中华医学超声杂志

应用化学 ›› 1996, Vol. 0 ›› Issue (5): 29-32.

• 研究论文 • 上一篇    下一篇

1－对甲苯磺酰基－3－芳基－4－苯基－1,4,2－二氮磷杂环戊－5－酮的合成及除草活性

陈茹玉, 何良年, 杨秀凤   

  1. 南开大学元素有机化学研究所 元素有机化学国家重点实验室 天津 300071
  • 收稿日期:1995-12-28 修回日期:1996-05-17 出版日期:1996-10-10 发布日期:1996-10-10
  • 基金资助:
    国家自然科学基金

Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1,4,2-Diazaphospholidin-5-one-2-Oxides

Chen Ruyu, He Liangnian, Yang Xiufeng   

  1. Institute of Elemento-Organic Chemistry, Nankai University, The National Key Laboratory of Elemento-Organic Chemistry, Tianjin 300071
  • Received:1995-12-28 Revised:1996-05-17 Published:1996-10-10 Online:1996-10-10

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摘要： 通过1-苯基-3-对甲苯磺酰基脲与亚磷酸三苯酯和取代苯甲醛在甲苯中进行的类Man-nich反应合成1-对甲苯磺酰基-2-苯氧基-2-氧代-3-芳基-4-苯基-1,4,2-二氮磷杂环戊-5-酮。化合物的结构经元素分析、NMR、MS及部分化合物的红外光谱所证实,对合成过程中所涉及到的副反应进行了初步探讨,生物测定实验表明,某些产物具有良好的选择性除草活性。

关键词: 二氮磷杂环戊酮, 合成, 除草活性

Abstract: A series of 1-(p-toluenesulfonyl)-2-phenoxy-3-aryl-4-phenyl-1,4,2-diazaphospholidin-5-one-2-oxides (2) has been synthesized by the. Mannich-type reaction of 1-phenyl-3- (ptoluenesulfonyl) urea(1), substituted benzaldehydes and triphenyl phosphite in anhydrous toluene. The side reactions were discussed. The structures of new compounds were characterized by 1H NMR, 31P NMR, elemental analysis, MS and IR spectra. The results of preliminary bioassay showed that the compound 2 possesses good selective herbicidal activity against rape.

Key words: diazaphospholidin-one, synthesis, herbicidal activity

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