应用化学 ›› 2009, Vol. 26 ›› Issue (6): 657-661.

• 研究论文 • 上一篇    下一篇

新型咔唑羧酸类衍生物的合成、表征及光学性质研究

,,宋文利,,,,,   

  1. 安徽大学化学化工学院
  • 收稿日期:2008-05-05 修回日期:2008-08-04 出版日期:2009-06-10 发布日期:2009-06-10

Synthesis, Characterization and OpticalProperties of a novel Carbazole carboxylate derivative

  • Received:2008-05-05 Revised:2008-08-04 Published:2009-06-10 Online:2009-06-10

摘要:

以咔唑为原料,合成了一种新型的咔唑类衍生物-9-异辛基-3, 6-咔唑二丙烯酸,其结构经1H NMR, IR和MS表征。运用UV、单光子液体荧光和固体荧光研究了中间体和目标产物的线性光学性质。结果表明:该化合物有望成为具有应用价值的发光材料。

关键词: 咔唑, 丙烯酸, Heck反应, 咔唑, 丙烯酸, Heck反应

Abstract:

A new carbazole derivative, 9-isooctyl-3, 6-carbazole dicrylic acid, was synthesized and characterized by 1H NMR IR and MS. UV, one-photon excited fluorescence spectra and solid fluorescence of the intermediate and title production were investigated. The results showed that the compound will become the appliable luminescent materials.

Key words: carbazole, crylic acid, Heck Reaction