中华医学超声杂志

应用化学 ›› 1994, Vol. 0 ›› Issue (4): 45-49.

• 研究论文 • 上一篇    下一篇

TTF·M(dmit)2型电荷转移配合物的合成及其拉曼光谱

肖玉方, 姚钟麒, 金道森   

  1. 中国科学院兰州化学物理研究所 兰州 730000
  • 收稿日期:1993-09-08 修回日期:1994-01-07 出版日期:1994-08-10 发布日期:1994-08-10

Synthesis and Raman Spectra of Charge Complexes TTF·M (dmit)2

Xiao Yufang, Yao Zhongqi, Jin Daosen   

  1. Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000
  • Received:1993-09-08 Revised:1994-01-07 Published:1994-08-10 Online:1994-08-10

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摘要： 合成了8种四硫富瓦烯·二-(1,3-二硫杂环戊-4-烯-2-硫酮-4,5-二巯基)金属(缩写为TTF·M(dmit)2)电荷转移配合物,其中7种配合物为首次合成,拉曼光谱的研究结果表明,对同一种电子受体,电子给体的还原电势Ep越小,配合物的电荷转移度ρ值越大。

关键词: 四硫富瓦烯, 电荷转移配合物, 合成, 拉曼光谱

Abstract: Eight Charge transfer complexes of type TTF·M (dmit)2(M= Zn,Ni,Cu) were svnthesized.The raman spectra of the complexes showed that the lower the reduction potential(Ep) of the donor part of the complex,the larger the charge transfer degree(ρ)of the complex with the same acceptor.

Key words: tetrathiafulvalene, dimercapto-dithiol-thione, charge transfer complex, synthesis, Raman spectrum

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