Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on  the Size and Properties of Polyaniline

doi:10.11944/j.issn.1000-0518.2020.07.190360

Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (7): 764-771.DOI: 10.11944/j.issn.1000-0518.2020.07.190360

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Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline

ZHANG Yanhui, WANG Lin, MUSLIM Arzugul^*, LAN Haidie

Electrochemical Engineering Center,School of Chemistry and Chemical Engineering,Xinjiang Normal University,Urumqi 830054,China

Received:2019-12-30 Published:2020-07-01 Online:2020-07-07
Contact: MUSLIM Arzugul, professor; Tel:0991-4332091; E-mail:arzu_hma@sina.com; Research interests:electroactive polymer materials
Supported by:
Supported by the National Natural Science Foundation of China(No.51763023), and the Scientific Research Plan for Universities of Xinjiang(No.XJEDU2017S028)

Abstract

Abstract: Use of amphiphilic block copolymers as templates is one of the effective methods to construct conducting polymer nanostructures and adjust their morphologies and sizes. The change of the length of core-forming block has a significant effect on their micellization behavior, and then changes the morphology and size of conducting polymers limited by their micelle morphology. The change of morphology and size will inevitably lead to the change of electrochemical properties of conducting polymers. In this paper, the morphology and size of polyaniline (PANI) were controlled and its electrochemical performance was optimized by block copolymer template induction. Polystyrene-b-poly(acrylic acid) (PS_x-b-PAA₇₀, x=38, 64, 101) was successfully synthesized by reversible addition-fragmentation chain transfer radical polymerization (RAFT) and its self-assembled micelles were used as templates to prepare PANI. When the length of core forming block is shorter, the PANI shows rod-like particles with diameters 100~200 nm. When x=101, PANI presents spatial network structure and has the highest discharge specific capacitance. When the current density is 1 A/g, its discharge specific capacity can reach 386.71 F/g.

Key words: polystyrene-b-poly(acrylic acid), block copolymer template, polyaniline, capacitance

ZHANG Yanhui, WANG Lin, MUSLIM Arzugul, LAN Haidie. Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline[J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 764-771.

References

[1] Gibson T J,Peter S,Mcdaid W J,et al. Single-Domain Antibody-Functionalized pH-Responsive Amphiphilic Block Copolymer Nanoparticles for Epidermal Growth Factor Receptor Targeted Cancer Therapy[J]. ACS Macro Lett,2018,7(8):1010-1015.
[2] Lü J H,Yu Y,Gao J F,et al. Thermo-Responsive Amphiphilic Block Copolymers Stablilized Gold Nanoparticles:Synthesis and High Catalytic Properties[J]. Langmuir,2018,34(28):8205-8214.
[3] Park S H,Ahn Y,Jang M,et al. Effects of Methacrylate Based Amphiphilic Block Copolymer Additives on Ultra Filtration PVDF Membrane Formation[J]. Sep Purif Technol,2018,202:34-44.
[4] Li Z J,Sun J J,Huang Y X,et al. A Nanomicellar Prodrug Carrier Based on Ibuprofen-Conjugated Polymer for Co-delivery of Doxorubicin[J]. Front Pharmacol,2018,9:781-792.
[5] Yoo S I,Sohn B H,Wang C Z ,et al.. Localized Synthesis of Polypyrrole in the Nanopattern of Monolayer Films of Diblock Copolymer Micelles[J]. Langmuir,2004,20:10734-10736.
[6] Yin Z G,Zheng Q D. Controlled Synthesis and Energy Application of One-Dimensional Conducting Polymer Nanostructures:An Overview[J]. J Phys Chem B,2010,114:1314-1324.
[7] DONG Jianhua. The Frontier and Development of Polymer Science[M]. Beijing:Science Press,2006:516(in Chinese).
董建华. 高分子科学前沿与进展[M]. 北京:科学出版社,2006:516.
[8] Zhao Z X,Muslim A,Abdunazar A,et al. Preparation of Polybenzidine Submicrorods with Controllable Morphology Using Poly(ethylene oxide)-b-Polystyrene as a Template and Its Electrochemical Properties[J]. J Macromol Sci A,2017,54(10):727-734.
[9] Bucholz T,Sun Y M,Loo Y L. Near-Monodispersed Polyaniline Particles Through Template Synthesis and Simultaneous Doping with Diblock Copolymers of PMA and PAAMPSA[J]. J Mater Chem,2008,18:5835-5842.
[10] Benaglia M,Rizzardo E,Alberti A,et al. Searching for More Effective Agents and Conditions for the RAFT Polymerization of MMA:Influence of Dithioester Substituents, Solvent, and Temperature[J]. Macromolecules,2005,38(8):3129-3140.
[11] ZHU Hui,LIU Shiyong,PAN Quanming,et al. Synthesis of Amphiphilic Block Copolymer Poly(styrene-b-acrylic acid) by Atom Transfer Radical Polymerization and Its Micellization[J]. Chem J Chinese Univ,2002,23(1):138-142(in Chinese).
朱蕙,刘世勇,潘全名,等. 窄分布两亲性嵌段共聚物的合成及其胶束化行为研究[J]. 高等学校化学学报,2002,23(1):138-142.
[12] SUN Chunhui,CAO Xia,FU Peng,et al. Synthesis of Block Copolymer Poly(ε-Caprolactone)₄-b-Poly(Acrylic Acid)₄[J]. Polym Mater Sci Eng,2012,28(1):41-44(in Chinese).
孙春会,曹霞,付鹏,等. 聚(ε-己内酯)-b-聚丙烯酸嵌段聚合物的合成[J]. 高分子材料科学与工程,2012,28(1):41-44.
[13] HUA Man,YANG Wei,XUE Qiao,et al. Study on Synthesis of Amphiphilic PS-b-PMAA and Their Micellization[J]. Acta Chim Sin,2005,63(7):631-636(in Chinese).
华曼,杨伟,薛乔,等. 两亲性嵌段共聚物PS-b-PMAA合成与胶束化行为研究[J]. 化学学报,2005,63(7):631-636.
[14] Huang J,Virji S,Weiller B H,et al. Polyaniline Nanofibers:Facile Synthesis and Chemical Sensors[J]. J Am Chem Soc,2003,125(2):314-315.
[15] Ghosh T,Ghosh R,Basak U,et al. Candle Soot Derived Carbon Nanodot/Polyaniline Hybrid Materials Through Controlled Grafting of Polyaniline Chains for Supercapacitors[J]. J Mater Chem A,2018,6:6476-6492.
[16] GAO Lei,LIAO Yi,ZHANG Xiaohua,et al. Preparation and Enhanced Electrocapacitive Properties of Polyaniline Nanothorns on the Surface of Nitrogen Doped Hollow Carbon Spheres[J]. Chem J Chinese Univ,2013,34(12):2845-2849(in Chinese).
高磊,廖奕,张小华,等. 聚苯胺纳米刺/掺氮空心碳球复合材料的制备及电容性能[J]. 高等学校化学学报,2013,34(12):2845-2849.
[17] KAN Kan,FU Dong,WANG Jue. Preparation and Capacitive Performance of Interconnected Composite Nanowire Based on Polyaniline Coated Carbon Nanofiber[J]. Fine Chem,2019,36(10):2060-2067(in Chinese).
阚侃,付东,王珏,等. 交联状聚苯胺包覆碳纤维复合纳米线制备及电容特性[J]. 精细化工,2019,36(10):2060-2067.
[18] ZHAO Qiang,LV Mangeng. Synthesis of Three-Dimensional Ordered Polyaniline-Graphene Nanocomposite and Its Application for Supercapacitor Electrode[J]. Fine Chem,2016,33(6):635-642(in Chinese).
赵强,吕满庚. 三维有序结构聚苯胺/石墨烯纳米复合材料的制备及其在超级电容器电极中应用[J]. 精细化工,2016,33(6):635-642.
[19] Chen W,Xia C,Rakhi R B,et al. A General Approach toward Enhancement of Pseudocapacitive Performance of Conducting Polymers by Redox-Active Electrolytes[J]. J Power Sources,2014,267(4):521-526.
[20] Liu Y,Ma Y,Guang S,et al. Facile Fabrication of Three Dimensional Highly Ordered Structural Polyaniline-Graphene Bulk Hybrid Materials for High Performance Supercapacitor Electrodes[J]. J Mater Chem A,2014,2:813-823.
[21] Wang Y,Shi Z,Huang Y,et al. Supercapacitor Devices Based on Graphene Materials[J]. J Phys Chem C,2009,113:13103-13107.

Influence of the Core Forming Block Length of Polystyrene-b-Poly(acrylic acid) Template on the Size and Properties of Polyaniline

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