Coconut char sulfonic acid: A mild, reusable and highly efficient heterogeneous catalyst for the synthesis of calix[4]resorcinarenes

doi:10.3724/SP.J.1095.2010.90188

Chinese Journal of Applied Chemistry ›› 2010, Vol. 27 ›› Issue (02): 237-239.DOI: 10.3724/SP.J.1095.2010.90188

• Original Articles • Previous Articles Next Articles

Coconut char sulfonic acid: A mild, reusable and highly efficient heterogeneous catalyst for the synthesis of calix[4]resorcinarenes

ZUO Chuan-Peng, YANG Zhi-Gao, YIN Du-Lin*, YUAN Zhi-Ye, XU Qiong, MAO Li-Qiu

(Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research,
Ministry of Education,Institute of Fine Catalysis and Synthesis,
Hunan Normal University,Changsha 410081)

Received:2009-03-20 Revised:2009-06-28 Published:2010-02-10 Online:2010-02-10

Abstract

Abstract:

A novel solid sulfonic acid was prepared from coconut shell via carbonization and sulfonation and used as catalyst for the condensation of aldehydes and resorcinol, calix[4]resorcinarenes were prepared rapidly in good yield (49%-95%). The structures of the target compounds were confirmed by IR、¹H NMR and MS.

Key words: coconut char sulfonation, solid-state catalyst, grinding method, aldehyde, resorcinol

CLC Number:

ZUO Chuan-Peng, YANG Zhi-Gao, YIN Du-Lin*, YUAN Zhi-Ye, XU Qiong, MAO Li-Qiu. Coconut char sulfonic acid: A mild, reusable and highly efficient heterogeneous catalyst for the synthesis of calix[4]resorcinarenes[J]. Chinese Journal of Applied Chemistry, 2010, 27(02): 237-239.

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Coconut char sulfonic acid: A mild, reusable and highly efficient heterogeneous catalyst for the synthesis of calix[4]resorcinarenes

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