In Situ Synthesis and Structural Analysis of Copper-Dipyridine Tetrazole

doi:10.11944/j.issn.1000-0518.2019.02.180190

Chinese Journal of Applied Chemistry ›› 2019, Vol. 36 ›› Issue (2): 223-229.DOI: 10.11944/j.issn.1000-0518.2019.02.180190

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In Situ Synthesis and Structural Analysis of Copper-Dipyridine Tetrazole

CHEN　Shaopeng^a,TAN　Yuhui^a^*(),YANG　Kang^a,LI　Chao^a,ZHOU　Haitiao^a,YANG　Shaoping^b^*(),LUO　Ziyu^a,TANG　Yunzhi^a

^aSchool of Materials and Chemical Engineering,Jiangxi University of Science and Technology,Ganzhou,Jiangxi 341000,China
^bSchool of Mechanical & Material Engineering,Wuzhou University,Wuzhou,Guangxi 543002,China;

Received:2018-05-24 Published:2019-02-01 Online:2019-01-31
Contact: TAN　Yuhui,YANG　Shaoping
Supported by:
Supported by the National Natural Science Foundation of China(No.21471070, No.21761013, No.21671086, No.21461010), the Program of Jiangxi Provincial Science and Technology Department(No.20153BCB22006)

Abstract

Abstract:

Hydrothermal reaction of 5,5'-dicyano-3,3'-bipyridyl ligands and sodium azide in the presence of the Lewis acid CuSO₄ in water and ethanol provided a novel metal organic tetrazole complex. X-ray single crystal diffraction analysis shows that this complex belongs to a tetragonal system with P4/ncc space group. This complex displays an interesting infinite two-dimensional(2D) network structure bridge linked by the pyridyl N atoms. The highly disordered sulfate around the central metals are likely to become ordered at low temperatures, leading to structural phase changes. The packing diagram of the crystal structure shows a butterfly hairpin shape. The highly nitrogenated structure allows this complex to be a potential high-energy material.

Key words: tetrazole complex, pyridyl, two-dimensional network structure

CHEN　Shaopeng, TAN　Yuhui, YANG　Kang, LI　Chao, ZHOU　Haitiao, YANG　Shaoping, LUO　Ziyu, TANG　Yunzhi. In Situ Synthesis and Structural Analysis of Copper-Dipyridine Tetrazole[J]. Chinese Journal of Applied Chemistry, 2019, 36(2): 223-229.

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In Situ Synthesis and Structural Analysis of Copper-Dipyridine Tetrazole

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