Preparation of Hypercrosslinked Poly（Naphthalene-based） Microporous Carbon and Its Electrochemical Properties

doi:10.19894/j.issn.1000-0518.240163

Chinese Journal of Applied Chemistry ›› 2024, Vol. 41 ›› Issue (12): 1742-1750.DOI: 10.19894/j.issn.1000-0518.240163

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Preparation of Hypercrosslinked Poly（Naphthalene-based） Microporous Carbon and Its Electrochemical Properties

Sheng-Long HU¹(), Zhen-Long LEI², De-Jun CHEN¹

^1.Lanzhou Auxiliary Agent Plant Company Limited，Lanzhou 730311，China
^2.School of Petrochemical Engineering，Lanzhou University of Technology，Lanzhou 730050，China

Received:2024-05-22 Accepted:2024-11-10 Published:2024-12-01 Online:2025-01-02
Contact: Sheng-Long HU
About author:hushenglong@lanquan.com
Supported by:
Lanzhou Talent Innovation and Entrepreneurship Project(2021-RC-20)

Abstract

Abstract:

With superior chemical stability， high specific surface area and porosity， the hypercrosslinked polymers are of great interests in the field of energy conversion and storage. Here， a hypercrosslinked poly（naphthalene-based） polymer （MON） was synthesized using an external cross-linking agent via a novel “knitting” method. Following this， MON-derived microporous carbon （MONC-800-2） was prepared via chemical activation for advanced supercapacitors. The MONC-800-2 features a high specific surface area of 2002.90 m2/g and microporosity of 90.10%. The MONC-800-2 shows a superior specific capacity of 254.0 F/g at current density of 1.0 A/g. Consequently， the assembled symmetrical supercapacitor with MONC-800-2 displays a high specific capacity of 43.0 F/g， superior cycling stability （with a capacity retention rate of 94.55% at 2.0 A/g over 5000 cycles）， high Coulomb efficiency of 99.91%， and good energy density of 5.97 Wh/kg at a power density of 500 W/kg. This work offers valuable insights into the application of hypercrosslinked polymers-derived carbon materials in supercapacitors.

Key words: Supercapacitor, Electrode material, Carbon material, Precursor, Hypercrosslinked polymer

CLC Number:

O646.5

Sheng-Long HU, Zhen-Long LEI, De-Jun CHEN. Preparation of Hypercrosslinked Poly（Naphthalene-based） Microporous Carbon and Its Electrochemical Properties[J]. Chinese Journal of Applied Chemistry, 2024, 41(12): 1742-1750.

Figures/Tables 10

Fig.1 （A） FT-IR and （B） TGA-DTG curves of MON

Fig.2 Raman spectra of MONC-800 and MONC-800-A

Fig.3 XRD spectra of MONC-800-A

Fig.4 N2 absorption/desorption （A） and aperture distribution （B） curves for MONC-800， MONC-800-1， MONC-800-2 and MONC-800-3

Table 1 Specific surface area and parameters of pore space of MONC-800 and MONC-800-A

Sample	S_BET/（m²·g^-1）	S_micro/（m²·g^-1）	S_micro·S_BET^-1/%	V_total/（cm³·g^-1）	D_average/nm
MONC-800	588.75	495.67	84.19	0.65	4.44
MONC-800-1	1 785.57	1 613.97	90.38	1.49	3.33
MONC-800-2	2 002.90	1 804.66	90.10	2.03	4.04
MONC-800-3	1 756.35	1 392.10	79.26	2.05	4.68

Fig.5 （A，B） SEM，（C，D） TEM and （E，F） energy dispersive spectroscopy-mapping images of MON and MONC-800-2

Fig.6 Electrochemical performance of MONC-800 and MONC-800-A

Fig.7 Electrochemical performance of MONC-800-2

Fig.8 Assembly diagram of supercapacitor

Fig.9 Electrochemical performance of SSC

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Preparation of Hypercrosslinked Poly（Naphthalene-based） Microporous Carbon and Its Electrochemical Properties

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