Synthesis,Characterization and Bioactivity of Some Bicopper Complexes

Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (3): 11-15.

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Synthesis,Characterization and Bioactivity of Some Bicopper Complexes

Yang Luqin, Yan Shiping, Bai Lingjun, Liao Daizheng, Jiang Zonghui, Wang Genglin, Shen Panwen

Department of Chemistry, Nankai University, Tianjin 300071

Received:1993-08-30 Revised:1993-12-03 Published:1994-06-10 Online:1994-06-10

Abstract

Abstract: Nine novel bicopper complexes of N,N,N',N″,N″-pentabenzimidazolylmethyl diethylenetriamine were synthesized and characterized by IR,UV-vis,ESR and magnetic susceptibity measurements. Their catecholase and bioactivities were measured. There appeared an antiferromagnetic exchange interaction between copper ions within the complexes. The coordination bond Cu-N was partially covanlent.It was found for the first time that the compounds containing benzimidazole ligand have antitumer activities in vitro and herbicidal and fungicidal activities as well.

Key words: bicopper complex, benzimidazole, bioactivity, ESR, magnetic property

Yang Luqin, Yan Shiping, Bai Lingjun, Liao Daizheng, Jiang Zonghui, Wang Genglin, Shen Panwen. Synthesis,Characterization and Bioactivity of Some Bicopper Complexes[J]. Chinese Journal of Applied Chemistry, 1994, 0(3): 11-15.

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Synthesis,Characterization and Bioactivity of Some Bicopper Complexes

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