1-二茂铁基-3-[(9-乙基)咔唑-3-基]丙烯酮的合成及三阶非线性光学性质

doi:10.11944/j.issn.1000-0518.2015.09.150020

摘要/Abstract

摘要：

合成了一个新的非线性光学(NLO)有机材料1-二茂铁基-3-[(9-乙基)咔唑-3-基]丙烯酮(FCAK),并通过NMR、IR、MS和元素分析等技术手段进行了表征。采用粉末Nd∶YAG激光技术测定了标题化合物的三阶非线性光学性质并确定了相关参数。激光脉冲为4 ns时,非线性折射率n₂=-3.5×10^-18 m²/W,非线性吸收系数β=-2.7×10^-11 m/W,三阶非线性极化率χ⁽³⁾=2.04×10^-12 esu,三阶非线性分子超极化率γ=1.1×10^-30 esu。激光脉冲为21 ps时,n₂=0.55×10^-18 m²/W,β=-0.6×10^-11 m/W,χ⁽³⁾=3.4×10^-13 esu,γ=0.13×10^-30 esu。

关键词: 二茂铁衍生物, 二茂铁基-[(乙基)咔唑-基]丙烯酮, 查耳酮, 合成, 非线性光学性质

Abstract:

A new nonlinear optical(NLO) organic material, 1-ferrocenyl-3-((9-ethyl) carbazole-3-yl) acrylic ketone(FCAK), was synthesized and characterized by IR, MS, NMR and element analysis. The title compound exhibits third-order nonlinear optical properties. The related parameters were obtained by powder technique using the Nd∶YAG laser. When the laser pulse is four nanoseconds, the nonlinear refractive index n₂ is -3.5×10^-18 m²/W, the nonlinear absorption coefficient β is -2.7×10^-11 m/W, the third-order nonlinear polarizability χ⁽³⁾ is 2.04×10^-12 esu, the third-order nonlinear molecular hyperpolarizability γ is 1.1×10^-30 esu. When the laser pulse is twenty one picoseconds, n₂ is 0.55×10^-18 m²/W, β is -0.6×10^-11 m/W, χ⁽³⁾ is 3.4×10^-13 esu, γ is 0.13×10^-30 esu.

Key words: ferrocenyl derivative, ferrocenyl-((ethyl)carbazole-yl)acrylic ketone, Chalcone, synthesis, nonlinear optical property

石玉芳,孙金鱼,刘成琪,赵明根. 1-二茂铁基-3-[(9-乙基)咔唑-3-基]丙烯酮的合成及三阶非线性光学性质[J]. 应用化学, 2015, 32(9): 994-998.

SHI Yufang,SUN Jinyu,LIU Chengqi,ZHAO Minggen. Synthesis and Nonlinear Optical Properties of 1-Ferrocenyl-3-((9-ethyl)carbazole-3-yl)acrylic Ketone[J]. Chinese Journal of Applied Chemistry, 2015, 32(9): 994-998.

参考文献

[1]	Venkatram N,Akundi M A,Narayana Rao D. Nonlinear Absorption, Scattering and Optical Limiting Studies of CdS Nanoparticles[J]. Opt Express,2005,13(3):867-872.
[2]	Prabhu A N,Jayarama A,Subrahmanya B K,et al.Growth, Characterization and Structural Investigation of a Novel Nonlinear Optical Crystal[J]. J Mol Struct,2013,1031(1):79-84.
[3]	QIU Yongqing,GAI Xiulan,YANG Bin,et al.Theoretical Calculation of Nonlinear Properties of Substituent Chalcone and Its Derivatives Using Finite Field(FF)/PM3[J]. J Northeast Normal Univ(Nat Sci Edn),2000,32(1):56-59(in Chinese). 仇永清,盖秀兰,杨滨,等. 取代查尔酮衍生物非线性光学性质的FF/PM3理论计算[J]. 东北师大学报(自然科学版),2000,32(1):56-59.
[4]	LIU Yuting,FU Quejun,YIN Dawei,et al.The New Research Development of Functional Ferrocene Material[J]. New Chem Mater,2009,37(3):27-29(in Chinese). 刘玉婷,傅雀军,尹大为,等. 含二茂铁功能材料的最新研究进展[J]. 化工新型材料,2009,37(3):27-29.
[5]	Said A,Wamsley C,Hagan D J,et al.Third and Fifth-order Optical Nonlinearities in Organic Materials[J]. Chem Phys Lett,1994,228(6):646-650.
[6]	Zhan D,Zhang D,Zhu D,et al.Third and Fifth-order Optical Nonlinearities in a New Stilbazolium Derivative[J]. J Opt Soc Am B,2002,19(3):369-375.
[7]	Ravindra H J,Kiran A J,Chandrasekharan K,et al.Third Order Nonlinear Optical Properties and Optical Limiting in Donor/Acceptor Substituted 4-Methoxy Chalcone Derivatives[J]. Appl Phys B,2007,88(1):105-110.
[8]	Zhao M T,Singh B P,Prasad P N. A Systematic Study of Polarizability and Microscopic Third-order Optical Nonlinearity in Thiophene Oligomers[J]. J Chem Phys,1988,89:5535-5541.
[9]	Sun R,Yan B L,Ge J F,et al.Third-order Nonlinear Optical Properties of Unsymmetric Pentamethine Cyanine Dyes Possessing Benzoxazolyl and Benzothiazolyl Groups[J]. Dyes Pigm,2013,96(1):189-195.

[1]	李佳铮, 何述钟. 天然产物Polygalolides的全合成研究进展[J]. 应用化学, 2023, 40(5): 615-624.
[2]	刘振邦, 张硕, 包宇, 马英明, 梁蔚淇, 王伟, 何颖, 牛利. 深度学习在化学信息学中的应用研究进展[J]. 应用化学, 2023, 40(3): 360-373.
[3]	刘洋, 张海宝, 陈强. 纳秒脉冲介质阻挡放电等离子体合成氨工艺条件优化[J]. 应用化学, 2023, 40(2): 268-276.
[4]	曹蓉, 夏杰桢, 廖漫华, 赵路超, 赵晨, 吴琪. 单原子催化剂在电化学合成氨中的理论研究进展[J]. 应用化学, 2023, 40(1): 9-23.
[5]	田秦秦, 张佳, 陈峙, 何炜, 张生勇. 泊沙康唑的合成、检测及其临床应用研究进展[J]. 应用化学, 2022, 39(8): 1177-1189.
[6]	孟丹, 郑开元, 陈珊珊, 卓钊龙, 王丽丽. 硅、氮共掺杂碳点荧光粉的制备及发光性能[J]. 应用化学, 2022, 39(11): 1766-1773.
[7]	吴之强, 韩新宁, 刘阳, 王刚, 詹海鹃, 刘万毅. 水相或无溶剂绿色催化合成双吲哚基甲烷研究进展[J]. 应用化学, 2021, 38(8): 881-896.
[8]	薄纯辉, 姜维佳, 王玉高, 石利红, 董川. 煤基碳量子点合成研究进展[J]. 应用化学, 2021, 38(7): 767-788.
[9]	刘洋, 张海宝, 陈强. 低温等离子体合成氨研究进展[J]. 应用化学, 2021, 38(6): 622-636.
[10]	刘玉婷, 孙嘉希, 尹大伟. 含二茂铁基聚合物的合成及应用研究进展[J]. 应用化学, 2021, 38(4): 343-366.
[11]	谢志琦, 张婷, 李英崴, 王周君, 代飞, 张瑞锐, 刘瑞霞. 钒磷氧合成条件对丁烷选择性氧化催化性能的影响[J]. 应用化学, 2021, 38(4): 414-421.
[12]	毕一飘, 宫雪, 杨发, 阮明波, 宋平, 徐维林. 多价MnO_x/C电催化剂用于高效氮还原反应[J]. 应用化学, 2020, 37(9): 1048-1055.
[13]	张宝华, 史兰香. 一锅法合成芳(杂环)胺亚甲基双膦酸四乙酯[J]. 应用化学, 2020, 37(8): 877-882.
[14]	孟雅婷, 焦媛, 张羱, 高艺芳, 路雯婧, 刘洋, 董川. 红色荧光碳点的制备及其对过硫酸根的检测[J]. 应用化学, 2020, 37(6): 719-725.
[15]	张转芳, 郑建华, 辛建娇, 赵楠, 陈洁, 许芮. Keggin型多酸基晶态材料的合成及催化性能[J]. 应用化学, 2020, 37(4): 481-488.