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石墨烯修饰玻碳电极测定邻苯二酚

罗启枚,王辉宪,刘登友*,王琳   

  1. (湖南农业大学理学院应用化学系 长沙 410128)
  • 收稿日期:2011-09-19 修回日期:2011-11-15 出版日期:2012-09-10 发布日期:2012-09-10
  • 通讯作者: 刘登友，副教授; Tel/Fax:0731-84617022; E-mail:liudy100@yahoo.com.cn; 研究方向：碳材料
  • 基金资助:
    湖南省省级科技计划资助项目（2009NK3107）

Determination of Catechol with Graphene Modified Glassy Carbon Electrode

LUO Qimei, WANG Huixian, LIU Dengyou*, WANG Ling   

  1. (Department of Applied Chemsitry，College of Science,Hunan Agricultural University,Changsha 410128,China)
  • Received:2011-09-19 Revised:2011-11-15 Published:2012-09-10 Online:2012-09-10
  • Contact: liudengyou
  • About author:

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1175

被引次数

17 | 2

摘要： 制备了用于测定邻苯二酚（CAT）的石墨烯修饰电极，并应用循环伏安法研究了CAT在该修饰电极上的电化学行为；用差分脉冲伏安法研究了测试底液的pH值对该修饰电极性能的影响，结果表明，此修饰电极在含不同浓度CAT的PBS溶液(pH=7.0)中测定，响应电流与CAT浓度在5.0×10-8～5.6×10-4 mol/L范围内有良好的线性关系，相关系数r=0.9919，检出限为6.68×10-9 mol/L（S/N=3）。 与其它几种修饰电极相比，石墨烯修饰电极制备简单、响应时间快、操作简便，稳定性和重现性良好，有应用价值。

关键词: 石墨烯, 测定, 差分脉冲伏安法, 邻苯二酚

Abstract: A graphene modified glassy carbon electrode was fabricated for the determination of catechol. The electrochemical behaviors of the modified electrodes were investigated by cyclic voltammetry(CV). The influence of the solution pH on the modified electrode was studied by differential pulse voltammetry(DPV). It was found that there was a good linear relationship between the response current and the concentration of catechol over the range from 5.0×10-8 to 5.6×10-4 mol/L, with the correlation coefficient of 0.9919 and the detection limit of 6.68×10-9 mol/L(S/N=3). Compared with other modified electrode, the graphene modified glassy carbon electrode was convenient to prepare, and it exhibited a fast response time and longterm stability, and could be used in the determination of catechol.

Key words: graphene, determination, differential pulse voltammetry, cathol

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