应用化学 ›› 1993, Vol. 0 ›› Issue (4): 30-34.
• 研究论文 • 上一篇 下一篇
王则民, 曹锦荣, 朱福森
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Wang Zemin, Cao Jinrong, Zhu Fusen
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摘要： 合成了6种稀土(RE)-萘乙酸(NAA)-邻菲绕啉(Phen)固体配合物,其通式为RE(NAA)3·Phen(RE=Y,La,Nd,Sm,Eu,Er)。通过元素分析,摩尔电导,IR,UV-Vis,H-NMR,XPS和TG-DTA分析,研究了配合物组成、性质及稀土离子与配体间的成键特性。
关键词: 稀土, 萘乙酸, 邻菲绕啉, 三元配合物, 合成
Abstract: Six new solid complexes of rare earth with 1-naphthaleneaeetie acid(NAA) and 1,10-phenanthroline (Phen) were prepared. These complexes all have the compsition of RE(NAA)3·Phen (RE=Y, La, Nd, Sm, Eu, Er). The compositions, properties and bonding specificity between RE3+ and ligands have been confirmed by elemental analysis,molar conductance, IR, UV-Vis, H-NMR,XPS spectra and TG-DTA measurements.
Key words: rare earth, naphthaleneacetic acid, phenanthroline, ternary complex, synthesis
王则民, 曹锦荣, 朱福森. 稀土萘乙酸邻菲绕啉三元配合物的合成和表征[J]. 应用化学, 1993, 0(4): 30-34.
Wang Zemin, Cao Jinrong, Zhu Fusen. SYNTHESIS AND CHARACTERIZATION OF TERNARY COMPLEXES OF RARE EARTH WITH 1-NAPHTHALENEACETIC ACID AND 1,10-PHENANTHROLINE[J]. Chinese Journal of Applied Chemistry, 1993, 0(4): 30-34.
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