二维层状氮化二钙作为钠离子电池负极材料

doi:10.11944/j.issn.1000-0518.2018.03.170425

摘要/Abstract

摘要：

以Ca₃N₂为前驱体,用高温热解法制备了2D层状结构Ca₂N 并用X射线和扫描电镜对Ca₂N的组成、结构和形貌进行了表征。作为钠离子电池新型负极材料,在50 mA/g电流密度充放电,首次放电比容量可达584 mA·h/g,可逆比容量达180 mA·h/g。在2000 mA/g大电流密度下,仍有70 mA·h/g。

关键词: 氮化二钙, 二维层状结构, 钠离子电池, 负极材料

Abstract:

Two-dimensional layered Ca₂N was synthesized via a pyrolysis method with Ca₃N₂ precursor. The component, structure and morphology of Ca₂N were characterized by X-ray diffraction and scanning electron microscope. As a novel anode material of sodium ion batteries, the initial discharge capacity is up to 584 mA·h/g and the reversible capacity is about 180 mA·h/g at a current density of 50 mA/g. Even at a high current density of 2000 mA/g, a capacity of 70 mA·h/g can be retained.

Key words: dicalcium nitride, two-dimensional layered structure, sodium ion batteries, anode material

陈光海, 白莹, 吴锋, 吴川. 二维层状氮化二钙作为钠离子电池负极材料[J]. 应用化学, 2018, 35(3): 366-368.

CHEN Guanghai, BAI Ying, WU Feng, WU Chuan. Two-Dimensional Layered Dicalcium Nitride as Anode Material for Sodium Ion Batteries[J]. Chinese Journal of Applied Chemistry, 2018, 35(3): 366-368.

参考文献

[1]	Yabuuchi N,Kubota K,Dahbi M,et al. Research Development on Sodium-Ion Batteries[J]. Chem Rev,2014,114(23):11636-11682.
[2]	LI Hui,WU Chuan,WU Feng,et al. Sodium Ion Battery:A Promising Energy-Storage Candidate for Supporting Renewable Electricity[J]. Acta Chim Sin,2014,72(1):21-29(in Chinese). 李慧,吴川,吴锋,等. 钠离子电池:储能电池的一种新选择[J]. 化学学报,2014,72(1):21-29.
[3]	Yim T,Han Y K.Tris(trimethylsilyl) Phosphite as an Efficient Electrolyte Additive to Improve the Surface Stability of Graphite Anodes[J]. ACS Appl Mater Interfaces,2017,9(38):32851-32858.
[4]	Liu Y Y,Merinov, B V,Goddard III W A. Origin of Low Sodium Capacity in Graphite and Generally Weak Substrate Binding of Na and Mg Among Alkali and Alkaline Earth Metals[J]. Proc Natl Acad Sci USA,2016,113(14):3735-3739.
[5]	Ni Q,Bai Y,Wu F,et al. Polyanion-Type Electrode Materials for Sodium-Ion Batteries[J]. Adv Sci,2017,4:1600275.
[6]	Liu J H,Liu X W.Two-Dimensional Nanoarchitectures for Lithium Storage[J]. Adv Mater,2012,24(30):4097-4111.
[7]	Hu J P,Xu B,Yang S A,et al. 2D Electrides as Promising Anode Materials for Na-Ion Batteries from First-Principles Study[J]. ACS Appl Mater Interfaces,2015,7(43):24016-24022.
[8]	Gregory D H,Bowman A,Baker C F,et al. Dicalcium Nitride, Ca2N-A 2D “Excess Electron” Compound; Synthetic Routes and Crystal Chemistry[J]. J Mater Chem,2000,10(7):1635-1641.
[9]	Lee K,Kim S W,Toda Y,et al. Dicalcium Nitride as a Two-Dimensional Electride with an Anionic Electron Layer[J]. Nature,2013,494(7437):336-340.
[10]	Chen G H,Bai Y,Li H,et al. Multilayered Electride Ca2N Electrode via Compression Molding Fabrication for Sodium Ion Batteries[J]. ACS Appl Mater Interfaces,2017,9(8):6666-6669.
[11]	Naguib M,Mashtalir O,Carle J,et al. Two-Dimensional Transition Metal Carbides[J]. ACS Nano,2012,6(2):1322-1331.

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