Preparation and Properties of Ionic Liquid and Ethylene-Vinyl Acetate Copolymer Composites

doi:10.11944/j.issn.1000-0518.2015.10.150095

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (10): 1146-1152.DOI: 10.11944/j.issn.1000-0518.2015.10.150095

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Preparation and Properties of Ionic Liquid and Ethylene-Vinyl Acetate Copolymer Composites

JIN Mingyue^a^b,FU Luxiang^b,YOU Jichun^a,Li Yongjin^a^*()

^aCollege of Materials,Chemistry and Chemical Engineering,Hangzhou Normal University,Hangzhou 310036,China
^bResearch Center of Plastic Engineering,School of Materials Science and Engineering,Shenyang University of Chemical Technology,Shenyang 110142,China

Received:2015-03-12 Accepted:2015-07-13 Published:2015-10-10 Online:2015-10-10
Contact: Li Yongjin
Supported by:
Supported by the National Natural Science Foundation of China(No.21074029)

Abstract

Abstract:

Two binary blends of tributylmethylammoniu bis(trifluoromethanesulfonyl)imide([TBMA][NTf₂]) and ethylene-vinyl acetate copolymer(EVM), 1-butyl-3-methyl-imidazolium tetrafluoroborate([EMIM][BF₄]) and EVM were prepared by melt blending. The blend of EVM and [TBMA][NTf₂] is fully miscible and shows better anti-static electricity, while the blend of EVM and [BMIMBF₄] is immiscible. In addition, TGA analysis indicated that [TBMA][NTf₂] promoted EVM pyrogenation, while [EMIM][BF₄] had little influence on the thermal stability of EVM. EVM filled with [TBMA][NTf₂] is flexible at room temperature. The modulus of EVM/[TBMA][NTf₂] composite is 0.58 MPa and the elongation at break is as high as 2997% with 20% mass fraction loading of ionic liquids.

Key words: ionic liquids, ethylene-vinyl acetate copolymer elastomer, compatibility, thermal stability, anti-static electricity

JIN Mingyue,FU Luxiang,YOU Jichun,Li Yongjin. Preparation and Properties of Ionic Liquid and Ethylene-Vinyl Acetate Copolymer Composites[J]. Chinese Journal of Applied Chemistry, 2015, 32(10): 1146-1152.

References

[1]	Huddleston J G,Visser A E,Reichert W M,et al.Characterization and Comparison of Hydrophilic and Hydrophobic Room Temperature Ionic Liquids Incorporating the Imidazolium Cation[J]. Green Chem,2001,3:156-164.
[2]	Zhao L P,Li Y J,Liu Z F,et al.Carbon Nanotube-conducting Polymer Core-shell Hybrid using an Imidazolium-salt-based Ionic Liquid as a Linker: Designed as a Potential Platinum Electrode Alternative Material for Large-scale Solution Processing[J]. Chem Mater,2010,22(21):5949-5956.
[3]	Chen Y,Tao J,Deng L,et al.Polyetherimide/Bucky Gels Nanocomposites with Superior Conductivity and Thermal Stability[J]. ACS Appl Mater Interfaces,2013,5(15):7478-7484.
[4]	Bourbigou H O,Magna1 L,Morvan D. Ionic Liquids and Catalysis:Recent Progress from Knowledge to Applications:A Review[J]. Appl Catal A,2010,373(1/2):1-56.
[5]	Xing C Y,Zhao M M,Zhao L P,et al.Ionic Liquid Modified Poly(vinylidenefluoride):Crystalline Structures, Miscibility, and Physical Properties[J]. Polym Chem,2013,4(24):5726-5734.
[6]	Mark P S,Mustafizur R,Christopher S B. Application of Ionic Liquids as Low Volatility Plasticizers for PMMA[J]. Eur Polym J,2003,39(10):1947-1953.
[7]	Mark P S,Christopher S B,Michael G B,et al.Application of Ionic Liquids as Plasticizers for Poly(methyl methacrylate)[J]. Chem Commun,2002,13:1370-1371.
[8]	Xu H,Tong F F,Yu J,et al.A One-Pot Method to Prepare Transparent Poly(methylmethacrylate)/Montmorillonite Nanocomposites Using Imidazolium-Based Ionic Liquids[J]. Polym Int,2012,61(9):1382-1388.
[9]	Xing C Y,Zheng X,Xu L Q,et al. Toward an Optically Transparent, Antielectrostatic,Robust Polymer Composite:Morphology and Properties of Polycarbonate/Ionic Liquid Composites[J]. Ind Eng Chem Res,2014,53(11):4304 4311.
[10]	Zhao L P,Li Y J,Cao X J,et al.Multifunctional Role of an Ionic Liquid in Melt-blended Poly(methyl methacrylate)/Multi-walled Carbon Nanotube Nanocomposites[J]. Nanotechnology,2012,23(25):1-8.
[11]	Wang L,Jiang P K. Thermal and Flame Retardant Properties of Ethylene-Vinyl Acetate Copolymer/Modified Multiwalled Carbon Nanotube Composites[J]. J Appl Polym Sci,2011,119(5):2974-2983.
[12]	Kubisa R. Ionic Liquids in the Synthesis and Modification of Polymers[J]. J Polym Sci Part A:Polym Chem,2005,43:54675-683.
[13]	Wei D,Ivaska A. Applications of Ionic Liquids in Electrochemical Sensors[J]. Anal Chim Acta,2008,607(2):126-135.
[14]	Mark P S,Christopher S B,Michael G B,et al.Application of Ionic Liquids as Plasticizers for Poly(methyl methacrylate)[J]. Chem Commun,2002,13:1370-1371.

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Preparation and Properties of Ionic Liquid and Ethylene-Vinyl Acetate Copolymer Composites

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