应用化学 ›› 1997, Vol. 0 ›› Issue (5): 43-46.

• 研究论文 • 上一篇    下一篇

烷氧基取代金属酞菁的合成及其吸收光谱性质

沈淑引, 刘恺, 丁西明, 周庆复, 许慧君   

  1. 中国科学院感光化学研究所光功能材料工程研究中心, 北京 100101
  • 收稿日期:1997-02-28 修回日期:1997-07-02 出版日期:1997-10-10 发布日期:1997-10-10
  • 基金资助:
    国家高技术新材料委员会资助

Synthesis and Spectroscopic Properties of Metal Phthalocyanine with Alkoxy Chains

Shen Shuyin, Liu Kai, Ding Ximing, Zhou Qingfu, Xu Huijun   

  1. Engineering Research Center for Photofunctional Materials, Institute of Photographic Chemistry, Chinese Academy of Sciences, Beijing 100101
  • Received:1997-02-28 Revised:1997-07-02 Published:1997-10-10 Online:1997-10-10

摘要: 合成了6种烷氧基取代的酞菁化合物,并进行了元素分析。研究了它们在溶液和薄膜中的吸收光谱性质。

关键词: 烷氧基酞菁, 合成, 吸收光谱

Abstract: Six derivatives of alkoxy metal phthalocyanine were synthesized and identified by elemental analysis. They have solubility of 10-30 g/L in chloroform. Their spectroscopic properties in solution and thin film were investigated. In solution the red shift was observed in the Q band absorption for compounds Ⅴ and Ⅵ. The absorption spectra of the thin film was found to be broadened and shifted to long wave length, dependent on the chain length of the substituents.

Key words: alkoxy metal phthalocyanine, synthesis, absorption spectrum