Chinese Journal of Applied Chemistry ›› 2020, Vol. 37 ›› Issue (11): 1221-1235.DOI: 10.11944/j.issn.1000-0518.2020.11.200208

• Review • Previous Articles     Next Articles

Recent Progress of Metal Organic Frameworks-Based Hollow Materials

CHEN Jiaqi, ZHOU Yan, SUN Jingwen, ZHU Junwu, WANG Xin*, FU Yongsheng*   

  1. Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology,Nanjing 210094,China
  • Received:2020-07-10 Revised:2020-08-05 Accepted:2020-08-24 Online:2020-11-01 Published:2020-11-04
  • Contact: FU Yongsheng, professor; Tel/Fax:025-84315054;; Research interests:synthesis of functional materials and the applications in energy storage and conversion
    Co-rresponding author:WANG Xin, professor; Tel/Fax:025-84305667;; Research interests:preparation of functional materials via soft chemistry and their applications in energy and environment
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.51772156, No.51872144), the Natural Science Foundation of Jiangsu Province(No.BK20180019, No.BK20171423)

Abstract: Metal organic frameworks (MOFs) hollow materials, such as hydroxide, phosphide and sulfide, have attracted great attention in the applications of energy storage and conversion owing to their advantageous features of large specific area, low density, high loading capacity and excellent ion permeability. This review summarizes various synthetic strategies and formation mechanism for different structural MOFs-derived hollow materials. The promising electrochemical applications in the supercapacitors, lithium ion battery, and electrocatalysis are prominently elucidated. An outlook of development prospects and challenges for MOFs hollow structured derivatives is also discussed.

Key words: metal organic frameworks, hollow, synthesis, supercapacitor, lithium ion battery, electrocatalysis

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