Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities

Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (2): 20-23.

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Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities

Fu Xiangkai, Wen Shuying, Kang Wei

Department of Chemistry, Southwest China Normal University, Chongqing 630715

Received:1994-06-29 Revised:1994-09-19 Published:1995-04-10 Online:1995-04-10

Abstract

Abstract: Zirconium dibutylaminomethylphosphonate-phosphites Zr(HPO₃)_2-x·(O₃PCH₂N-Bu₂)_x·H₂O (ZPDBN-ZP,x=0.8, 0.6, 0.5, 0.4,0.35) have been prepared for the first time. Partly quaternized ZPDBN-ZP with benzylbromide,zirconium (benzyldibutylammo-niomethy phosphonate bromide-dibuty ammoniomethy phosphonate-phosphite) Zr(HPO₃)_2-x·(O₃PCH₂NBu₂)_x-y·(O₃PCH₂N⁺Bu₂PhCH₂Br^-)_y·have been obtained. lion,esterification, Heterogeneous PTC reactions of H₂O(ZPBBDB-ZPDBN-ZP,y

Key words: zirconium dibutylaminomethylphosphonate, zirconium phosphite, PTC reaction, quaternization, nucleophilic substitution, etherification, esterification, carbene addition

Fu Xiangkai, Wen Shuying, Kang Wei. Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities[J]. Chinese Journal of Applied Chemistry, 1995, 0(2): 20-23.

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Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities

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