Synthesis and Molecular Structure of Copper Complex of Terpyridine Bearing with Imidazolium Salts

doi:10.11944/j.issn.1000-0518.2016.02.150194

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (2): 206-212.DOI: 10.11944/j.issn.1000-0518.2016.02.150194

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Synthesis and Molecular Structure of Copper Complex of Terpyridine Bearing with Imidazolium Salts

MU Huarong^a,BI Xin^b,SUN Jing^b,YAN Chaoguo^b^*()

^aCollege of Chemical Engineering,Yangzhou Polytechnic Institute,Yangzhou,Jiangsu 225127,China
^bCollege of Chemistry & Chemical Engineering,Yangzhou University,Yangzhou,Jiangsu 225002,China

Received:2015-06-11 Accepted:2015-11-12 Published:2016-02-01 Online:2016-02-01
Contact: YAN Chaoguo
Supported by:
Supported by the National Natural Science Foundation of China(No.20972132, No.21301119)

Abstract

Abstract:

A series of functionalized terpyridine ligands containing alkyl bridged imidazolium salts were designed and prepared in convenient manner. The transition metal complexes of these functionalized terpyridine ligands were investigated and the single crystal structure of Cu complex was successfully determined by X-ray diffraction. In the copper complex, Cu²⁺ was coordinated with two terpyridine units to form distorted octahedron symmetry. Monoclinic, space group P 21/c; a=1.7229(3) nm, b=1.5924(2) nm, c=2.1590(3) nm, α=90°, β=101.332(2)°, γ=90°, M_r=1298.09, V=5.8078(15) nm³, D_c=1.485 mg/m³, Z=4, F(000)=2684.

Key words: terpyridine, imidazolium salt, transition metal complex, crystal structure

MU Huarong, BI Xin, SUN Jing, YAN Chaoguo. Synthesis and Molecular Structure of Copper Complex of Terpyridine Bearing with Imidazolium Salts[J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 206-212.

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Synthesis and Molecular Structure of Copper Complex of Terpyridine Bearing with Imidazolium Salts

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