Synthesis,Structure,Electrical and Magnetic Properties of NdSr1-χMχNiO4(M=Ca,Ba)

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (4): 50-53.

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Synthesis,Structure,Electrical and Magnetic Properties of NdSr_1-χM_χNiO₄(M=Ca,Ba)

Li Siwen, Ren Yufang

Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chmistcy, Chinese Academy of Sciences, Changchun 130022

Received:1993-09-27 Revised:1993-12-09 Published:1994-08-10 Online:1994-08-10

Abstract

Abstract: new series of solid solution NdSr_1－χM_χNiO₄(M=Ca:0.0≤χ≤1.0;M=Ba:0.0≤χ≤0.6) were synthesized by solid state reaction method,and their structures, magnetic and electical properties and IR spectra have been studied.All the samples crystallized in tetragonal system,with exception of the NdCaNiO₄ which crystallized in orthorhombic system. IR spectra of NdSr_1－χM_χNiO₄ showed that the lengths of two Ni-D bonds decrease with the increase of Ca contents. The electric conduction changed from metalic type to semiconductive type,when χ≥0.4(M=Ca,Ba), and the room temperature resistivities of NdSr_1－χM_χNiO₄ increased with the increase of Ca contents. Magnetic susceptibility measurements revealed that Ni³⁺ ions in all the samples at 77～300K Were in low-spin state.

Key words: mixed oxide, synthesis, electrical property, magnetic susceptibility

Li Siwen, Ren Yufang. Synthesis,Structure,Electrical and Magnetic Properties of NdSr_1-χM_χNiO₄(M=Ca,Ba)[J]. Chinese Journal of Applied Chemistry, 1994, 0(4): 50-53.

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Synthesis,Structure,Electrical and Magnetic Properties of NdSr_1-χM_χNiO₄(M=Ca,Ba)

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