芘基查尔酮的合成及三阶非线性光学性质

doi:10.11944/j.issn.1000-0518.2015.10.150061

摘要/Abstract

摘要：

合成了一种新的具有潜在应用价值的非线性光学(NLO)有机材料1-(芘-1-基)-3-(4-二甲氨基苯基)丙烯酮(PMAK),并通过 NMR、IR、MS和元素分析等技术手段进行了表征。采用溶液Nd:YAG激光技术测定了PMAK的三阶非线性光学性质并确定了相关参数。纳秒实验结果:折射率n₂=-3.5×10^-17 m²/W,吸收系数β=7.0×10^-10 m/W,极化率χ⁽³⁾=2.54×10^-11 esu,分子超极化率γ=3.44×10^-30 esu;皮秒实验结果:n₂=-2.8×10^-18 m²/W,β=8.3×10^-11 m/W,χ⁽³⁾=2.49×10^-12 esu,γ=3.33×10^-31 esu。

关键词: 芘的衍生物, (芘-基)-(二甲氨基苯基)丙烯酮, 查尔酮, 合成, 非线性光学性质

Abstract:

A new nonlinear optical(NLO) organic material, 1-(pyrene-1-yl)- 3-(4-dimethyl aminophenyl)acrylic ketone(PMAK), was synthesized and characterized with ¹H NMR, IR, MS and elemental analysis. Meanwhile, the three-order nonlinear optical property of PMAK was tested by the Nd:YAG powder laser technology and the relevant parameters were determined. Nanosecond results are as follows:the refractive index n₂=-3.5×10^-17 m²/W, the absorption coefficient β=7.0×10^-10 m/W, the polarization rate χ⁽³⁾=2.54×10^-11 esu, the molecular hyperpolarizability γ=3.44×10^-30 esu. Picosecond results are as follows:n₂=-2.8×10^-18 m²/W, β=8.3×10^-11 m/W, χ⁽³⁾=2.49×10^-12 esu, γ=3.33×10^-31 esu.

Key words: pyrene derivative, (pyrene-yl)-(dimethylaminophenyl)acrylic ketone, chalcone, nonlinear optical property

孙金鱼,石玉芳,王桂林,赵明根. 芘基查尔酮的合成及三阶非线性光学性质[J]. 应用化学, 2015, 32(10): 1134-1138.

SUN Jinyu,SHI Yufang,WANG Guilin,ZHAO Minggen. Synthesis and Three-order Nonlinear Optical Property of Pyrenyl Chalcone[J]. Chinese Journal of Applied Chemistry, 2015, 32(10): 1134-1138.

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