Analysis of Common Organic Acids in Petrochemical Wastewater by High Performance Liquid Chromatography

doi:10.3724/SP.J.1095.2013.20528

Chinese Journal of Applied Chemistry

• Full Papers • Previous Articles Next Articles

Analysis of Common Organic Acids in Petrochemical Wastewater by High Performance Liquid Chromatography

XING Fei^1,2, XI Hongbo², ZHOU Yuexi^2*, XU Jixian¹, DAI Benhui^1,2, LI Wenjin^1,2, YANG Weihua¹

(1.College of Urban Construction,Hebei University of Engineering,Handan 056038,China；
2.Research Center of Water Pollution Control Technology,Chinese Research Academy of Environmental Sciences,Beijing 100012,China)

Received:2012-11-16 Revised:2013-01-28 Published:2013-09-10 Online:2013-09-10
Contact: xing

Abstract

Abstract: High performance liquid chromatography(HPLC) was used for simultaneous detecting acrylic acid, methacrylic acid and p-toluenesulfonic acid in petrochemical wastewater. The pH of the water sample was adjusted to 1.6, and then solution was filtered with 0.45 μm cellulose acetate membrane before chromatographic analysis. The optimized chromatographic conditions are as follows: phosphate buffer solution(pH=3.0)/acetonitrile(volume ratio is 93∶7) as the mobile phase, flow rate=1.0 mL/min, ZORBAX-SB-C18 column, temperature=30 ℃, MWD detector with detection wavelength at 195 nm, and the injection volume of 10 μL. Under the optimal conditions, the detection limit of acrylic acid, p-toluenesulfonic acid and methacrylic acid is 0.030, 0.028 and 0.050 mg/L, respectively. The relative standard deviations of the samples are 1.83%, 0.69% and 0.84%, respectively, while the recoveries are in the range from 96% to 112%.

Key words: high performance liquid chromatography, acrylic acid, methacrylic acid, p-Toluenesulfonic acid

CLC Number:

O621

XING Fei1,2, XI Hongbo2, ZHOU Yuexi2*, XU Jixian1, DAI Benhui1,2, LI Wenjin1,2, YANG Weihua1. Analysis of Common Organic Acids in Petrochemical Wastewater by High Performance Liquid Chromatography[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.20528.

References

[1] WANG Chaohui,YIN Yiwei,CHEN Shanwen,et al. Studies on Acute Toxicity of Acrylic Acid and Its Esters to Aquatic Organisms[J]. J Jinan Univ,2002,23(5):75-80(in Chinese).

王朝晖,尹伊伟,陈善文,等. 丙烯酸及丙烯酯对水生生物的急性毒性[J]. 暨南大学学报,2002,23(5):75-80.

[2] Greim H. Toxicity and Ecotoxicity of Sulfonic Acids Structure Activity Relationship[J]. Chemosphere,1994,28(12):2203-2236.

[3] LI Deliang,ZHANG Ling,ZHONG Xianjin,et al. Study on the Pretreatment of Doxycycline Wastewater by Adsorption Coagulation[J]. Chemistry,2006,69(8):577-581(in Chinese).

李德亮,张凌,钟先锦,等. 强力霉素废水的吸附-混凝预处理研究[J]. 化学通报,2006,69(8):577-581.

[4] Rosell M,Lacorte S,Barcelo D. Simultaneous Determination of Methyl Tert-butyl Ether, Its Degradation Products and Other Gasoline Additive in Soil Samples by Closed-system Purge- and Trap Gas Chromatography-mass Spectrometry[J]. J Chromatogr A,2006,1132:28-38.

[5] TIAN Jing. Soilquality-determination of Volatile Aromatic Hydrocarbons-headspace/Gas Chromatographic Method[J]. Environ Sci Manage,2007,32(11):125-128(in Chinese).

田靖. 顶空/气相色谱法测定土壤中的挥发性芳烃[J]. 环境科学与管理,2007,32(11):125-128.

[6] Czech Z,Pelech R. Use of Pyrolysis and Gas Chromatography for the Determination of Acrylic Acid Concentration in Acrylic Copolymers Containing Carboxylic Groups[J]. Poly Test,2008,27(7):870-872.

[7] LI Xiaojuan,ZHOU Changmei,WU Jian. Determination of Propionic Acid and Acrylic Acid in Air in a Workplace by Gas Chromatography[J]. Chinese J Health Lab Technol,2007,17(10):1780-1781(in Chinese).

李小娟,周长美,吴健. 工作场所空气中丙酸及丙烯酸的气相色谱测定[J]. 中国卫生检疫杂志,2007,17(10):1780-1781.

[8] XI Hongbo,ZHOU Yuexi,SONG Yudong. Determination of Semi-volatile Organic Compounds in Phenol-acetone Production Wastewater by GC/MS[J]. Environ Pollut Control,2012,34(2):9-13(in Chinese).

席宏波,周岳溪,宋玉栋. 气相色谱/质谱测定苯酚丙酮生产废水中半挥发性有机物[J]. 环境污染与防治,2012,34(2):9-13.

[9] SONG Guangqing,XI Hongbo,PAN Ling,et al. Analysis of Organic Pollutants in Refinery Wastewater by Gas Chromatography[J]. Petrochem Technol,2012,41(4):464-469(in Chinese).

宋广清,席宏波,潘玲,等. 炼油废水中有机污染物的气相色谱分析[J]. 石油化工,2012,41(4):464-469.

[10] Casella I G,Pierri M,Contursi M. Determination of Acrylamide and Acrylic Acid by Isocratic Liquid Chromatography with Pulsed Electrochemical Detection[J]. J Chromatogr A,2006,1107(1/2):198-203.

[11] CHANG Fengmin,JIANG Jinyuan,WANG Junjun,et al. Determination of Main Pollutants in Acrylic Wastewater by High Performance Liquid Chromatography[J]. Environ Sci Technol,2010,33(9):177-179(in Chinese).

常风民,蒋进元,王俊钧,等. 高效液相色谱法测定腈纶废水中的特征污染物[J]. 环境科学与技术,2010,33(9):177-179.

[12] ZHANG Ling,LI Deliang,CUI Jiehu,et al. Simultaneous Determination of Sulfosalicylic Acid and p-Toluene Sulfonic Acid in Doxycycline Wastewater by UV Spectrophotometry[J]. J Instrum Anal,2006,25(4):108-110(in Chinese).

张凌,李德亮,崔节虎,等. 紫外光谱法同时测定强力霉素废水中磺基水杨酸与对甲基苯磺酸[J]. 分析测试学报,2006,25(4):108-110.

[13] FAN Zhiqing,SONG Yudong,ZHOU Yuexi. Determination of Acrylic Acid and p-Toluenesulfonic Acid in Butyl Acrylate-production Wastewater by Ion Chromatography[J]. Chinese, Environ Monitor,2010,26(3):26-28(in Chinese).

范志庆,宋玉栋,周岳溪. 离子色谱法测定丙烯酸丁酯生产废水中丙烯酸和对甲基苯磺酸[J]. 中国环境监测,2010,26(3):26-28.

[14] Argekar A P,Kunjir S S. Quantitative Estimation of Sultamicilln p-Toluenesulfonate in Pharmaceutical Preparations by Reverse-phase High Performance Liquid Chromatography[J]. J Pharm Biomed Anal,1996,15(3):423-427.

[15] Graham E T,Mark G,Andrea P. Low Level Determination of p-Toluenesulfonate and Benzenesulfonate Esters in Drug Substance by High Performance Liquid Chromatography/Mass Spectrometry[J]. J Chromatogr A,2006,1119(1/2):231-237.

[16] CHEN Gang,WANG Jun,HUANG Cheng. High Performance Liquid Chromatography Applications in the Petrochemical Industry[J]. Appl Chem Ind,2011,40(1):128-131(in Chinese).

陈刚,王军,黄程. 高效液相色谱技术在石油化工中的应用[J]. 应用化工,2011,40(1):128-131.

[17] MA Ying. The Technology of High-performance Liquid Chromatography and the Application in Determination of Water Quality[D]. Tianjin:Tianjin University,2009(in Chinese).

马颖. 高效液相色谱技术及在水质检测方面的应用[D]. 天津:天津大学,2009.

[18] CHEN Miao. Investigation on Quality Control Strategies of HPLC Analysis[J]. Public Commun Sci Technol,2011,11(22):89-90(in Chinese).

陈苗. 高效液相色谱分析的质量控制策略探讨[J]. 科技传播,2011,11(22):89-90.

[19] XU Hong,HOU Jian. The Choicing Ways of Chromatographic Column and Mobil Phase about HPLC[J]. Metrol Measure Tech,2010,37(2):10-11(in Chinese).

徐红,侯健. 高效液相色谱的色谱柱的类型和流动相的选择方法[J]. 计量与测试技术,2010,37(2):10-11.

[20] ZHAO Shuying,SUN Jun,LU Xinchun. Application and Precautions in the Reversed-phase Liquid Chromatography Analysis of Buffer Solution[J]. Chinese J Health Lab Technol,2008,18(2):359-360(in Chinese).

赵淑英,孙军,鲁新春. 缓冲溶液在反相液相色谱法分析中的应用及注意事项[J]. 中国卫生检验杂志,2008,18(2):359-360.

[21] CHENG Hongda,LI Tong,ZHANG Weibing. Influence of Temperature on Separation Behaves of HPLC[J]. Modern Sci Instru,2006,5:74-79(in Chinese).

成洪达,李彤,张维冰. 温度对高效液相色谱分离性能的影响[J]. 现代科学仪器,2006,5:74-79.

[22] WANG Yanjie,NA Guangshui,WANG Zhen,et al. Connotation and Calculation Methods of Detection Limit[J]. Chem Anal Meter,2012,21(5):85-88(in Chinese).

王艳洁,那广水,王震,等. 检出限的涵义和计算方法[J]. 化学分析计量,2012,21(5):85-88.

[23] DING Yi,PENG Cheng. Evaluation of Four Simple Methods for Calculating the Method Detection Limit of HPLC Analysis[J]. Modern Food Sci Technol,2009,25(11):1372-1374(in Chinese).

丁怡,彭程. 多种方法评估液相色谱方法检出限的初步探讨[J]. 现代食品科技,2009,25(11):1372-1374.

Analysis of Common Organic Acids in Petrochemical Wastewater by High Performance Liquid Chromatography

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ze-Shan LENG, Hong-Mei GUO, Han-Qing CAI, Jian ZHANG. Research on Simultaneous Determination of Eight Artificial Sweeteners in Food by High Performance Liquid Chromatography with Charged Aerosol Detector [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 436-440.
[2]	Yu-Huang LI, Ze-Yi LU, Hong-Mei YUAN, Gang WANG, Cheng-Jiang ZHANG. Preparation and Application of Acylhydrazone Bonded Polymer Gel in Nitrofuran Drugs Analysis [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 100-108.
[3]	Hao FU, Wan-Qi XIONG, Zhen WANG, Ai-Hong DUAN, Li-Ming YUAN. Covalent Organic Framework Material Derivative of Chiral Camphor Used as High Performance Liquid Chromatography Stationary Phase for Resolution of Racemates [J]. Chinese Journal of Applied Chemistry, 2022, 39(9): 1371-1381.
[4]	Shu-Fang LI, Xue-Fei HAO, Hong-Qi WANG, Xiao-Meng GUO, Shu-Hui FENG, Hai-Yan YIN, Dong-Mei LIU, Yong-Jie YU. Automatic Data Analysis Strategy Coupled with Q Exactive High Resolution Mass Spectrometry for Studying Different Industrial Process of Lonicerae Japonicae Flos [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 819-827.
[5]	Hui-Jing SUN, Dong-Ni CUI. Determination of Aldicarb， Aldicarb Sulfoxide， Aldicarb Sulfone in Water by Solid Phase Extraction and UPLC⁃MS/MS with Isotope Dilution [J]. Chinese Journal of Applied Chemistry, 2022, 39(3): 470-479.
[6]	Yao CHEN, Ying TANG. Determination of Hydrazine in Clozapine by Precolumn Derivatization High Performance Liquid Chromatography Method [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 322-331.
[7]	Xiao-Cui YI, Wei YI, Lin LEI, Hao ZENG, Yi-Feng JIANG, Wei-Li LI, Chun-Lin CHEN. Simultaneous Determination of Six Benzodiazepines in Rat Urine by Liquid Chromatography Tandem Mass Spectrometry [J]. Chinese Journal of Applied Chemistry, 2022, 39(02): 340-348.
[8]	WANG Cong, ZHAO Xiao-Yu, WANG Hai-Yan, CAO Jin, WANG Gang-Li. Detection of 73 Veterinary Drugs Residues in Animal Muscle Tissues by High Performance Liquid Chromatography-Triple Quadrupole Mass Spectrometry [J]. Chinese Journal of Applied Chemistry, 2021, 38(12): 1663-1675.
[9]	WANG Wei, WU Yan, CHU Liu-Xi, YUAN Lin, ZHU Min-Hui, YANG Jin, DENG Hui-Hua. Detection of Endocannabinoids and Glucocorticoids in Hair of People Living with HIV by High Performance Liquid Chromatography Tandem Mass Spectrometry [J]. Chinese Journal of Applied Chemistry, 2021, 38(11): 1521-1530.
[10]	ZHANG Yanhui, WANG Lin, MUSLIM Arzugul, LAN Haidie. Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 764-771.
[11]	WANG Haitao, LIU Haifeng, LIU Yan, ZHAO Wenbo, GAO Runli, DUAN Jingzhong, ZHANG Yuanpeng. Determination of the Purity of o-Chlorobenzylidene Malononitrile by Multiple Analysis Methods [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 810-815.
[12]	HU Xueyi, HU Yitao, FANG Yun, XIA Yongmei, QIAN Fei. Quantitative Analysis of Residual Nonylcyclohexanol in Nonylcyclohexanol Polyoxyethylene Ethers by Normal Phase High Performance Liquid Chromatography [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 816-822.
[13]	CAI Zhibin,SUN Jinying,XU Xiaoyan,ZHANG Ying,LAI Jianhui,LIU Jinming. QuEChERS Purification with HPLC-MS/MS for Rapid Confirmation in Acute Clenbuterol Poisoning Case Sample [J]. Chinese Journal of Applied Chemistry, 2019, 36(7): 832-838.
[14]	WANG Yue,CAI Chen,LIU Huiling,SUN Li,LI Yanchao,MENG Zhaohong. Quantitative Analysis of Cephalosporin C in Soil by High Performance Liquid Chromatography with Ultrasound-assisted Extraction and Solid-Phase Extraction [J]. Chinese Journal of Applied Chemistry, 2018, 35(6): 722-728.
[15]	ZHANG Junqi, JIN Shuping, HAN Yuqi, YU Xinghai, YUE Guoren. Preparation and Swelling Properties of Coal Fly Ash Composited Sodium Polyacrylate Hydrogel [J]. Chinese Journal of Applied Chemistry, 2016, 33(4): 419-429.