应用化学 ›› 1993, Vol. 0 ›› Issue (4): 116-118.

• 研究简报 • 上一篇    

四[对-氧代(2-山萮酸乙酯基)]苯基卟啉银(Ⅱ)、镉(Ⅱ)的合成及其LB膜

谷淑珍, 金日镇, 杨文龙   

  1. 中国科学院长春应用化学研究所 130022 长春
  • 收稿日期:1992-09-22 修回日期:1992-11-26 出版日期:1993-08-10 发布日期:1993-08-10

SYNTHESES OF SILVER(Ⅱ)AND CADMIUM(Ⅱ)TETRA-4-OXY(2-ETHYL BEHENATE)PHENYLPORPHYRIN AND THEIR LANGMUIR-BLODGETT FILMS

Gu Shuzhen. Jin Rizhen, Yang Wenlong   

  1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 130022 Changchun
  • Received:1992-09-22 Revised:1992-11-26 Published:1993-08-10 Online:1993-08-10

摘要: Barraud等将具有两亲性的长链取代基接到苯环的对位上,制备了四[对-氧代(2-山萮酸乙酯基)]苯基卟啉,具有较好的成膜性能,我们按其方法合成了两个高价过渡金属Ag(Ⅱ)、Cd(Ⅱ)的四[对-氧代(2-山萮乙酯基)]苯基卟啉配合物,对它们的结构进行了表征,测定了π-A曲线及LB膜的可见吸收光谱和红外光谱。

关键词: 金属卟啉衍生物, 合成, LB膜

Abstract: Silver (Ⅱ) and cadmium(Ⅱ) tetra-4-oxy(2-ethylbehenate) phenyl porphyrin were synthesized. The LB films of the complexes gave the collapse pressures over 60mN/m. Visible spectra were recorded for the solution and multilayer and IR and ESR spectra for the solid.

Key words: metal porphyrin derivative, synthesis, LB film