无机铅卤钙钛矿纳米晶的合成、性能及应用

doi:10.11944/j.issn.1000-0518.2016.09.160212

摘要/Abstract

摘要：

无机铅卤钙钛矿CsPbX₃(X=Cl,Br,I)纳米晶因具有较高荧光量子效率(~90%)、发光波长覆盖整个可见光谱(400~700 nm)、半高宽相对较窄(12~42 nm)等诸多优点而备受关注,这些性能使之成为当前最具有潜在应用价值的发光材料之一。因此,近年来对该类无机铅卤钙钛矿材料的报道越来越多。本文主要介绍了无机铅卤钙钛矿发光材料的发展历程、结构、制备方法、生长机理及当前的主要应用领域等,最后概括了无机铅卤钙钛矿发光材料在当前研究背景下所面临的问题并展望了下一阶段的发展方向,为进一步提高其光学性能及开发新型高效的无机铅卤钙钛矿发光材料奠定基础。

关键词: 无机铅卤钙钛矿, CsPbX₃(X=Cl,Br,I), 发光材料, 纳米晶, 光电器件

Abstract:

Inorganic halide perovskite CsPbX₃(X=Cl,Br,I) nanocrystals(NCs) have been received much concern because it owns many excellent optical properties, such as high quantum yield(~90%), the emission wavelength covering the entire visible light region(400~700 nm), and the narrow full width at half maximum(12~42 nm). These advantages make it becomes one of the luminescence materials which have the most potential applications. Therefore, in recent years, reports involving inorganic halide perovskite materials become more and more. In this review, the development history, the synthetic routes, structures, growth mechanisms, and applications of inorganic halide perovskite NCs that make them excellent optoelectronic materials for various strategies are mainly discussed and highlighted. The existing problems of inorganic halide perovskite luminescence materials under the current research backgrounds are summarized. Finally, perspectives on future exploration of inorganic halide perovskite NCs for photoelectric devices are also given.

Key words: Inorganic halide perovskite, CsPbX₃(X=Cl,Br,I), photoluminescent materials, nanocrystals, photoelectric devices

楼孙棋, 宣曈曈, 郁彩艳, 李会利. 无机铅卤钙钛矿纳米晶的合成、性能及应用[J]. 应用化学, 2016, 33(9): 977-993.

LOU Sunqi, XUAN Tongtong, YU Caiyan, LI Huili. Synthesis, Properties and Applications of Inorganic Halide Perovskite Nanocrystals[J]. Chinese Journal of Applied Chemistry, 2016, 33(9): 977-993.

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