Chinese Journal of Applied Chemistry

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Electrospinning Fabrication and Upconversion Luminescent Properties of CaTiO3∶Er3+ Microbelts

PENG Chong1,2, YANG Dongmei1,2, LI Guogang1,2, LIAN Hongzhou1, LIN Jun1*   

  1. (1.State Key Laboratory of Rare Earth Resource Utilization,Changchun Institute of
    Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;
    2.University of Chinese Academy of Sciences,Beijing 100049,China)
  • Received:2012-09-26 Revised:2012-10-10 Published:2012-12-10 Online:2012-12-10

Abstract: One-dimensional CaTiO3∶Er3+ microbelts have been prepared by electrospinning method. X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, scanning electron microscopy(SEM), transmission electron microscopy(TEM), high-resolution transmission electron microscopy(HRTEM), up-converted luminescence were used to characterize the resulting samples. SEM and TEM analysis indicate that the obtained precursor belts have a uniform size, and the as-formed microbelts consist of nanoparticles. Under 980 nm laser beam excitation, the CaTiO3∶Er3+ samples exhibit a green emission band with a maximum at 546 nm originating from the 4S3/2→4I15/2 transitions of Er3+ ions. When the Er3+ concentration increases, the red emission of CaTiO3∶Er3+ increases relative to the green emission, which is due to the energy transfer between Er3+ ions.

Key words: upconversion, electrospinning, microbelts, erbium

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