过渡金属基层状双羟基化合物的调控及其在电化学水氧化中的应用

doi:10.11944/j.issn.1000-0518.2018.08.180130

摘要/Abstract

摘要：

过渡金属基层状双羟基化合物(transition metals based layered double hydroxides,TM LDHs)由于大的比表面积,开放的微观结构,可调的层间距和化学成分等优势,近年来被广泛应用于催化领域。本综述文章将集中介绍TM LDH在电催化水氧化中的应用,从其化学成分和微观结构的调控两方面入手,详述TM LDH具有优异催化水性能的原因,并对其催化性能未来进一步的可能发展进行展望。

关键词: 过渡金属基催化剂, 层状双羟基化合物, 水分解, 电催化, 二维纳米材料, 层状结构

Abstract:

Benefiting from the large specific surface area, open microstructure, tunable interlayer distance and chemical composition, the transition metals based layered double hydroxides(TM LDHs) have been widely applied and studied as efficient catalysts in recent years. This review introduces the design and applications of LDHs for electrochemical catalytic water oxidation. Illustrative examples are given on the origin of the advanced catalytic performance of TM LDHs towards water splitting, by focusing on their chemical compositions, microstructures and electronic properties. Possible strategies for further improving the catalytic performance and future development of TM LDHs are also prospected.

Key words: transition metals-based catalysts, layered double hydroxides, water splitting, electrocatalysis, two-dimensional nanomaterials, layered structure

龙霞,王亚琼,鞠敏,王政,杨世和. 过渡金属基层状双羟基化合物的调控及其在电化学水氧化中的应用[J]. 应用化学, 2018, 35(8): 881-889.

LONG Xia,WANG Yaqiong,JU Min,WANG Zheng,YANG Shihe. Elaboration and Application of Transition Metals Based Layered Double Hydroxides for Electrochemical Water Oxidation[J]. Chinese Journal of Applied Chemistry, 2018, 35(8): 881-889.

参考文献

[1]	Dresselhaus M S,Thomas I L.Alternative Energy Technologies[J]. Nature,2001,414(6861):332-337.
[2]	Crabtree G W,Dresselhaus M S,Buchanan M V.The Hydrogen Economy[J]. Phys Today,2004,57(12):39-44.
[3]	Turner J A.Sustainable Hydrogen Production[J]. Science,2004,305(5686):972-974.
[4]	Koper M T M. Thermodynamic Theory of Multi-Electron Transfer Reactions:Implications for Electrocatalysis[J]. J Electroanal Chem,2011,660(2):254-260.
[5]	Long X,Wang Z L,Xiao S,et al. Transition Metal Based Layered Double Hydroxides Tailored for Energy Conversion and Storage[J]. Mater Today,2016,19(4):213-226.
[6]	Ma W,Ma R Z,Wang C X,et al. A Superlattice of Alternately Stacked Ni-Fe Hydroxide Nanosheets and Graphene for Efficient Splitting of Water[J]. ACS Nano,2015,9(2):1977-1984.
[7]	Long X,Li J K,Xiao S,et al. A Strongly Coupled Graphene and FeNi Double Hydroxide Hybrid as an Excellent Electrocatalyst for the Oxygen Evolution Reaction[J]. Angew Chem Int Ed,2014,53(29):7584-7588.
[8]	Lu Z,Xu W W,Zhu W,et al. Three-Dimensional NiFe Layered Double Hydroxide Film for High-Efficiency Oxygen Evolution Reaction[J]. Chem Commun,2014,50(49):6479-6482.
[9]	Gerken J B,Shaner S E,Masse R C,et al. A Survey of Diverse Earth Abundant Oxygen Evolution Electrocatalysts Showing Enhanced Activity from Ni-Fe Oxides Containing a Third Metal[J]. Energy Environ Sci,2014,7(7):2376-2382.
[10]	Kim J,Yin X,Tsao K C,et al. Ca2Mn2O5 as Oxygen-Deficient Perovskite Electrocatalyst for Oxygen Evolution Reaction[J]. J Am Chem Soc,2014,136(42):14646-14649.
[11]	Suntivich J,May K J,Gasteiger H A,et al. A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles[J]. Science,2011,334(6061):1383-1385.
[12]	Lee J G,Hwang J,Hwang H J,et al. A New Family of Perovskite Catalysts for Oxygen-Evolution Reaction in Alkaline Media: BaNiO3 and BaNi0.83O2.5[J]. J Am Chem Soc,2016,138(10):3541-3547.
[13]	Trotochaud L,Young S L,Ranney J K,et al. Nickel-Iron Oxyhydroxide Oxygen-Evolution Electrocatalysts:The Role of Intentional and Incidental Iron Incorporation[J]. J Am Chem Soc,2014,136(18):6744-6753.
[14]	Ahn H S,Bard A J.Surface Interrogation Scanning Electrochemical Microscopy of Ni1-xFexOOH(0<x<0.27) Oxygen Evolving Catalyst: Kinetics of the “Fast” Iron Sites[J]. J Am Chem Soc,2016,138(1): 313-318.
[15]	Zhang B,Zheng X L,Voznyy O,et al. Homogeneously Dispersed Multimetal Oxygen-Evolving Catalysts[J]. Science,2016,352(6283):333-337.
[16]	Feng J X,Ye S H,Xu H,et al. Design and Synthesis of FeOOH/CeO2 Heterolayered Nanotube Electrocatalysts for the Oxygen Evolution Reaction[J]. Adv Mater,2016,28(23):4698-4703.
[17]	Wang Y Y,Liu D D,Liu Z J,et al. Porous Cobalt-Iron Nitride Nanowires as Excellent Bifunctional Electrocatalysts for Overall Water Splitting[J]. Chem Commun,2016,52(85):12614-12617.
[18]	Yu X Y,Feng Y,Guan B Y,et al. Carbon Coated Porous Nickel Phosphides Nanoplates for Highly Efficient Oxygen Rvolution Reaction[J]. Energy Environ Sci,2016,9(4):1246-1250.
[19]	Li D,Baydoun H,Verani C N,et al. Efficient Water Oxidation Using CoMnP Nanoparticles[J]. J Am Chem Soc,2016,138(12):4006-4009.
[20]	Wang Q,O'Hare D. Recent Advances in the Synthesis and Application of Layered Double Hydroxide(LDH) Nanosheets[J]. Chem Rev,2012,112(7):4124-4155.
[21]	Patel R,Park J T,Patel M,et al. Transition-Metal-Based Layered Double Hydroxides Tailored for Energy Conversion and Storage[J]. J Mater Chem A,2018,6(1):12-29.
[22]	Fan G L,Li F,Evans D G,et al. Catalytic Applications of Layered Double Hydroxides: Recent Advances and Perspectives[J]. Chem Soc Rev,2014,43(20):7040-7066.
[23]	Li Z H,Shao M F,An H L,et al. Fast Electrosynthesis of Fe-Containing Layered Double Hydroxide Arrays Toward Highly Efficient Electrocatalytic Oxidation Reactions[J]. Chem Sci,2015,6(11):6624-6631.
[24]	Tang C,Wang H S,Wang H F,et al. Spatially Confined Hybridization of Nanometer-Sized NiFe Hydroxides into Nitrogen-Doped Graphene Frameworks Leading to Superior Oxygen Evolution Reactivity[J]. Adv Mater,2015,27(30):4516-4522.
[25]	Wang Y Y,Zhang Y Q,Liu Z J,et al. Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts[J]. Angew Chem Int Ed,2017,56(21):5867-5871.
[26]	Vialat P,Mousty C,Taviot-Gueho C,et al. High-Performing Monometallic Cobalt Layered Double Hydroxide Supercapacitor with Defined Local Structure[J]. Adv Funct Mater,2014,24(30):4831-4842.
[27]	Nejati K,Akbari A R,Davari S,et al. Zn-Fe-Layered Double Hydroxide Intercalated with Vanadate and Molybdate Anions for Electrocatalytic Water Oxidation[J]. New J Chem,2018,42(4):2889-2895.
[28]	Li Y,Zhang L,Xiang X,et al. Engineering of ZnCo-Layered Double Hydroxide Nanowalls Toward High-Efficiency Electrochemical Water Oxidation[J]. J Mater Chem A,2014,2(33):13250-13258.
[29]	Zou X,Goswami A,Asefa T.Efficient Noble Metal-Free (Electro)catalysis of Water and Alcohol Oxidations by Zinc-Cobalt Layered Double Hydroxide[J]. J Am Chem Soc,2013,135(46):17242-17245.
[30]	Long X,Xiao S,Wang Z L,et al. Co Intake Mediated Formation of Ultrathin Nanosheets of Transition Metal LDH-An Advanced Electrocatalyst for Oxygen Evolution Reaction[J]. Chem Commun,2015,51(6):1120-1123.
[31]	Dinh K N,Zheng P L,Dai Z F,et al. Ultrathin Porous NiFeV Ternary Layer Hydroxide Nanosheets as a Highly Efficient Bifunctional Electrocatalyst for Overall Water Splitting[J]. Small,2018,14(8):1703257.
[32]	Smith R D L,Prevot M S,Fagan R D,et al. Photochemical Route for Accessing Amorphous Metal Oxide Materials for Water Oxidation Catalysis[J]. Science,2013,340(6128):60-63.
[33]	Gerken J B,Shaner S E,Masse R C,et al. A Survey of Diverse Earth Abundant Oxygen Evolution Electrocatalysts Showing Rnhanced Activity from Ni-Fe Oxides Containing a Third Metal[J]. Energy Environ Sci,2014,7(7):2376-2382.
[34]	Long X,Ma Z J,Yu H,et al. Porous FeNi Oxide Nanosheets as Advanced Electrochemical Catalysts for Sustained Water Oxidation[J]. J Mater Chem A,2016,4(39):14939-14943.
[35]	Grimaud A,May K J,Carlton C E,et al. Double Perovskites as a Family of Highly Active Catalysts for Oxygen Evolution in Alkaline Solution[J]. Nat Commun,2013,4:3439.
[36]	Klaus S,Cai Y,Louie M W,et al. Effects of Fe Electrolyte Impurities on Ni(OH)2/NiOOH Structure and Oxygen Evolution Activity[J]. J Phys Chem C,2015,119(13):7243-7254.
[37]	Corrigan D A.The Catalysis of the Oxygen Evolution Reaction by Iron Impurities in Thin-Film Nickel-Oxide Electrodes[J]. J Electrochem Soc,1987,134(2):377-384.
[38]	Hunter B M,Hieringer W,Winkler J R,et al. Effect of Interlayer Anions on [NiFe]-LDH Nanosheet Water Oxidation Activity[J]. Energy Environ Sci,2016,9:1734.
[39]	Gong M,Li Y G,Wang H L,et al. An Advanced Ni-Fe Layered Double Hydroxide Electrocatalyst for Water Oxidation[J]. J Am Chem Soc,2013,135(23):8452-8455.
[40]	Liu Y W,Hua X M,Xiao C,et al. Heterogeneous Spin States in Ultrathin Nanosheets Induce Subtle Lattice Distortion to Trigger Efficient Hydrogen Evolution[J]. J Am Chem Soc,2016,138(15):5087-5092.
[41]	Gunjakar J L,Kim T W,Kim H N,et al. Mesoporous Layer-by-Layer Ordered Nanohybrids of Layered Double Hydroxide and Layered Metal Oxide: Highly Active Visible Light Photocatalysts with Improved Chemical Stability[J]. J Am Chem Soc,2011,133(38):14998-15007.
[42]	Song F,Hu X L.Exfoliation of Layered Double Hydroxides for Enhanced Oxygen Evolution Catalysis[J]. Nat Commun,2014,5:5477.
[43]	Xu X,Song F,Hu X L.A Nickel Iron Diselenide-Derived Efficient Oxygen-Evolution Catalyst[J]. Nat Commun,2016,7:12324.
[44]	Tompsett D A,Parker S C,Islam M S.Rutile (beta-)MnO2 Surfaces and Vacancy Formation for High Electrochemical and Catalytic Performance[J]. J Am Chem Soc,2014,136(4):1418-1426.
[45]	Bao J,Zhang X D,Fan B,et al. Ultrathin Spinel-Structured Nanosheets Rich in Oxygen Deficiencies for Enhanced Electrocatalytic Water Oxidation[J]. Angew Chem Int Ed,2015,54(25):7399-7404.
[46]	Lei F C,Sun Y F,Liu K T,et al. Oxygen Vacancies Confined in Ultrathin Indium Oxide Porous Sheets for Promoted Visible-Light Water Splitting[J]. J Am Chem Soc,2014,136(19):6826-6829.
[47]	Wang Q,Chen L,Guan S,et al. Ultrathin and Vacancy-Rich CoAl-Layered Double Hydroxide/Graphite Oxide Catalysts:Promotional Effect of Cobalt Vacancies and Oxygen Vacancies in Alcohol Oxidation[J]. ACS Catal,2018,8(4):3104-3115.
[48]	Wang Y Y,Xie C,Zhang Z Y,et al. In Situ Exfoliated, N-Doped, and Edge-Rich Ultrathin Layered Double Hydroxides Nanosheets for Oxygen Evolution Reaction[J]. Adv Funct Mater,2018,28(4):1703363.
[49]	Liu R,Wang Y Y,Liu D D,et al. Water-Plasma-Enabled Exfoliation of Ultrathin Layered Double Hydroxide Nanosheets with Multivacancies for Water Oxidation[J]. Adv Mater,2017,29(30):1701546.
[50]	Xie Q,Cai Z,Li P,et al. Layered Double Hydroxides with Atomic-Scale Defects for Superior Eectrocatalysis[J]. Nano Res. ,2018,10.1007/s12274-018-2033-9.
[51]	Zhang Y,Cui B,Zhao C,et al. Co-Ni Layered Double Hydroxides for Water Oxidation in Neutral Electrolyte[J]. Phys Chem Chem Phys,2013,15(19):7363-7369.
[52]	Gao X Y,Long X,Yu H,et al. Ni Nanoparticles Decorated NiFe Layered Double Hydroxide as Bifunctional Electrochemical Catalyst[J]. J Electrochem Soc,2017,164(6):H307-H310.
[53]	Long X,Lin H,Zhou D,et al. Enhancing Full Water-Splitting Performance of Transition Metal Bifunctional Electrocatalysts in Alkaline Solutions by Tailoring CeO2-Transition Metal Oxides-Ni Nanointerfaces[J]. ACS Energy Lett,2018,3(2):290-296.
[54]	Li K D,Zhang J F,Wu R,et al. Anchoring CoO Domains on CoSe2 Nanobelts as Bifunctional Electrocatalysts for Overall Water Splitting in Neutral Media[J]. Adv Sci,2016,3:1500426.
[55]	Zhao Y F,Chen S Q,Sun B,et al. Graphene-Co3O4 Nanocomposite as Electrocatalyst with High Performance for Oxygen Evolution Reaction[J]. Sci Rep,2015,5:7629.