fabric with polydimethylsiloxane (PDMS) solution. Fourier transform infrared spectrometer (FTIR) and scanning electronic microscopy (SEM) analysis confirmed that the pristine cotton fabrics is successfully modified by Mg(OH)2 and PDMS. The hydrophobicity, thermal stability, flame retardant and durability of the treated cotton fibers were tested. The results indicated that Mg(OH)2 is loaded on the fabric, which makes the surface of the pristine cotton to have a certain micro-nano structure and forms a rough coating. When the concentration of Mg(OH)2 was 1.0 mol/L, Mg(OH)2/PDMS coated fabric had contact angle (CA) of 158°, the limit oxygen index(LOI) of 24.5%, and the thermal conductivity of 0.0305 W/(m·K), suggesting excellent superhydrophobicity and flame-retardant performance. After 20 times of washing, 100 times of friction and under extreme processing conditions for coated fabric, its CA was greater than 150°, its LOI value was higher than 23%, revealing that the coated fabric has an excellent durability.

Key words: magnesium hydroxide, fabric coating, hydrophobicity, flame retardant property, cotton fabric