SYNTHESIS OF 1,2-BIS(1,12-DIAZA-3,4:9,10-DIBENZO-5,8-DIOXACYCLOPENTADECANEN-ACETIC ACID)ETHANE AND ITS LANTHANIDE COMPLEXES

Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (4): 22-25.

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SYNTHESIS OF 1,2-BIS(1,12-DIAZA-3,4:9,10-DIBENZO-5,8-DIOXACYCLOPENTADECANEN-ACETIC ACID)ETHANE AND ITS LANTHANIDE COMPLEXES

Xie Fuxin^1,2, Tian Yupeng^1,2, Xu Zhiqiang^1,2, Ni Shisheng^1,2

Department of Chemistry, Anhui University, 230039 Hefei

Received:1992-08-18 Revised:1992-11-06 Published:1993-08-10 Online:1993-08-10

Abstract

Abstract: The synthesis and characterization of a new bis-N-functionalized diaza-dioxa maeroeycle 1,2-his(1, 12-diaza-3, 4:9,10-dibenzo-5, 8-dioxaeyclopentadeeane-N-aeetie aeid) ethane (H₂L²) are reported. Eight lanthanide (La, Pr, Nd, Sm, Eu, Gd, Dy, Yb) complexes with this ligand have been prepared in methanol solution by the reaction of H₂L² with rare earth nitrate respectively. These complexes have a general formula of Ln₂L²(NO₃)₄·nH₂O. Their coordination properties are discussed.

Key words: bis-N-acetic acid substituted diaza-dioxa macrocycle, rare earth, complex, synthesis

Xie Fuxin, Tian Yupeng, Xu Zhiqiang, Ni Shisheng. SYNTHESIS OF 1,2-BIS(1,12-DIAZA-3,4:9,10-DIBENZO-5,8-DIOXACYCLOPENTADECANEN-ACETIC ACID)ETHANE AND ITS LANTHANIDE COMPLEXES[J]. Chinese Journal of Applied Chemistry, 1993, 0(4): 22-25.

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SYNTHESIS OF 1,2-BIS(1,12-DIAZA-3,4:9,10-DIBENZO-5,8-DIOXACYCLOPENTADECANEN-ACETIC ACID)ETHANE AND ITS LANTHANIDE COMPLEXES

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