Corrosion Inhibition of Q235 Steel by Moxifloxacin in Hydrochloric Acid Solution

doi:10.11944/j.issn.1000-0518.2017.08.170039

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (8): 955-964.DOI: 10.11944/j.issn.1000-0518.2017.08.170039

• Full Papers • Previous Articles Next Articles

Corrosion Inhibition of Q235 Steel by Moxifloxacin in Hydrochloric Acid Solution

ZHENG Xingwen^a^b^*(),GONG Min^b,CHEN Shilin^a

^aSchool of Chemical and Pharmaceutical Engineering
^bKey Laboratory of Material Corrosion and Protection of Sichuan Province,Sichuan University of Science & Engineering,Zigong,Sichuan 643000,China

Received:2017-02-20 Accepted:2017-05-24 Published:2017-07-25 Online:2017-07-26
Contact: ZHENG Xingwen
Supported by:
Supported by Talent Project of Sichuan University of Science & Engineering(No.2016RCL11) , the Open Funds of Material Corrosion and Protection Key Laboratory of Sichuan Province(No.2016CL03)

Abstract

Abstract:

In order to develop new environment-friendly corrosion inhibitors, the corrosion inhibition of Q235 steel by moxifloxacin in 1 mol/L HCl solution and its mechanism were investigated using electrochemical measurements, mass loss method and quantum chemistry calculation. The results reveal that moxifloxacin is an effective mixed-type inhibitor with a predominantly cathodic action for the corrosion of Q235 steel in HCl solution. The inhibition efficiency increases with increased concentration of the inhibitor, but decreases with incremental temperature. The adsorption of moxifloxacin on steel surface is a spontaneous process, and obeys the Langmuir isotherm as well as the El-Awady thermodynamic-kinetic model. Accordingly, the thermodynamic and kinetic parameters were calculated and discussed. Moreover, quantum chemistry calculation was employed to give further insight into the inhibition mechanism of moxifloxacin, and the results showed that the corrosion inhibition of moxifloxacin was caused by physical adsorption and chemical adsorption.

Key words: moxifloxacin, Q235 steel, corrosion inhibitor, adsorption

ZHENG Xingwen, GONG Min, CHEN Shilin. Corrosion Inhibition of Q235 Steel by Moxifloxacin in Hydrochloric Acid Solution[J]. Chinese Journal of Applied Chemistry, 2017, 34(8): 955-964.

References

[1]	Gece G. Drugs:A Review of Promising Novel Corrosion Inhibitors[J]. Corros Sci,2011,53(12):3873-3898.
[2]	ZHENG Qingsi. Overview of the Clinical Application of Moxifloxacin Hydrochloride[J]. Acta Med Sin,2014,27(1):195-197(in Chinese). 郑清四. 盐酸莫西沙星的临床应用进展[J]. 华夏医学,2014,27(1):195-197.
[3]	LU Dingqiang,WANG Weibao,LING Youquan,et al.Progress in Synthesis and Applications of Moxifloxacin Hydrochloride[J]. Mod Chem Ind,2014,34(2):33-37(in Chinese). 卢定强,王维胞,凌岫泉,等. 新一代喹诺酮类盐酸莫西沙星的合成及应用研究进展[J]. 现代化工,2014,34(2):33-37.
[4]	YAN Yin,LIU Ruiquan. Synthesis of Aryloxymethyl Imidazolinium Quaternary Ammonium Salt and Its Evaluation as a Corrosion Inhibitor[J]. Chinese J Appl Chem,2014,31(7):852-859(in Chinese). 燕音,刘瑞泉. 芳氧亚甲基咪唑啉季铵盐的合成及缓蚀性能评价[J]. 应用化学,2014,31(7):852-859.
[5]	WEI Jian,XIE Bin,LAI Chuan,et al.Synthesis, Characterization and Corrosion Inhibition of N,N-Diethylammonium O,O'-(2-Methyl-2,4-pentylene) Dithiophosphate[J]. Chinese J Appl Chem,2016,33(2):190-199(in Chinese). 魏健,谢斌,赖川,等. O,O'-(2-甲基-2,4-亚戊基)二硫代磷酸-N,N-二乙铵的合成、表征及缓蚀性能评价[J]. 应用化学,2016,33(2):190-199.
[6]	LI Xianghong,DENG Shuduan,FU Hui. Corrosion Inhibition of 2-Aminopyrimidine for Steel in Hydrochloric Acid Media[J]. Chinese J Appl Chem,2012,29(2):209-215(in Chinese). 李向红,邓书端,付惠. 2-氨基嘧啶在盐酸介质中对钢的缓蚀性能[J]. 应用化学,2012,29(2):209-215.
[7]	Zheng X,Zhang S,Li W,et al.Investigation of 1-Butyl-3-Methyl-1H-menzimidazolium Iodide as Inhibitor for Mild Steel in Sulfuric Acid Solution[J]. Corros Sci,2014,80(3):383-392.
[8]	Zheng X,Zhang S,Gong M,et al.Experimental and Theoretical Study on the Corrosion Inhibition of Mild Steel by 1-Octyl-3-methylimidazolium L-Prolinate in Sulfuric Acid Solution[J]. Ind Eng Chem Res,2014,53(42):16349-16358.
[9]	SU Tiejun,LI Kehua,LUO Yunbai. Inhibition Behavior of 1-Phenylaminomethylbenzimidazole for Mild Steel in Hydrochloric Acid[J]. Chinese J Appl Chem,2015,32(4):464-471(in Chinese). 苏铁军,李克华,罗运柏. 盐酸中1-苯胺甲基苯并咪唑对碳钢的缓蚀行为[J]. 应用化学,2015,32(4):464-471.
[10]	LI Mingli,LIU Dan,CAO Shuyun,et al.Corrosion Inhibition of Q235 Steel in HCl Solution by Brönsted Acid Ionic Liquid[J]. J Chinese Soc Corros Prot,2015,35(5):400-406(in Chinese). 李明丽,刘丹,曹淑云,等. 盐酸介质中Brönsted酸离子液体对Q235钢的缓蚀行为[J]. 中国腐蚀与防护学报,2015,35(5):400-406.
[11]	ZHANG Honghong,XIE Yan,LIU Yuanwei,et al.Inhibition of Mild Steel Corrosion in Hydrochloric Acid Solution by Salicylaldehyde Thiosemicarbazone[J]. Chinese J Appl Chem,2015,32(6):720-725(in Chinese). 张红红,谢彦,刘元伟,等. 盐酸介质中水杨醛缩氨基硫脲对碳钢的缓蚀作用[J]. 应用化学,2015,32(6):720-725.
[12]	CHEN Wen,GUAN Chunping,YANG Shenming,et al.Corrosion Inhibition of Equisetum Ramosissimum Extractive for Carbon Steel in Hydrochloric Acid Solution[J]. J Chinese Soc Corros Prot,2016,36(2):177-184(in Chinese). 陈文,管春平,杨申明,等. 节节草提取物在盐酸介质中对碳钢的缓蚀行为研究[J]. 中国腐蚀与防护学报,2016,36(2):177-184.
[13]	WANG Chunxia,CHEN Jingping,ZHANG Xiaohong,et al.Corrosion Inhibition of Octyl Isoquinolinium Bromide on Q235 Carbon Steel in HCl Solution[J]. J Chinese Soc Corros Prot,2016,36(3):245-252(in Chinese). 王春霞,陈敬平,张晓红,等. 溴化N-辛烷异喹啉在盐酸溶液中对Q235碳钢的缓蚀行为[J]. 中国腐蚀与防护学报,2016,36(3):245-252.
[14]	Oguzie E E,Enenebeaku C K,Akalezi C O,et al.Adsorption and Corrosion-Inhibiting Effect of Dacryodis Edulis Extract on Low-Carbon-Steel Corrosion in Acidic Media[J]. J Colloid Interface Sci,2010,349:283-292.
[15]	Hegazy M A,Badawi A M, Rehim S S A E, et al. Corrosion Inhibition of Carbon Steel Using Novel N-(2-(2-Mercaptoacetoxy)ethyl)-N,N-dimethyl Dodecan-1-aminium Bromide During Acid Pickling[J]. Corros Sci,2013,69(2):110-122.
[16]	Cao Z,Tang Y,Cang H,et al.Novel Benzimidazole Derivatives as Corrosion Inhibitors of Mild Steel in the Acidic Media.Part II:Theoretical Studies[J]. Corros Sci,2014,83(6):292-298.
[17]	LIAN Bingjie,SHI Zemin,XU Hui,et al.Adsorption Mechanism of Azole Corrosion Inhibitors on Cu Surface[J]. Surf Technol,2015,44(12):19-26(in Chinese). 廉兵杰,石泽民,徐慧,等. 唑类缓蚀剂在铜表面的吸附机理[J]. 表面技术,2015,44(12):19-26.
[18]	Obi-Egbedi N O,Obot I B. Inhibitive Properties, Thermodynamic and Quantum Chemical Studies of Alloxazine on Mild Steel Corrosion in H2SO4[J]. Corros Sci,2011,53(1):263-275.

Corrosion Inhibition of Q235 Steel by Moxifloxacin in Hydrochloric Acid Solution

RichHTML

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Ning YUAN, Jie MA, Jin-Ling ZHANG, Jian-Sheng ZHANG. Preparation of PCN-6（M） Bimetallic Organic Framework Materials by Steam-assisted Method and Their CO₂ and CH₄ Adsorption Performance [J]. Chinese Journal of Applied Chemistry, 2023, 40(6): 896-903.
[2]	Chen-Li HAO, Qing-Wei DING, Shi-Chang JIA, Yang-Bo MAO, Song-Bai WANG, Jun MA. Adsorption of Methylene Blue on Titanate Nanotubes Modified with Lipoic Acid [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 749-757.
[3]	Qin ZHANG, Wen-Bin LIU, Li-Jiao FAN, Yu-Ming XIE, Guo-Lin HUANG. Research Progress in the Preparation of Functionalized Mesoporous Silica and Its Application in Adsorption and Separation of Uranium from Water [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 169-187.
[4]	Yue-Hua ZHAO, Da-Peng WANG. Coadsorption Kinetics of Amino‑Functionalized Graphene Oxide and Fatty Acids at the Water/Oil Interface [J]. Chinese Journal of Applied Chemistry, 2022, 39(8): 1274-1284.
[5]	Cong-Jun CAO, Han-Xiao MA, Cheng-Min HOU, Xiao-Jian DING, Biao GUAN. Adsorption of Cu（Ⅱ） from Solution by Modified Magnetic Ethyl Cellulose [J]. Chinese Journal of Applied Chemistry, 2022, 39(6): 969-979.
[6]	Song-Song XUE, Zheng-Feng XIE, Jia-Wei HE, Tian-Yi ZHANG, Bao-Ping XIA, Yu-Qin LI. Synthesis of Sulfonylhydrazone Probe with High Selectivity and Rapid Identification of Hg（Ⅱ） Ion and Its Application in Adsorption [J]. Chinese Journal of Applied Chemistry, 2022, 39(5): 760-768.
[7]	Jian-Shuang ZHANG, Mei-Zhen GAO, Meng-Yao WANG, Qi SHI, Jin-Xiang DONG. Zeolitic Imidazolate Framework ZIF‑71 for Adsorption and Separation of 2，3‑Butanediol/1，3‑Propanediol From Dilute Aqueous Solutions [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1735-1745.
[8]	Ding-Kun YUAN, Wei-Fan CHU, Jia-Hui NI. Preparation of Copper Ferrocyanide⁃Polyacrylamide/ Carboxymethyl Cellulose/Graphene Composite Hydrogel and Its Adsorption Performance of Rubidium [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1746-1756.
[9]	LIU Wen-Bin, YANG Sha-Sha, HUANG Guo-Lin, FAN Li-Jiao, XIE Yu-Ming. Synthesis of Phosphorylated Xanthan Gum/Graphene Oxide and Its Selective Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 658-667.
[10]	TIAN Long, DOU Wei-Xin, YANG Wei-Ting, WANG Cheng. Size Effect of ZIF-8 on the Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 0-0.
[11]	TIAN Long, DOU Wei-Xin, YANG Wei-Ting, WANG Cheng. Size Effect of ZIF-8 on the Adsorption of Uranium [J]. Chinese Journal of Applied Chemistry, 2021, 38(1): 84-91.
[12]	WANG Fengping, HU Xiaoqiang, DING Yanwei, LI Jielan, ZHANG Wei. Synergistic Inhibition Effect of Potassium Sorbate and Zn²⁺ Ions on Corrosion of Q235 Steel in NaCl Solution [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 960-968.
[13]	SHI Yanlong, FENG Xiaojuan, YANG Ruihua, WANG Jianrong. Preparation of Superhydrophobic and Superoleophilic Corn Straw Fibers Oil Absorbents and Application to the Removal of Spilled Oil from Water [J]. Chinese Journal of Applied Chemistry, 2020, 37(7): 793-802.
[14]	ZHAO Bingbing, DENG Dongyang, CHEN Guihua, SONG Qingmei, FU Jianping, ZHANG Sukun, ZHOU Chengyong, JÜ Yongming. Main Influencing Factors and Removal Mechanism of Phosphate Anions by Chitosan-Fe(III) Composite Gel Beads [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 673-682.
[15]	LIN Yongcen, DONG Xue, MA Yuqin, ZHAO Lang. Designed Formation of NiCo-Layered Double Hydroxide Derived from Zeolitic Imidazolate Framework-67 with Selective Dye Adsorption Property [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 683-694.