应用化学

• 研究论文 • 上一篇    下一篇

电沉积Al/Pb-Ag阳极在硫酸中的电化学性能

王帅1,陈步明1,2*,郭忠诚1,2,周松兵1   

  1. (1.昆明理工大学 冶金与能源工程学院 昆明 650093;2.昆明理工恒达科技有限公司 昆明 650106)
  • 收稿日期:2013-12-03 修回日期:2014-02-25 出版日期:2014-09-03 发布日期:2014-09-03
  • 通讯作者: 陈步明,副教授; Tel/Fax:0871-68352599; E-mail:cbm12@qq.com; 研究方向:表面工程和冶金新材料
  • 基金资助:
    国家自然科学基金项目(51004056);云南省应用基础研究基金项目(2010ZC052)

Electrochemical Performances of Electrodeposited Al/Pb-Ag Anode in Sulfuric Acid

WANG Shuai1, CHEN Buming1,2*, GUO Zhongcheng1,2, ZHOU Songbing1, YANG Haitao1   

  1. (1.Faculty of Metallurgical an Energy Engineering,Kunming University of
    Science and Technology,Kunming  650093,China;
    2.Kunming Hengda Technology Co.,LTD,Kunming 650106,China)
  • Received:2013-12-03 Revised:2014-02-25 Published:2014-09-03 Online:2014-09-03

摘要: 采用阳极极化曲线、循环伏安法、交流阻抗法、XRD和SEM等技术手段研究了银含量对铝基铅银合金电化学性能的影响。 结果表明,在硫酸电解液中,随着银含量的增加,合金的耐腐蚀性逐渐提高,腐蚀膜的阻抗和析氧过电位逐渐降低。

关键词: 电沉积铅银合金, 电化学, 阳极, 耐腐蚀性能

Abstract: Lead-silver anodes with different contents of silver were prepared on the surface of Al substrates by electrodeposition. The impact of the silver concentration on the electrochemical properties of electrodeposited lead-silver alloys was investigated by the anodic polarization curves, cyclic voltammetry, EIS, XRD and SEM. The results show that the increase of silver contents to the lead-silver anodes can enhance the corrosion resistance and decrease the impedance of the corrosion film and oxygen overpotential.

Key words: electrodeposited lead-silver alloy, electrochemical, anode, corrosion-resistance behavior

中图分类号: