石墨烯/碳纳米管复合薄膜的制备进展

doi:10.3724/SP.J.1095.2014.30444

摘要/Abstract

摘要： 石墨烯/碳纳米管复合材料具有石墨烯和碳纳米管的共同特性，它弥补了石墨烯不连续和碳纳米管网存在间隙这两方面缺点。本文探讨了石墨烯/碳纳米管复合薄膜的制备新进展，阐述了利用自组装合成、非原位合成以及非化学合成等方法制备厚度薄、强度高和比电容高等特点的石墨烯/碳纳米管复合薄膜的方法，对石墨烯/碳纳米管复合薄膜在传感器、锂电池和超级电容器等方面的应用前景进行了展望。

关键词: 石墨烯, 碳纳米管, 复合薄膜

Abstract: Graphene/carbon nanotube composite materials have the common characteristics of both graphene and carbon nanotubes. The composite materials overcome the discontinuous faults of graphene and network clearance of carbon nanotubes. In this paper, the recent progress in the preparation of graghene/carbon nanotubes composite film was described. In situ, self-assembly and chemical-free syntheses of graphene/carbon nanotubes composite film with thin thickness, high strength and high specific capacitance characteristics, respectively, were summarized. The application of graphene/carbon nanotubes composite film in sensor, lithium battery and supercapacitor were proposed.

Key words: graphene, carbon nanotube, composite films

中图分类号:

O613.7

莫尊理, 王博, 赵国平, 朱小波, 郭瑞斌. 石墨烯/碳纳米管复合薄膜的制备进展[J]. 应用化学, DOI: 10.3724/SP.J.1095.2014.30444.

MO Zunli*, WANG Bo, ZHAO Guoping, ZHU Xiaobo, GUO Ruibin. Progress in Preparation of Graphene/Carbon Nanotube Composite Films[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30444.

参考文献

[1] Jha N,Jafri R I,Rajalakshmi N,et al. Graphene-multi Walled Carbon Nanotube Hybrid Electrocatalyst Support Material for Direct Methanol Fuel Cell[J]. Int J Hydrogen Energy,2011,36(12):7284-7290.

[2] Yang S,Shen C,Lu X,et al. Preparation and Electrochemistry of Graphene Nanosheets Multiwalled Carbon Nanotubes Hybrid Nanomaterials as Pd Electrocatalyst Support for Formic Acid Oxidation[J]. Electrochim Acta,2012,62:242-249.

[3] Shen L,Zhang X,Li H,et al. Design and Tailoring of a Three-Dimensional TiO2 Graphene Carbon Nanotube Nanocomposite for Fast Lithium Storage[J]. J Phys Chem Lett,2011,2(24):3096-3101.

[4] Lin J,Zhang C,Yan Z,et al. 3-Dimensional Graphene Carbon Nanotube Carpet-Based Microsupercapacitors with High Electrochemical Performance[J]. Nano Lett,2012,13(1):72-78.

[5] Tkalya E E,Ghislandi M,Koning C E. The Use of Surfactants for Dispersing Carbon Nanotubes and Graphene to Make Conductive Nanocomposites[J]. Curr Opin Colloid Interface Sci,2012,17(4):225-232.

[6] Mani V,Devadas B,Chen S M. Direct Electrochemistry of Glucose Oxidase at Electrochemically Reduced Graphene Oxide-Multiwalled Carbon Nanotubes Hybrid Material Modified Electrode for Glucose Biosensor[J]. Biosens Bioelectron,2012,41(15):309-315.

[7] Guo S,Wen D,Zhai Y,et al. Ionic Liquid Graphene Hybrid Nanosheets as an Enhanced Material for Electrochemical Determination of Trinitrotoluene[J]. Biosensors and Bioelectronics,2011,26(8):3475-3481.

[8] Pumera M,Ambrosi A,Bonanni A,et al. Graphene for Electrochemical Sensing and Biosensing[J]. TrAC Trends Anal Chem,2010,29(9):954-965.

[9] Geim A K,Novoselov K S. The Rise of Graphene[J]. Nat Mater,2007,6(3):183-191.

[10] REN Wencai,GAO Libo,MA Laipeng,et al. Preparation of Graphene by Chemical Vapor Deposition[J]. New Carbon Mater,2011,26(1):71-80(in Chinese).

任文才,高力波,马来鹏,等. 石墨烯的化学气相沉积法制备[J]. 新型炭材料,2011,26(1):71-80.

[11] ZHU Hongwei,XU Zhiping,XIE Dan. The Structure Performance Characterization and Preparation of Graphene[M]. Beijing:Tsinghua University Press,2011:102-113(in Chinese).

朱宏伟,徐志平,谢丹. 石墨烯-制备、结构方法与性能表征[M]. 北京：清华大学出版社，2011:102-113.

[12] Maldonado S,Morin S,Stevenson K J. Structure, Composition, and ChemicalReactivity of Carbon Nanotubes by Selective Nitrogen Doping[J]. Carbon,2006,44(8):1429-1437.

[13] Zheng Z,Wang Z,Feng Q,et al. Preparation of Surface-silvered Graphene-CNTs/Polyimide Hybrid Films:Processing, Morphology and Properties[J]. Mater Chem Phys,2012,138(1):350-357.

[14] Li W,Dichiara A,Bai J. Carbon Nanotube-Graphene Nanoplatelet Hybrids as High-performance Multifunctional Reinforcements in Epoxy Composites[J]. Compos Sci Techn,2013,74(24):221-227.

[15] NIE Haiyu. The Preparation of Carbon Nanotubes[J]. Plast Ind,2004,32(10):11-14(in Chinese).

聂海瑜. 碳纳米管的制备[J]. 塑料工业,2004,32(10):11-14.

[16] Cai D,Song M,Xu C. Highly Conductive Carbon-Nanotube/Graphite-Oxide Hybrid Films[J]. Adv Mater,2008,20(9):1706-1709.

[17] Tung V C,Chen L M,Allen M J,et al. Low-Temperature Solution Processing of Graphene-Carbon Nanotube Hybrid Materials[JP] for High-performance Transparent Conductors[J]. Nano Lett,2009,9(5):1949-1955.

[18] Pu J,Wan S,Lu Z,et al. Controlled Water Adhesion and Electrowetting of Conducting Hydrophobic Graphene/Carbon Nanotubes Composite Films on Engineering Materials[J]. J Maters Chem A,2013,1(4):1254-1260.

[19] Shi K,Zhitomirsky I. Electrophoretic Nanotechnology of Graphene-Carbon Nanotube and Graphene-Polypyrrole Nanofiber Composites for Electrochemical Supercapacitors[J]. J Colloid Interface Sci,2013,407:474-481.

[20] Su Y,Zhitomirsky I. Electrophoretic Deposition of Graphene, Carbon Nanotubes and Composite Films Using Methyl Violet Dye as a Aispersing Agent[J]. Colloids Surf A:Physicochem Eng Aspects,2013,436:97-103.

[21] Zhu G,Pan L,Lu T,et al. Electrophoretic Deposition of Reduced Graphene-Carbon Nanotubes Composite Films as Counter Electrodes of Dye-Sensitized Solar Cells[J]. J Mater Chem,2011,21(38):14869-14875.

[22] Yang S Y,Chang K H,Lee Y F,et al. Constructing a Hierarchical Graphene-Carbon Nanotube Architecture for Enhancing Exposure of Graphene and Electrochemical Activity of Pt Nanoclusters[J]. Electrochem Commun，2010,12(9):1206-1209.

[23] Kim Y K,Min D H. Durable Large-Area Thin Films of Graphene/Carbon Nanotube Double Layers as a Transparent Electrode[J]. Langmuir,2009,25(19):11302-11306.

[24] Yu D,Dai L. Self-Assembled Graphene/Carbon Nanotube Hybrid Films for Supercapacitors[J]. J Phy Chem Lett,2009,1(2):467-470

[25] LIU Yan,NIU Weifen,XU Lan. Hydrogen Peroxide Sensor Basedon Grapheme/Multi-Walled Carbon Nanotubes via Layer-by-Layer Assembly Technique[J]. Chinese J Anal Chem,2011,39(11):1676-1681(in Chinese).

刘艳,牛卫芬,徐岚. 基于层层自组装技术制备石墨烯/多壁碳纳米管共修饰的过氧化氢传感器的研究[J]. 分析化学,2011,39(11):1676-1681.

[26] Liu X,Hu Y S,Müller J O,et al. Composites of Molecular-Anchored Graphene and Nanotubes with Multitubular Structure:A New Type of Carbon Electrode[J]. Chem Sus Chem,2010,3(2):261-265.

[27] Kim J Y,Jang J W,Youn D H,et al. Graphene-Carbon Nanotube Composite as an Effective Conducting Scaffold to Enhance the Photoelectrochemical Water Oxidation Activity of a Hematite Film[J]. RSC Adv,2012,2(25):9415-9422.

[28] Li C,Li Z,Zhu H,et al. Graphene Nano-“Patches” on a Carbon Nanotube Network for Highly Transparent/Conductive Thin Film Applications[J]. J Phys Chem C,2010,114(33):14008-14012.

[29] Wu Y,Zhang T,Zhang F,et al. In Situ Synthesis of Graphene/Single-Walled Carbon Nanotube Hybrid Material by Arc-Discharge and Its Application in Supercapacitors[J]. Nano Energy,2012,1(6):820-827.

[30] Dong X,Li B,Wei A,et al. One-Step Growth of Graphene-Carbon Nanotube Hybrid Materials by Chemical Vapor Deposition[J]. Carbon,2011,49(9):2944-2949.

[31] Su Q,Liang Y,Feng X,et al. Towards Free-Standing Graphene/Carbon Nanotube Composite Films via Acetylene-Assisted Thermolysis of Organocobalt Functionalized Graphene Sheets[J]. Chem Commun,2010,46(43):8279-8281.

[32] Shuangqiang C,Waikong Y,Qi L,et al. Chemical-free Synthesis of Graphene-carbon Nanotube Hybrid Materials for Reversible Lithium Storage in Lithium-Ion batteries[J]. Carbon,2012,50(12):4557-4565.

[33] Hwang S H,Park H W,Park Y B,et al. Electromechanical Strain Sensing Using Polycarbonate-Impregnated Carbon Nanotube-Graphene Nanoplatelet Hybrid Composite Sheets[J]. Compos Sci Techn,2013,89:1-9

[34] Wassei J K,Cha K C,Tung V C,et al. The Effects of Thionyl Chloride on the Properties of Graphene and Graphene Carbon Nanotube Composites[J]. J Mater Chem,2011,21(10):3391-3396.

[35] Wang M,Zheng J. Direct Electrochemistry and Electrocatalysis of Hemoglobin Immobilized on the Functionalized Graphene-Carbon Nanotube Composite Film[J]. J Electrochem Soc,2012,159(6):F150-F156.