TETRAKIS-4-(2,4-DI-t-PENTYL PHENOXY)PHTHALOCYANINE COPPER(Ⅱ):SYNTHESIS AND LB FILMS THEREFROM

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (2): 52-55.

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TETRAKIS-4-(2,4-DI-t-PENTYL PHENOXY)PHTHALOCYANINE COPPER(Ⅱ):SYNTHESIS AND LB FILMS THEREFROM

Li Yajun¹, Pang Xiao min¹, Jiang Dapeng¹, Lu Ande¹, Hua Yulin¹, Cai Xiaoping², Lin Lin², Chen Wenqi²

1. Changchun Institute of Physics, Academia Sinica, Changchun;
2. Changchun Institute of Applied Chemistry, Acedemia Sinica, Changchun 130022

Received:1989-10-27 Revised:1990-05-19 Published:1991-04-10 Online:1991-04-10

Abstract

Abstract: The title phthalocyanine derivative is easily soluble in chloroform.Electron spectro-scopy showed that the molecules in dilute chloroform solution and LB film therefromobtained were in monomolecular and associated state respectively.The monolayers of the title compound spread from the chloroform solution were depo-sited on solid supports by LB technique according to the Z-type.The surface pressure ofthe film was near 25mN.m^-1.The chemiresistors prepared from 30-layer LB films of thetitle compound were sensitive to NH₃ gas at concentration of 2ppm with good selectivity.

Key words: phthaloeyanine derivative, NH₃ sensibility, LB film, synthesis

Li Yajun, Pang Xiao min, Jiang Dapeng, Lu Ande, Hua Yulin, Cai Xiaoping, Lin Lin, Chen Wenqi. TETRAKIS-4-(2,4-DI-t-PENTYL PHENOXY)PHTHALOCYANINE COPPER(Ⅱ):SYNTHESIS AND LB FILMS THEREFROM[J]. Chinese Journal of Applied Chemistry, 1991, 0(2): 52-55.

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TETRAKIS-4-(2,4-DI-t-PENTYL PHENOXY)PHTHALOCYANINE COPPER(Ⅱ):SYNTHESIS AND LB FILMS THEREFROM

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