Synthesis and Characterization of Novel High Impact Strength Epoxy Vinyl Ester Resin

doi:10.11944/j.issn.1000-0518.2015.08.140416

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (8): 916-921.DOI: 10.11944/j.issn.1000-0518.2015.08.140416

• Full Papers • Previous Articles Next Articles

Synthesis and Characterization of Novel High Impact Strength Epoxy Vinyl Ester Resin

JIN Cheng^a^*(),WANG Erping^a,ZHU Yanhong^b,JIANG Jie^a,GU Lijun^c

^aNew United Group Company Limited, Changzhou, Jiangsu 213166, China
^bJiangsu Changhai Composite Materials Company Limited, Changzhou, Jiangsu 213102, China
^cKey Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Yunnan Minzu University, Kunming 650500, China

Received:2014-12-08 Accepted:2015-04-24 Published:2015-08-08 Online:2015-08-08
Contact: JIN Cheng
Supported by:
Supported by the State Ethnic Affairs Commission Opening Fund of Key Laboratory of Ethnic Medicine Resource Chemistry(No;MJY090103)

Abstract

Abstract:

With the introduction of flexible epoxy-terminated polyether(ETPE) as the monomer, herein, we reported a facile and efficient synthesis approach for novel epoxy vinyl ester resin(EVER-2) with high impact toughness. The resin was analyzed by Fourier-transform infrared(FTIR), ¹H nuclear magnetic resonance(¹H NMR) and ¹³C nuclear magnetic resonance(¹³C NMR) spectroscopy. Mechanical properties such as tensile strength, flexural strength, impact strength and heat distortion temperature were also determined for EVER-2. The cured resin containing 7.9% mass fraction of ETPE has outstanding performance on impact strength. SEM (scanning electron microscopy) analysis reveals that EVER-2 matrix displays a single-phase morphology and its galss fiber/EVER-2 composite(EVERL-2) exhibits better bonding between the matrix and glass fiber, which means that EVERL-2 can bear more impact strength than galss fiber/ EVER-1 composite(EVERL-1). Moreover, plausible toughening mechanisms of EVER-2 and EVERL-2 were proposed.

Key words: epoxy vinyl ester resin, epoxy-terminated polyether, impact strength, synthesis

CLC Number:

JIN Cheng, WANG Erping, ZHU Yanhong, JIANG Jie, GU Lijun. Synthesis and Characterization of Novel High Impact Strength Epoxy Vinyl Ester Resin[J]. Chinese Journal of Applied Chemistry, 2015, 32(8): 916-921.

References

[1]	Grishchuk S, Castellà N, Apostolov A A, et al.Structure and Properties of Vinyl Ester Resins Modified with Organophilic Synthetic Layered Silicates Bearing Non-and Co-reactive Intercalants[J]. J Compos Mater, 2012, 46:941-947.
[2]	Jin L, Agag T, Ishida H. Use of Allyl-Functional Benzoxazine Monomers as Replacement for Styrene in Vinyl Ester Resins[J]. Polym Int, 2013, 62(1):71-78.
[3]	Yang X J, Li S H, Tang X D, et al.Research on Preparation, Properties and UV Curing Behaviors of Novel Myrcene-Based Vinyl Ester Resin[J]. Adv Mater Res, 2013, 807:2826-2830.
[4]	Garg M S, Srivastava D. Effect of Glycidyl Methacrylate(GMA) Content on Thermal and Mechanical Properties of Ternary Blend Systems Based on Cardanol-Based Vinyl Ester Resin, Styrene and Glycidyl Methacrylate[J]. Prog Org Coat, 2014, 77(7):1208-1220.
[5]	ZHOU Runpei, CHEN Hui, FANG Qunying, et al.Study of High Toughness and Low Shrinkage MFE-5 Vinyl Ester Resin[J]. Fiber Reinf Plast Compos, 2000, (2):21-22(in Chinese). 周润培, 陈晖, 方群英, 等. 高韧性、低收缩MFE-5乙烯基酯树脂的研究[J]. 玻璃钢/复合材料, 2000, (2):21-22.
[6]	SU Jiang, JIANG Yonghua. Research on Toughening of MFE Vinyl Ester Resin[J]. Thermoset Resin, 2007, 22(1):33-35(in Chinese). 苏江, 蒋永华. MFE乙烯基酯树脂的增韧研究[J]. 热固性树脂, 2007, 22(1):33-35.
[7]	Auad M L, Frontini P M, Borrajo J, et al.Liquid Rubber Modified Vinyl Ester Resins: Fracture and Mechanical Behavior[J]. Polymer, 2001, 42(8):3723-3730.
[8]	Robinette E J, Ziaee S, Palmese G R. Toughening of Vinyl Ester Resin Using Butadiene-Acrylonitrile Rubber Modifiers[J]. Polymer, 2004, 45(18):6143-6154.
[9]	LU Shiping, WANG Tiantang, SHEN Wei. Property Study of Vinyl Ester Resin Toughened with BNR[J]. Fiber Reinf Plast Compos, 2002, (6):27-28(in Chinese). 陆士平, 王天堂, 沈伟. 丁腈橡胶增韧乙烯基酯树脂的性能研究[J]. 玻璃钢/复合材料, 2002, (6):27-28.
[10]	Wang S, Wang J L, Ji Q, et al.Miscibility and Morphologies of Poly(arylene ether phenyl phosphine oxide/sulfone) Copolymer/Vinyl Ester ResinMixtures and Their Cured Networks[J]. J Polym Sci, Part B:Polym Phys, 2000, 38(18):2409-2421.
[11]	ZHANG Hongjun, ZHOU Xiaodong, DAI Gance, et al.Toughening Glass Fiber Reinforced Vinyl Ester Resin Composite[J]. Polym Mater Sci Eng, 2005, 21(3):21-25 (in Chinese). 张宏军, 周晓东, 戴干策, 等. 玻璃纤维增强乙烯基酯树脂复合材料的增韧[J]. 高分子材料科学与工程, 2005, 21(3):21-25.
[12]	Rao B S, Mandec P J, Marechal E. Synthesis of Vinyl Ester Resins Evidence of Secondary Reactions by 13C NMR[J]. Polym Bull, 1986, 16(2/3):153-157.
[13]	Sultania M, Rai J S P, Srivastava D. Kinetic Modeling of Esterification of Cardanol-Based Epoxy Resin in the Presence of Triphenylphosphine for Producing Vinyl Ester Resin:Mechanistic Rate Equation[J]. J Appl Polym Sci, 2010, 118(4):1979-1989.
[14]	Gu L J, Jin C. Synthesis and Antitumor Activity of α-Aminophosphonates Containing Thiazole[5, 4-b]Pyridine Moiety[J]. Org Biomol Chem, 2012, 10(35):7098-7102.
[15]	Gu L J, Wang R, Jin C, et al.Novel Synthetic Route to α-Aminophosphonates Containing Benzothiazole Moiety[J]. Chinese J Chem, 2012, 30(10):2483-2487.
[16]	SU Lianzheng, JIN Cheng, GU Lijun. Improved Synthesis and Characterization of 1-Benzyl-3-Alkyl benzotriazolium Ionic Liquids[J]. Chinese J Appl Chem, 2013, 30(8):867-871(in Chinese). 宿连征, 金诚, 谷利军. 改进法合成1-苄基-3-烷基苯并三氮唑类离子液体及其表征[J]. 应用化学, 2013, 30(8):867-871.
[17]	Gu L J, Jin C, Guo J M, et al.A Novel Strategy for the Construction of Substituted Benzoxazoles via a Tandem Oxidative Process[J]. Chem Commun, 2013, 49(93):10968-10970.
[18]	Gu L J, Jin C, Zhang H T, et al.Copper-Catalyzed Aerobic Oxidative Cleavage of C—C Bonds in Epoxides Leading to Aryl Ketones[J]. J Org Chem, 2014, 79(17):8453-8456.
[19]	Gu L J, Jin C. Copper-Catalyzed Aerobic Oxidative Cleavage of C—C Bonds in Epoxides Leading to Aryl Nitriles and Aryl Aldehydes[J]. Chem Commun, 2015, 51(30):6572-6575.
[20]	Gu L J, Jin C, Zhang H T. Nickel N-Heterocyclic Carbene Catalyzed C—C Bond Formation:A New Route to Aryl Ketones[J]. Chem-Eur J, 2015, 21(24):8741-8744.
[21]	ZHAO Liying, MA Huiru, GUAN Jianguo. Influence of Polyether Segment Length on Mechanical Properties of Cured Epoxy Resins Based on Amino-Terminated Poly(ethylene glycol) and Diglycidyl Ether of Bisphenol[J]. Chem J Chinese Univ, 2009, 30(7):1454-1458(in Chinese). 赵立英, 马会茹, 官建国. 聚醚链段长度对氨基聚醚-环氧树脂力学性能的影响[J]. 高等学校化学学报, 2009, 30(7):1454-1458.
[22]	Sultania M, Yadaw S B, Rai J S P, et al. Laminates Based on Vinyl Ester Resin and Glass Fabric A Study on the Thermal, Mechanical and Morphological Characteristics[J]. Mat Sci Eng A-Struct, 2010, 527(18):4560-4570.

Synthesis and Characterization of Novel High Impact Strength Epoxy Vinyl Ester Resin

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jia-Zheng LI, Shu-Zhong HE. Research Progress of Total Synthesis of Polygalolides [J]. Chinese Journal of Applied Chemistry, 2023, 40(5): 615-624.
[2]	Zhen-Bang LIU, Shuo ZHANG, Yu BAO, Ying-Ming MA, Wei-Qi LIANG, Wei WANG, Ying HE, Li NIU. Progress of Application Research on Cheminformatics in Deep Learning [J]. Chinese Journal of Applied Chemistry, 2023, 40(3): 360-373.
[3]	Yang LIU, Hai-Bao ZHANG, Qiang CHEN. Optimization of Process Parameters for Ammonia Synthesis by Nanosecond Pulsed Dielectric Barrier Discharge Plasma [J]. Chinese Journal of Applied Chemistry, 2023, 40(2): 268-276.
[4]	Rong CAO, Jie-Zhen XIA, Man-Hua LIAO, Lu-Chao ZHAO, Chen ZHAO, Qi WU. Theoretical Research Progress of Single Atom Catalysts in Electrochemical Synthesis of Ammonia [J]. Chinese Journal of Applied Chemistry, 2023, 40(1): 9-23.
[5]	Dan MENG, Kai-Yuan ZHENG, Shan-Shan CHEN, Zhao-Long ZHUO, Li-Li WANG. Preparation and Luminescence Properties of Silicon and Nitrogen Co⁃doped Carbon Dots Phosphors [J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1766-1773.
[6]	WU Zhi-Qiang, HAN Xin-Ning, LIU Yang, WANG Gang, ZHAN Hai-Juan, LIU Wan-Yi. Research Progress on Synthesis of Bis(indolyl)methanes under Aqueous or Solvent-free Catalysis [J]. Chinese Journal of Applied Chemistry, 2021, 38(8): 881-896.
[7]	BO Chun-Hui, JIANG Wei-Jia, WANG Yu-Gao, SHI Li-Hong, DONG Chuan. Research Progress on Synthesis of Coal-based Carbon Quantum Dots [J]. Chinese Journal of Applied Chemistry, 2021, 38(7): 767-788.
[8]	LIU Yang, ZHANG Hai-Bao, CHEN Qiang. Research Progress on Ammonia Synthesis Using Low Temperature Plasma [J]. Chinese Journal of Applied Chemistry, 2021, 38(6): 622-636.
[9]	LIU Yu-Ting, SUN Jia-Xi, YIN Da-Wei. Research Progress on the Synthesis and Application of Ferroncene-based Polymers [J]. Chinese Journal of Applied Chemistry, 2021, 38(4): 343-366.
[10]	XIE Zhi-Qi, ZHANG Ting, LI Ying-Wei, WANG Zhou-Jun, DAI Fei, ZHANG Rui-Rui, LIU Rui-Xia. Effect of Synthesis Conditions of Vanadium Phosphorus Oxygen (VPO) Catalyst on Catalytic Performance for Selective Oxidation of Butane [J]. Chinese Journal of Applied Chemistry, 2021, 38(4): 414-421.
[11]	GAO Feng, XU Zi-Di, GUAN Chun-Qian, WANG Yan, ZANG Yun-Hao, QU Jiang-Ying. Green Controllable Synthesis of Sulfur/Graphene Aerogel and Performance of Lithium Sulfur Battery [J]. Chinese Journal of Applied Chemistry, 2021, 38(4): 439-446.
[12]	BI Yipiao, GONG Xue, YANG Fa, RUAN Mingbo, SONG Ping, XU Weilin. Polyvalent MnO_x/C Electrocatalyst for Highly Efficient Nitrogen Reduction Reaction [J]. Chinese Journal of Applied Chemistry, 2020, 37(9): 1048-1055.
[13]	ZHANG Baohua, SHI Lanxiang. One-Pot Synthesis of Aryl/Heteroaryl Aminomethylene Bisphosphonates [J]. Chinese Journal of Applied Chemistry, 2020, 37(8): 877-882.
[14]	MENG Yating, JIAO Yuan, ZHANG Yuan, GAO Yifang, LU Wenjing, LIU Yang, DONG Chuan. Synthesis of Red Emission Fluorescent Carbon Dots and Its Application for Detection of Persulfate [J]. Chinese Journal of Applied Chemistry, 2020, 37(6): 719-725.
[15]	CHEN Lin, MIN Man, LIN Jidi. Synthesis and Antioxidation Activity of 3-Amino-7,8-dimethoxycoumarin and Its Derivatives [J]. Chinese Journal of Applied Chemistry, 2020, 37(12): 1420-1425.