Synthesis and Crystal Structure of N,N',N″-Tris(2-hydroxypropyl)-1,4,7-triazacyclodecane Co(Ⅱ) Complex

doi:10.11944/j.issn.1000-0518.2016.02.150236

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (2): 200-205.DOI: 10.11944/j.issn.1000-0518.2016.02.150236

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Synthesis and Crystal Structure of N,N',N″-Tris(2-hydroxypropyl)-1,4,7-triazacyclodecane Co(Ⅱ) Complex

GUO Hui(),ZHANG KeYao,LI Na,ZHANG Shuan

College of Pharmacy,Shaanxi University of Chinese Medicine,Xianyang,Shaanxi 712046,China

Received:2015-07-08 Accepted:2015-11-17 Published:2016-02-01 Online:2016-02-01
Contact: GUO Hui
Supported by:
Supported by the National Natural Science Foundation of China(No.81001669), the Natural Science Foundation research project of Shaanxi Province(No.09JK393, No.12JK1013), the Chinese Medicine and New Drug Research Key Laboratory Project of Shaanxi Province(No.12JS039)

Abstract

Abstract:

One novel macrocyclic triamine derived ligand N,N',N″-tris(2-hydroxypropyl)-1,4,7-triazacyclodecane and its transition metal complexes, [CoL] [ClO₄]₂ were synthesized and characterized by physico-chemical and spectroscopic methods. The crystal structure of [CoL][ClO₄]₂ was determined. The complex belongs to crystallographic system of monoclinic and space group:P2/N(1). The complex is hexacoordinate and the center Co atom exists in a distortion three prism coordination environment. The six coordinating atoms come from three nitrogen atoms and three oxygen atoms of the ligand. The average Co—N bond length and Co—O bond length are 0.2114(6) nm and 0.2097(6) nm, respectively. A regular supramolecular network structure are formed through the hydrogen bonding O••••H—O between three oxygen atoms of the perchlorate with three oxygen atoms of the neighboring ligands.

Key words: m-acrocyclic triamine derivative, synthesis, crystal structure, Co(Ⅱ) complex

GUO Hui, ZHANG KeYao, LI Na, ZHANG Shuan. Synthesis and Crystal Structure of N,N',N″-Tris(2-hydroxypropyl)-1,4,7-triazacyclodecane Co(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 200-205.

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Synthesis and Crystal Structure of N,N',N″-Tris(2-hydroxypropyl)-1,4,7-triazacyclodecane Co(Ⅱ) Complex

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