Catalytic Synthesis and Purification of Bisphenol S by the Products of Converted Disodium Naphthalenedisulfonate

doi:10.11944/j.issn.1000-0518.2017.05.160331

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (5): 550-556.DOI: 10.11944/j.issn.1000-0518.2017.05.160331

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Catalytic Synthesis and Purification of Bisphenol S by the Products of Converted Disodium Naphthalenedisulfonate

ZHANG Tianyong^a^b,YANG Yuqiu^a^b,LI Bin^a^b^*(),WANG Zhichao^a^b,ZHANG Guoling^c^d,CHEN Song^a,AN Jing^c^d

^aTianjin Key Laboratory of Applied Catalysis Science and Engineering,School of Chemical Engineering and Technology,Tianjin University,Tianjin 300354,China
^bTianjin Engineering Research Center of Functional Fine Chemicals,Tianjin 300354,China
^cKemai Chemical Co., Ltd.,Tianjin 300270,China
^dTianjin Enterprises Key Laboratory of Green Rubber Auxiliary,Tianjin 300270,China

Received:2016-08-19 Accepted:2016-11-04 Published:2017-05-02 Online:2017-05-02
Contact: LI Bin
Supported by:
Supported by the National Natural Science Foundation of China(No.21276187), the Tianjin Science and Technology Innovation Platform Program(No.14TXGCCX00017), the Tianjin Municipal Natural Science Foundation(No.16JCYBJC20800)

Abstract

Abstract:

Transformation of disodium 2,6-naphthalenedisulfonate into 2,6-naphthalenedisulfonic acid was catalyzed by cationic exchange resin and the 2,6-naphthalenedisulfonic acid was used to catalyze the synthesis of bisphenol S(BPS). The effects of the reaction time, temperature and the amount of resin were investigated. The optimized exchange process was applied as follows:After disodium 2,6-naphthalenedisulfonate was completely dissolved, 37 times of 001×7 strong acidic polystyrene type cationic exchange resin were added into the system. The converted products were used to catalyze the synthesis of BPS. The yield of crude product BPS reached 93.5% and the mass fraction of BPS was 92.3%. Crude BPS was purified by adsorbent without organic solvent. The mass fraction of the product obtained by the process is high. The improved process is easy to be operated and industrialized. The improved purification process was applied as follows:Firstly 7 g of crude BPS was dissolved in 300 g hot water. Then 0.5 g sepiolite and 0.2 g active carbon were added under stirring. The wet product was dissolved in 180 g hot water again and another 0.3 g sepiolite was added. After 1 hour of stirring, a white product was obtained and the purity of BPS reached 99.7%. The water could be recycled, resulting in increasing yield of product BPS to 82.9% at the same time.

Key words: bisphenol S, disodium naphthalenedisulfonate, cationic exchange resin, purification, adsorbent

ZHANG Tianyong, YANG Yuqiu, LI Bin, WANG Zhichao, ZHANG Guoling, CHEN Song, AN Jing. Catalytic Synthesis and Purification of Bisphenol S by the Products of Converted Disodium Naphthalenedisulfonate[J]. Chinese Journal of Applied Chemistry, 2017, 34(5): 550-556.

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Catalytic Synthesis and Purification of Bisphenol S by the Products of Converted Disodium Naphthalenedisulfonate

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