Electrochemical Behavior of Li/Zeolotes Cells

Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (2): 24-28.

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Electrochemical Behavior of Li/Zeolotes Cells

Fang Yan

Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008

Received:1994-07-31 Revised:1994-10-31 Published:1995-04-10 Online:1995-04-10

Abstract

Abstract: The discharge and cyclic voltammetry behavior of a variety of zeolites as cathodeof lithium secondary cell have been studied by coulometric titration,infrared absorptionspectrosoepy and X-ray diffractometry. It was found that in the course of discharge lithiumis electrochemically intercalated into compound at discharge depth x<3.4mol.The intercala-tion free energy of Li into NaA zeolite was found to be -231kJ/mol (25℃).The chemicaldiffusion coefficient of lithium in Li_xNaA(x=0.17～0.69)was determined to be about 1×10^-9～1×10^-10cm²/s at room temperature.

Key words: lithium-zeolite cell, intercalation, electrochemical behavior

Fang Yan. Electrochemical Behavior of Li/Zeolotes Cells[J]. Chinese Journal of Applied Chemistry, 1995, 0(2): 24-28.

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Electrochemical Behavior of Li/Zeolotes Cells

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