中华医学超声杂志

应用化学 ›› 1989, Vol. 0 ›› Issue (6): 64-66.

• 研究简报 • 上一篇    下一篇

2-乙基己基膦酸单2-乙基己基酯与钴、镍、铜、锌固体萃合物的研究

黄可龙, 欧阳晖, 李元高, 董萍   

  1. 中南工业大学化学系 长沙
  • 收稿日期:1988-12-30 修回日期:1989-07-07 出版日期:1989-12-10 发布日期:1989-12-10

STUDY ON THE SOLID COMPLEXES OF DIVALENT COBALT, NICKEL, COPPER AND ZINC WITH ALKYLPHOSPHONIC ACID MONOESTER

Huang Kelong, Ouyang Hui, Li Yuangao, Dong Ping   

  1. Department of Chemistry, Central-South University of Technology, Changsha
  • Received:1988-12-30 Revised:1989-07-07 Published:1989-12-10 Online:1989-12-10

PDF

393

被引次数

3

摘要： 酸性磷(瞵)酸酯是一类重要的萃取剂,它们对金属离子的萃取性能和机理研究巳有报导,但大多限于溶液体系[1-3]。酸性磷酸酯金属萃合物的研究也有报导[4,5],但对固态烷基膦酸单烷基酯金属萃合物方面的报导较少。本文报导2-乙基已基膦酸2-乙基已基酯(简称HEH(EH)P或HA)金属(M=Co、Ni、Cu、Zn)固体萃合物的磁性,电子光谱和红外光谱,结合热分析结果对萃合物的成键特性和可能构型进行了讨论。

关键词: 萃取, 2-乙基已基膦酸2-乙基己基酯, 钴、镍、锌、铜离子, 固体萃合物

Abstract: The solid complexes were formed in the extraction of divalent metals (Co,Ni,Cu,Zn)from their nitrate solutions by 2-ethylhexyl phosphonic acid mono (2-ethlyhexyl) ester (HEH(EH)P). These complexes have been examined by elemental analysis, magnetic moment measurement and thermal analysis. The infrared spectra bave been investigated for HEH(EH)P-M(Ⅱ)(M=Co,Ni,Cu,Zn). The structures of the complexes have been elucidated.

Key words: Solvent extraction, 2-ethylhexyl phosphonic acid 2-ethylhexyl ester, CO,Ni,Cu,Zn ions, Solid complex

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