Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (6): 48-53.

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CHARACTERIZATION OF MOLECULAR WEIGHT DISTRIBUTION OF IRRADIATED POLYMERS BY SEC-LALLS METHOD

Zhang Wanxi, Wang Mouzhi, Sun Jiazhen, He Zhiduan   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022
  • Received:1989-03-18 Revised:1990-04-29 Published:1990-12-10 Online:1990-12-10

Abstract: In this paper, the effects of the extension influence of SEC column on the variables for a polymer with long chain branching were studied and the main coupled equations were drawn out and solved. The solving process is confirmed by computer simulation. The effects of the extension influence,correction parameter and experimental error on the results of determination have been discussed and a method for systematic characterization of themolecular weight distribution of irradiated polymers by SEC-LALLS technology was suggested.

Key words: irradiated polymer, molecular weight distribution, SEC, LALLS