Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature

doi:10.11944/j.issn.1000-0518.2016.02.150223

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (2): 175-180.DOI: 10.11944/j.issn.1000-0518.2016.02.150223

• Full Papers • Previous Articles Next Articles

Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature

HU Sanming^a,WEI Wei^b,YANG Tianbo^c,ZHENG Changmei^b^*(),ZHENG Chunbai^b^*(),DENG Pengyang^b

^aWuhan Wuchuan Electromechanical Equipment Company,Wuhan 430000,China
^bChangchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China
^cJilin University,Changchun 130025,China

Received:2015-07-01 Accepted:2015-11-17 Published:2016-02-01 Online:2016-02-01
Contact: ZHENG Changmei,ZHENG Chunbai
Supported by:
Supported by Science and Technology Cooperation Project of Hubei Province and Chinese Academy of Sciences, Wuhan Wuchuan Electromechanical Equipment Company Assist Project(No.110000Y129)

Abstract

Abstract:

Bisphenol-A epoxy resin E-51 was cured by [C₆mim]FeCl₄ and mixed amines at room temperature(20 ℃). Compared to other E-51 systems which were cured by aliphatic amine, E-51 systems cured by [C₆mim]FeCl₄/mixed amine have better mechanical properties, thermal properties, and aging properties. The effect of the amount of [C₆mim]FeCl₄ on the properties of the cured epoxy resin systems was also investigated. Tensile strength of the [C₆mim]FeCl₄/mixed amine cured E-51 system reaches 90 MPa, and the system maintains its excellent mechanical properties at high temperature(120 ℃). The TGA result shows that the decomposition temperature is 310 ℃ when the mass loss of epoxy system reaches 5%. Even after 7 days aging at 200 ℃, the tensile strength of the [C₆mim]FeCl₄/mixed amine cured epoxy resin system is 28 MPa. Therefore, the [C₆mim]FeCl₄/mixed amine cured epoxy resin system is a new type of epoxy resin cured system which can be applied under high temperature.

Key words: hexyl-methylimidazole iron tetrachloride, bisphenol-a epoxy resin, room temperature curing agent, properties

HU Sanming, WEI Wei, YANG Tianbo, ZHENG Changmei, ZHENG Chunbai, DENG Pengyang. Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature[J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 175-180.

References

[1]	SUN Manling,WU Liangyi. Application of The Principles and Techniques of Epoxy Resin[M]. Beijing:China Machine Press,2002:4-8(in Chinese). 孙曼灵,吴良义. 环氧树脂应用原理及技术[M]. 北京:机械工业出版社,2002:4-8.
[2]	CHEN Ping,LIU Shengping,WANG Dezhong. Epoxy Resin and Its Application[M]. BeiJing:Chemical Industry Press,2011:1-5(in Chinese). 陈平,刘胜平,王德中.环氧树脂及其应用[M]. 北京:化学工业出版社,2011:1-5.
[3]	SONG Junjun,ZHANG Jun. The Room Temperature Fast Curing Epoxy Adhesive Development Present Situation[J]. Heilongjiang Sci,2013,4(1):40-42(in Chinese). 宋军军,张君. 室温快速固化环氧胶黏剂的发展现状[J]. 黑龙江科学,2013,4(1):40-42.
[4]	WU Yanfei,HUANG Ying. Research Progress of Room Temperature Cured Heat-Resistant Adhesive[J]. Mater Develop Appl,2010,6:88-93(in Chinese). 吴燕飞,黄英. 室温固化耐温胶黏剂研究进展[J]. 材料开发与应用,2010,6:88-93.
[5]	DUAN Huajun,ZHANG Lianmeng,WANG Jun,et al.Study on the Properties of the Low Viscosity, Low Heat Liberation and High Toughening Curing Agent for Epoxy Resin[J]. Insulat Mater,2007,40(6):1-4(in Chinese). 段华军,张联盟,王均,等. 低放热、低粘度、高韧性环氧树脂室温固化剂的性能研究[J]. 绝缘材料,2007,40(6):1-4.
[6]	GONG Yunjin. Preparing TG301 Epoxy Resin Room Temperature Curing Agent with Modifed Hexanediamine[J]. China Adhes,1999,4(1):35-38(in Chinese). 龚云金. 改性己二胺制备TG301环氧树脂室温固化剂[J]. 中国胶黏剂,1999,4(1):35-38.
[7]	WANG Zhongyi,ZHANG Lianhong. Synthesis of Epoxy Resin Fast Curing Agent at Room Temperature[J]. Synth Resin Plast,2013,30(3):25-30(in Chinese). 王钟熠,张连红. 环氧树脂室温快速固化剂的合成[J]. 合成树脂及塑料,2013,30(3):25-30.
[8]	Dodiuk H,Kenig S,Liran I. Room Temperature Curing Epoxy Adhesives for Elevated Temperature Service[J]. J Adhes,1987,22(3):227-251.
[9]	ZHANG Xiaobo,LIU Haiping. Study on Synthesis and Performance of Flexible Curing Agent for Room Temperature Curing Epoxy Resin Adhesive[J]. China Adhes,2008,17(5):1-4(in Chinese). 张小博,刘海萍. 环氧树脂室温固化用柔性固化剂的制备与性能研究[J]. 中国胶黏剂,2008,17(5):1-4.
[10]	XIA Lanjun,LI Fuzhi,XIONG Hejian,et al.Performance of Silicone Modified Epoxy Resin Curable at Room Temperature[J]. Adhesion,2013,4(54):1-5(in Chinese). 夏兰君,李福志,熊和建,等. 有机硅改性环氧树脂及其室温固化的性能研究[J]. 粘接,2013,4(54):1-5.
[11]	LI Xiaohua,YANG Fuming,ZHOU Qing,et al.Synthesis and Properties of 1-Methyl-3-Alkylimnida-zolium Tetrahalogenoferrate Magnetic Ionic Liquids[J]. Process Eng J,2010,10(4):789-794(in Chinese). 李小华,杨富明,周清,等. 磁性离子液体1-甲基-3-烷基咪唑四氯化铁盐的合成及其物性表征[J]. 过程工程学报,2010,10(4):789-794.
[12]	MA Yuqin, WEI wei, ZHENG Changmei, et al. Reaction Characteristics of Epoxy Resins E-51 Cured by 1-Hexyl-3-methyl Imidazole Iron Tetrachloride Salt[J]. Chinese J Appl Chem,2015,32(6):636-640(in Chinese). 马玉芹,魏巍,郑昌梅,等. 1-己基-3-甲基咪唑四氯化铁盐固化环氧树脂E-51的反应特性[J]. 应用化学,2015,32(6):636-640.

[1]	Jia-Cheng ZHOU, Dong-Dong WANG, Yun-Bao GAO, Jing JIN, Wei JIANG. Rheological Properties and Bonding Properties of Modified Poly（Propylene Carbonate） Pressure-sensitive Adhesive [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 871-878.
[2]	Yu-Zhu CHEN, Si-Si LIU, Meng-Meng ZHANG, Xiang-De LIN, Dong-Dong ZENG. Polyurethane Dressing Based on Antibacterial Chitosan/Carboxymethyl Cellulose Composite Drug Coating [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 252-260.
[3]	Yu-Hua XIONG, Lei ZHOU, Shi-Zhong YANG, Bo-Zhong MU. Enzymatic Properties and Gel Breaking Performance of Low-temperature β-Mannanase [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 134-145.
[4]	Dan ZHANG, Fang LIU, Xue YANG, Dong-Hua XU, Tong-Fei SHI. Relationship Between Hardness and Impact Properties of Thermoplastic Polyurethane Blends [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1216-1223.
[5]	Mei-Lun ZHANG, Hong-Ran LING, Zai-Chun SUN, Bing-Chu MEI, Wei-Wei LI. Research Progress on the Preparation Methods of BaMgF₄ Powders [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 900-911.
[6]	Jing-Wan LIU, Qiong LI, Tao ZHANG, En-Peng WANG, Huan WANG, Xue CHEN, Chang-Bao CHEN. Research Progress on the Continuous Cropping Obstacles of Ginseng from Soil Improvement [J]. Chinese Journal of Applied Chemistry, 2022, 39(12): 1818-1832.
[7]	Yong-Xin TANG, Li-Wu NIE. Effect of Epoxy Resin Content on the Performance of Luminous Resin Permeable Concrete [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1665-1671.
[8]	Dan MENG, Kai-Yuan ZHENG, Shan-Shan CHEN, Zhao-Long ZHUO, Li-Li WANG. Preparation and Luminescence Properties of Silicon and Nitrogen Co⁃doped Carbon Dots Phosphors [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1766-1773.
[9]	Yu-Fang SHI, Ying-Jin WANG, Jin-Yu SUN, Ming-Gen ZHAO. Synthesis, Characterization, Photothermal Properties of Dichalcone Containing Polymethoxy Aromatic Group [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 235-240.
[10]	Chun-Mei ZHAO, Xiu-Miao ZHOU, Xi-Xi JIN, Yu-Hang WANG, Yi-Jing DANG. Preparation of Saddle-Shaped Cyclooctatetrathiophene-Based Hybrid Nanomaterials and Fluorescence Properties [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 283-288.
[11]	JI Quan-Zeng, MENG Jun-Ling , WANG Hao-Cong , AN Tao , LIU Xiao-Juan, MENG Jian. Phase Transformation of La₂CuO₄ Cathode Film and Its Influence on Electrochemical Properties [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 976-985.
[12]	JI Quan-Zeng, MENG Jun-Ling , WANG Hao-Cong , AN Tao , LIU Xiao-Juan, MENG Jian. Phase Transformation of La₂CuO₄ Cathode Film and Its Influence on Electrochemical Properties [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 0-0.
[13]	ZHU Meng-Meng, BAI Jue-Yao, CHEN Ren-Jie, LI Hui-Li. Synthesis and Properties of B-Site Doped All-Inorganic Perovskite Quantum Dots [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1541-1555.
[14]	Wei HONG, Li-Quan WANG, Jia-Ping LIN. Research Progress of Polymeric Hierarchical Microstructures and Their Properties [J]. Chinese Journal of Applied Chemistry, 2021, 38(10): 1310-1325.
[15]	CHEN Songhua, CHEN Xin, LIU Yongqi, HE Meiyun, FU Shanshan, PENG Li, YANG Jien. Self-assembly and Luminescence Properties of Intramolecular Charge Transfer Compound of Carbazole Derivatives [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1022-1029.

Properties of a New Type Heat-Resistant System of Epoxy Resin Cured at Room Temperature

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments