Electrocatalytical of Reduction of Oxygen at Cobalt Phthalocyanine and Its Derivative Modified Electrodes

Chinese Journal of Applied Chemistry ›› 2009, Vol. 26 ›› Issue (12): 1471-1475.

• Full Papers • Previous Articles Next Articles

Electrocatalytical of Reduction of Oxygen at Cobalt Phthalocyanine and Its Derivative Modified Electrodes

LI Ya-Nan1,2, HE Li-Hua1*, ZUO Xia1, GAO Shan1, ZHAO Hui1, JIANG Zhou3, CHEN Nai-Sheng3, HUANG Jin-Ling3

(1.Laboratory of Functional Materials,School of Chemistry and Materials Science,
Heilongjiang University,Harbin 150080;
2.Department of Food and Environmental Engineering,Heilongjiang Oriental College,Harbin;
3.Institute of Functional Materials,School of Chemistry and Chemical Engineering,Fuzhou University,Fuzhou)

Received:2009-01-15 Revised:2009-04-27 Published:2009-12-10 Online:2009-12-10
Contact: HUO Li-hua

Abstract

Abstract:

Tetrabromophthalocyanine cobalt (CoPcBr₄), phthalocyanine cobalt (CoPc) and tetra-α-(2,2,4-trimethyl-3-pentyloxy)phthalocyanine cobalt (CoPc(OC₈H₁₇)₄) modified electrodes were prepared on glass carbon (GC) electrodes by the adsorption method. Electrocatalytic reduction of molecular oxygen by the modified electrodes was studied in acidic media by means of cyclic voltammetry and linear sweep voltammetry. The effects of phthalocyanine cobalt with different substituted groups on electrocatalytic property were compared. The results indicate that they have good electrocatalytic activity for molecular oxygen reduction. CoPc and CoPc(OC₈H₁₇)₄ could catalyze O₂ to give H₂O₂ via two-electron transfer and the reduction peak potentials of O₂ positively shifted 0.33 V and 0.48 V respectively compared with the bare GC electrode. There are two reduction peaks at about -0.1 V and -0.7 V in the voltammogram obtained at CoPcBr₄ modified electrode, indicating that it catalyzed the reduction of O₂to H₂O₂ and then sequentially reduced H₂O₂to H₂O. Finally, it completed the four-electron reduction of O₂.

Key words: metellophthalocyanines, oxygen reduction, electrocatalysis

CLC Number:

O614

LI Ya-Nan, HE Li-Hua, ZUO Xia, GAO Shan, ZHAO Hui, JIANG Zhou, CHEN Nai-Sheng, HUANG Jin-Ling. Electrocatalytical of Reduction of Oxygen at Cobalt Phthalocyanine and Its Derivative Modified Electrodes[J]. Chinese Journal of Applied Chemistry, 2009, 26(12): 1471-1475.

References

1 Zagal J H. Coord Chem Rev [J], 1992, 119: 89

2 Choi H J, Kwag G, Kim S. J Electroanal Chem [J], 2001, 508: 105

3 Somashekarappa M P, Sampath S. Anal Chim Acta [J], 2004, 503: 195

4 Sehlotho N, Nyokong T, Zagal J H, Bedioui F. Electrochim Acta [J], 2006, 51: 5 125

5 Sun C Q, Zhang X Y, Jiang D, Gao Q, Xu H D, Sun Y P, Zhang X, Shen J C. J Electroanal Chem [J], 1996, 411: 73

6 Kobayashi N, Nevin W A. Appl Organomet Chem [J], 1996, 10: 57

7 Van Den Brink F, Visscher W, Barendrecht E. J Electroanal Chem [J], 1984, 172: 301

8 Zagal J, Bindra P, Yeager E. J Electrochem Soc [J], 1980, 127 (7): 1 506

9 Kobayashi N, Janda P, Lever A B P. Inorg Chem [J], 1992, 31: 5 172

10 Kobayashi N, Sudo K, Osa T. Bull Chem Soc Jpn [J], 1990, 63: 571

11 Paliteiro C, Hamnett A, Goodenough J B. J Electroanal Chem [J], 1988, 239: 273

12 Ebadi M, Alexiou C, Lever A B P. Can J Chem [J], 2001, 79: 992

13 Sehlotho N, Nyokong T. J Electroanal Chem [J], 2006, 595: 161

14 Kobayashi N, Nishiyama Y. J Phys Chem [J], 1985, 89: 1 167

15 Van Der Putten A, Elzing A, Visscher W, Barendrecht E. J Electroanal Chem [J], 1987, 221: 95

16 Ebadi M. Heterogeneous Catalysts Ruthenium Phthalocyanine Modified Graphite Electrode (PhD thesis), 2002: 110

17 Kobayashi N, Adachi K, Osa, T. Anal Sci [J], 1990, 6: 449

18 Janda P, Kobayashi N, Auburn P R, Lam H, Leznoff C C, Lever A B P. Can J Chem [J], 1989, 67:1 109

19 Cárdenas-Jirón G I, Gulppi M A, Caro C A, Río R, Páez M, Zagal J H. Electrochim Acta [J], 2001, 46: 3 227

20 Zagal J H, Cárdenas-Jirón G I. J Electroanal Chem [J], 2000, 489: 96

[1]	TANG Yanru1*, CHENG Baohai1, GAO Ying2, LI Yunhui2. Three-dimensional Nanocomposite Array Supercapacitor Electrode Based on the Synergistic Effects of Manganese Dioxide and Metallorganic Frameworks [J]. Chinese Journal of Applied Chemistry, 2014, 31(08): 977-982.
[2]	ZHANG Jiajia1, YU Dan1,2, WANG Wei1*. Preparation of Palladium(Ⅱ) Chloride-dopped Carboxylic Styrene Butadiene Latex Film for Electroless Copper Plating [J]. Chinese Journal of Applied Chemistry, 2014, 31(05): 589-593.
[3]	WANG Ruizhi, WANG Zhenzhen, ZHANG Ming, LI Fangfang, GUO Han, WANG Aijun, FENG Jiuju*. Room-temperature Synthesis and Photocatalytic Activity of Lamella Flower-like ZnO [J]. Chinese Journal of Applied Chemistry, 2014, 31(03): 316-322.
[4]	CHEN Chen2, ZHANG Rui2, WANG Xuan2, CAO Yunzhu2, BAI Fengying1*, ZHANG Xiaoxi2, LI Guanghua3, SHI Zhan3, XING Yongheng2. Synthesis, Structure and Mimic Haloperoxidase Catalytic Activity of Peroxovanadium Complexes [J]. Chinese Journal of Applied Chemistry, 2013, 30(12): 1453-1462.
[5]	JIN Rongrong1,2, MA Liqun1, YIN Dongming2, WANG Limin2,3*. Research Development of Cerium-Zinc Flow Battery [J]. Chinese Journal of Applied Chemistry, 2013, 30(08): 855-860.
[6]	CHEN Hong, ZHANG Li, CHEN Qingsong, LING Qidan*. Preparation and Characterization of a Yellow-fluorescent Hydrotalcite-like Compound [J]. Chinese Journal of Applied Chemistry, 2013, 30(07): 776-781.
[7]	WANG Zhenzhen, LI Fangfang, GUO Han, FENG Jiuju*, WANG Aijun. Hydrothermal In Situ Synthesis ZnO Nanoarrays and Their Photocatalytic Applications [J]. Chinese Journal of Applied Chemistry, 2013, 30(06): 667-672.
[8]	FAN Jinchuan1, YANG Ruiqing1, ZHAO Jie1, HUANG Wei2*. Chemical Change of Copper Species in Liquid Paraffin [J]. Chinese Journal of Applied Chemistry, 2013, 30(01): 67-72.
[9]	PENG Chong1,2, YANG Dongmei1,2, LI Guogang1,2, LIAN Hongzhou1, LIN Jun1*. Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO3∶Er3+ Microbelts [J]. Chinese Journal of Applied Chemistry, 2012, 29(12): 1438-1446.
[10]	YU Xuejiao, LIU Jianjun*, YU Yingchun, ZUO Shengli. Application of Fluorescent Quantum Dots Synthesized via Chemical Routes in Fingerprints Development [J]. Chinese Journal of Applied Chemistry, 2012, 29(08): 855-862.
[11]	MA Youmei, YANG Xiaoping*, JIA Xiaolong, GUO Lijuan. A Simple and Controllable Preparation of PbS Nanobelts [J]. Chinese Journal of Applied Chemistry, 2012, 29(05): 557-564.
[12]	CHEN Shikun1,2, ZHAO Xianghua1, WU Jieying1, TIAN Yupeng1*. Synthesis, Crystal Structure and Fluorescent Property of β-diketone and Triphenylphosphine Copper(I) Mixed-Ligand Complex [J]. Chinese Journal of Applied Chemistry, 2012, 29(03): 280-284.
[13]	LIU Wanqiang1,2*, ZHANG Shanshan1,2, WANG Limin2. Electrochemical Hydrogen Storage Properties of Ti-Based Quasicrystalline Composite Materials [J]. Chinese Journal of Applied Chemistry, 2011, 28(12): 1402-1407.
[14]	QIN Gaofei1,2, ZHOU Ying1, LUO Qin3, JIANG Wenwei1*, WANG Jide2 ,YANG Qin3. Process and Application of Recovering Platinum from Used Liquid-phase Catalysts by Solvent Extraction with Thiourea [J]. Chinese Journal of Applied Chemistry, 2011, 28(11): 1337-1339.
[15]	XUE Rujun. Extraction and Separation of Titanium and Iron with Sulfuric Acid Leaching of Fly Ash [J]. Chinese Journal of Applied Chemistry, 2011, 28(07): 804-808.

Electrocatalytical of Reduction of Oxygen at Cobalt Phthalocyanine and Its Derivative Modified Electrodes

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments