Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (4): 45-49.

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Synthesis and Raman Spectra of Charge Complexes TTF·M (dmit)2

Xiao Yufang, Yao Zhongqi, Jin Daosen   

  1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
  • Received:1993-09-08 Revised:1994-01-07 Published:1994-08-10 Online:1994-08-10

Abstract: Eight Charge transfer complexes of type TTF·M (dmit)2(M= Zn,Ni,Cu) were svnthesized.The raman spectra of the complexes showed that the lower the reduction potential(Ep) of the donor part of the complex,the larger the charge transfer degree(ρ)of the complex with the same acceptor.

Key words: tetrathiafulvalene, dimercapto-dithiol-thione, charge transfer complex, synthesis, Raman spectrum