Research Progress in Preparation and Application of Precious Metal Ion-Imprinted Polymers

doi:10.19894/j.issn.1000-0518.230068

Chinese Journal of Applied Chemistry ›› 2023, Vol. 40 ›› Issue (10): 1359-1375.DOI: 10.19894/j.issn.1000-0518.230068

• Review • Previous Articles

Research Progress in Preparation and Application of Precious Metal Ion-Imprinted Polymers

Yang PAN, Hui-Ling LU, Hao LI(), Jian-Ming PAN()

School of Chemistry and Chemical Engineering，Jiangsu University，Zhenjiang 212013，China

Received:2023-03-20 Accepted:2023-07-13 Published:2023-10-01 Online:2023-10-13
Contact: Hao LI,Jian-Ming PAN
About author:pjm@ujs.edu.cn
haoli5385@ujs.edu.cn
Supported by:
the National Natural Science Foundation of China(22208128);the Natural Science Foundation of Jiangsu Province(BK20210775);the Natural Science Research Program of Jiangsu Province(21KJB530005)

Abstract

Abstract:

Due to excellent physical and chemical properties， precious metals are widely used in various fields of national economy and national defense construction， and are extremely important economic and strategic resources. In recent years， due to the rapid growth in the demand for rare and precious metals， the contradiction between supply and demand has become increasingly serious. Therefore， it is very important to selective recovery of precious metals from secondary resources such as electronic waste with high precious metal content. Ion-imprinted polymers （IIPs） are widely used in solid phase extraction， preconcentration， water treatment， membrane separation and electrochemical sensors due to the advantages of simple preparation， cavity fixation， structural stability， good environmental adaptability， high regeneration capacity and selectivity for template ions. In this paper， the research progress of ion imprinting technology in the recovery of precious metals at home and abroad in recent years is reviewed， the preparation process and its application are introduced， and the current problems and future development directions of precious metal ion imprinting technology are analyzed and prospected.

Key words: Precious metals, Ion-imprinted, Selectivity, Recovery, Adsorption

CLC Number:

O635

Yang PAN, Hui-Ling LU, Hao LI, Jian-Ming PAN. Research Progress in Preparation and Application of Precious Metal Ion-Imprinted Polymers[J]. Chinese Journal of Applied Chemistry, 2023, 40(10): 1359-1375.

Figures/Tables 11

References 106

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102	ZAMBRZYCKA E， KIEDYSZ U， WILCZEWSKA A Z， et al. A novel ion imprinted polymer as a highly selective sorbent for separation of ruthenium ions from environmental samples［J］. Anal Methods， 2013， 5（12）： 3096-3105.
103	ZAMBRZYCKA E， GODLEWSKA-ŻYŁKIEWICZ B. A new ion imprinted polymer based on Ru（‍Ⅲ‍）-thiobarbituric acid complex for solid phase extraction of ruthenium（‍Ⅲ‍） prior to its determination by ETAAS［J］. Microchim Acta， 2014， 181（9）： 1019-1027.
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Imprinting strategy	Monomer	Solvent	Initiator/Crosslinker	Adsorption capacity/（mg·g^-1）	Detection method	Application	Ref.
Surface imprinting	APPA	Methanol	AIBN/EGDMA	76	FAAS	Preconcentration	［50］
Surface imprinting	APPA	Methanol	AIBN/EGDMA	81	FAAS	Preconcentration	［51］
Surface imprinting	APPA	Methanol	AIBN/EGDMA	67	FAAS	Preconcentration	［52］
Sol-gel	VIM	Acetic acid	—/Glutaraldehyde	810	ICP-OES	Preconcentration	［53］
Sol-gel	MB	Acetic acid	—/ECH	370	AAS	Preconcentration	［54］
Sol-gel	Tu	Acetic acid	—/Glutaraldehyde	933	AAS	Preconcentration	［55］
Sol-gel	PTCS	H₂O	—/Glyoxal	140	AAS	Preconcentration	［56］
Sol-gel	Tu	H₂O	—/ECH	185	ICP-OES	Preconcentration	［57］
Sol-gel	AcM， HEA	H₂O	DMPA/EGDMA	70	FAAS	Preconcentration	［58］
Bulk polymerization	4-VP	Methanol， H₂O	AMP/EGDMA	418	ICP-OES	Preconcentration	［59］
Bulk polymerization	EDA	DMSO	AMP/EGDMA	394	ICP-OES	Preconcentration	［59］
Bulk polymerization	ADT	DMSO	AMP/EGDMA	190	ICP-OES	Preconcentration	［59］
Sol-gel	TCTES	HCl		475	AAS	Preconcentration	［60］
Surface imprinting	VIM	Methanol，H₂O	AIBN/EGDMA	185	FAAS	SPE	［61］
Surface imprinting	VIM	Methanol，H₂O	AIBN/EGDMA	93	ICP-OES	SPE	［62］

Imprinting strategy	Monomer	Solvent	Initiator/Crosslinker	Adsorption capacity/（mg·g^-1）	Detection method	Application	Ref.
Surface imprinting	APPA	Methanol	AIBN/EGDMA	76	FAAS	Preconcentration	［50］
Surface imprinting	APPA	Methanol	AIBN/EGDMA	81	FAAS	Preconcentration	［51］
Surface imprinting	APPA	Methanol	AIBN/EGDMA	67	FAAS	Preconcentration	［52］
Sol-gel	VIM	Acetic acid	—/Glutaraldehyde	810	ICP-OES	Preconcentration	［53］
Sol-gel	MB	Acetic acid	—/ECH	370	AAS	Preconcentration	［54］
Sol-gel	Tu	Acetic acid	—/Glutaraldehyde	933	AAS	Preconcentration	［55］
Sol-gel	PTCS	H₂O	—/Glyoxal	140	AAS	Preconcentration	［56］
Sol-gel	Tu	H₂O	—/ECH	185	ICP-OES	Preconcentration	［57］
Sol-gel	AcM， HEA	H₂O	DMPA/EGDMA	70	FAAS	Preconcentration	［58］
Bulk polymerization	4-VP	Methanol， H₂O	AMP/EGDMA	418	ICP-OES	Preconcentration	［59］
Bulk polymerization	EDA	DMSO	AMP/EGDMA	394	ICP-OES	Preconcentration	［59］
Bulk polymerization	ADT	DMSO	AMP/EGDMA	190	ICP-OES	Preconcentration	［59］
Sol-gel	TCTES	HCl		475	AAS	Preconcentration	［60］
Surface imprinting	VIM	Methanol，H₂O	AIBN/EGDMA	185	FAAS	SPE	［61］
Surface imprinting	VIM	Methanol，H₂O	AIBN/EGDMA	93	ICP-OES	SPE	［62］

Imprinting strategy	Monomer	Solvent	Initiator/Crosslinker	Adsorption capacity/（mg·g^-1）	Detection method	Application	Ref.
Sol-gel	CS	Acetic acid	—/Glutaraldehyde	125	ICP-OES	Membrane	［63］
Sol-gel	CS	Acetic acid	—/Glutaraldehyde	2 312	FAAS	Membrane	［64］
Sol-gel	CS	H₂O	—/Glutaraldehyde	89	ICP-OES	Preconcentration	［65］
Surface imprinting	Tu	Ethanol	—/Glutaraldehyde	156	ICP-OES	Preconcentration	［66］
Surface imprinting	MPTS	Toluene		91	FAAS	Preconcentration	［67］
Precipitation	4-VP	Ethanol	DMPA/MBA	73	ICP-OES	Preconcentration	［68］
Precipitation Precipitation Precipitation	VIM 4-VP VIM	Ethanol Ethanol Ethanol	DMPA/MBA DMPA/MBA DMPA/MBA	77 26 36	ICP-OES FAAS FAAS	Preconcentration Preconcentration Preconcentration	［68］［69］［69］
Sol-gel Surface imprinting Surface imprinting	CS MPTS CS	Acetic acid Methanol，DMF Acetic acid	—/ECH	155 35 81	AAS AAS FAAS	Preconcentration Preconcentration Preconcentration	［70］［71］［72］
Bulk polymerization	4-VP	Acetonitrile	AIBN/EGDMA	19	FAAS	SPE	［73］
Precipitation	2-PA，2-VP	Methanol	AIBN/EGDMA	72	FAAS	SPE	［74］
Surface imprinting	MAA	DMSO	APS/EGDMA		DPSV	ECS	［75］
Precipitation	ATMIX	Acetonitrile	AIBN/EGDMA		MFS	ECS	［76］
Precipitation	L	Acetonitrile	AIBN/EGDMA	2	FAAS	ECS	［77］
Bulk polymerization	BQSB，4-VP	Acetonitrile	APS/EGDMA		DPSV	ECS	［78］

Imprinting strategy	Monomer	Solvent	Initiator/Crosslinker	Adsorption capacity/（mg·g^-1）	Detection method	Application	Ref.
Sol-gel	CS	Acetic acid	—/Glutaraldehyde	125	ICP-OES	Membrane	［63］
Sol-gel	CS	Acetic acid	—/Glutaraldehyde	2 312	FAAS	Membrane	［64］
Sol-gel	CS	H₂O	—/Glutaraldehyde	89	ICP-OES	Preconcentration	［65］
Surface imprinting	Tu	Ethanol	—/Glutaraldehyde	156	ICP-OES	Preconcentration	［66］
Surface imprinting	MPTS	Toluene		91	FAAS	Preconcentration	［67］
Precipitation	4-VP	Ethanol	DMPA/MBA	73	ICP-OES	Preconcentration	［68］
Precipitation Precipitation Precipitation	VIM 4-VP VIM	Ethanol Ethanol Ethanol	DMPA/MBA DMPA/MBA DMPA/MBA	77 26 36	ICP-OES FAAS FAAS	Preconcentration Preconcentration Preconcentration	［68］［69］［69］
Sol-gel Surface imprinting Surface imprinting	CS MPTS CS	Acetic acid Methanol，DMF Acetic acid	—/ECH	155 35 81	AAS AAS FAAS	Preconcentration Preconcentration Preconcentration	［70］［71］［72］
Bulk polymerization	4-VP	Acetonitrile	AIBN/EGDMA	19	FAAS	SPE	［73］
Precipitation	2-PA，2-VP	Methanol	AIBN/EGDMA	72	FAAS	SPE	［74］
Surface imprinting	MAA	DMSO	APS/EGDMA		DPSV	ECS	［75］
Precipitation	ATMIX	Acetonitrile	AIBN/EGDMA		MFS	ECS	［76］
Precipitation	L	Acetonitrile	AIBN/EGDMA	2	FAAS	ECS	［77］
Bulk polymerization	BQSB，4-VP	Acetonitrile	APS/EGDMA		DPSV	ECS	［78］

Imprinting strategy	Monomer	Solvent	Initiator/crosslinker	Adsorption capacity/（mg·g^-1）	Detection method	Application	Ref.
Sol-gel	CS	DMSO	—/ECH	653	AAS	Preconcentration	［79］
Sol-gel	CS	Acetic acid	—/ECH	326	ICP-OES	Preconcentration	［81］
Surface imprinting	NB， CS	Acetic acid	—/Glyoxal	275	ICP-OES	Preconcentration	［82］
Bulk polymerization	APDC， DMG	Ethanol	AIBN/DVB		ETAAS	Preconcentration	［83］
Bulk polymerization	4-VP， 2-ABN	Toluene	AIBN/DVB	39	AAS	Preconcentration	［84］
Precipitation	4-VP， 8-AQ	2-Methoxyethanol	AIBN/EGDMA	60	ICP-OES	Preconcentration	［85］
Surface imprinting	AHTB	Methanol	AIBN/EGDMA	60	AAS	Preconcentration	［87］
Precipitation Precipitation Precipitation	ATU ATU 4-VP	Methanol DMF H₂O Methanol	AIBN/EGDMA AIBN/EGDMA AIBN/EGDMA	46 83	AAS AAS DPSV	Preconcentration Preconcentration ECS	［89］［90］［91］

Research Progress in Preparation and Application of Precious Metal Ion-Imprinted Polymers

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